岩石中铅和锌的分离与测定     

王贵琴 《陕西地质》2007,35(1):103-107

以KHSO4作为沉淀济加入到小体积(1 mL)试液中,以K2SO4.PbSO4复盐形式沉淀分离Pb,用NaAc-HAc溶液热提取Pb,1 mg Pb的平均回收率为100.66%;滤液再蒸至1 mL小体积,NaCl-NaOH小体积两次沉淀分离Fe、Ti、Mn等干扰元素,存在于滤液中的Zn平均回收率为100.5%。分离所得的含Pb2 和Zn2 的溶液用EDTA分别进行滴定,测定下限由0.5%降至0.01%;测定结果与极谱法、原子吸收法相一致;方法的精密度(RSD,n=10)试验Pb为2.6%,Zn为1.4%。  相似文献   

基于小波包变换的面波分离技术研究   总被引：1，自引：0，他引：1  

张华  潘冬明  刘松 《物探化探计算技术》2007,29(3):193-196

依据面波视速度的分布范围,提出一种新的叠前面波分离技术,即把地震波场分成不受面波影响的波场和受面波影响的波场,然后利用小波包变换对受面波影响的波场进行时频分析,通过分解与重构,从中提取有效波,再将其与不受面波影响的波场合并,就可得到面波分离后的地震波场。该方法在成功分离面波的同时,可使有效波的能量(尤其是其低频能量)不受损失,既有效地保持信号的频宽不变,又提高了记录的信噪比。实际资料的处理结果表明:此方法在叠前面波分离方面具有有良好的效果。  相似文献   

多目标地球化学调查土壤样品中氮和碳的快速测定   总被引：2，自引：1，他引：2  

于兆水  胡外英张勤 《岩矿测试》2007,26(3):235-237

详细研究了元素分析仪的工作条件，建立了直接固体进样同时测定多目标地球化学调查土壤样苎支氮、碳的方法。方法简便、快速，检出限为氮14．5μg／g、碳0．013％。经土壤国家一级标准物质分析验证，测定值与标准值相符，精密度（RSD，n=12）为氮1．49％-3．27％、碳0.64％～3.63％。  相似文献   

Flotation Separation of Trace Elements from Alkaline-Earth Matrices by Co(III) Hexamethylenedithiocarbamate before ICP-AES Determination     

Vesna Zajkova Paneva  Katarina Cundeva  Trajce Stafilov 《Geostandards and Geoanalytical Research》2007,31(1):51-60

A method for the selective separation of Ag, Cd, Cr, Cu, Ni, Pb and Zn in traces from solutions of calcite (CaCO₃), dolomite (CaMg(CO₃)₂) and gypsum (CaSO₄.2H₂O) before their determination by inductively coupled plasma-atomic emission spectrometry (ICP-AES) is presented. The expected interferences of Ca and Mg on intensities of trace analytes were removed by collecting the elements of interest with cobalt(III) hexamethylenedithiocar-bamate, Co(HMDTC)₃. The flotation of aqueous solutions (1 l) of calcite, dolomite and gypsum was performed at pH 6.0, by 1.5 mg l⁻¹ Co and 0.6 mmol l⁻¹ HMDTC⁻. To minimise the effect of the reaction between Ca/Mg, which restrains the function of the surfactant, careful selection of the most suitable foaming reagent was necessary. The accuracy of the method was established by analysing natural alkaline-earth minerals by the standard addition method as well as using the dolomite reference materials GBW 07114 and GSJ JDo-1. The ICP-AES limits of detection following flotation on different minerals were found to be 0.080 μg g⁻¹ for Cd, 0.105 μg g⁻¹ for Ag, 0.142 μg g⁻¹ for Cu, 0.195 μg g⁻¹ for Cr, 0.212 μg g⁻¹ for Ni, 0.235 μg g⁻¹ for Zn and 0.450 μg g⁻¹ for Pb.  相似文献   

Extraction of rhyolitic component of Vedde microtephra from minerogenic lake sediments   总被引：5，自引：0，他引：5  

Chris S. M. Turney 《Journal of Paleolimnology》1998,19(2):199-206

A technique is described for the extraction of rhyolitic microtephra from inorganic Lateglacial lake sediments. This technique was successfully applied by Lowe and Turney (1996) and is an adaption of the method described by Pilcher & Hall (1992) for application to Holocene peat deposits. It uses a density separation procedure to concentrate any microtephra component in lake sediments and was applied to the investigation of a lake sediment succession from a small basin in NE Scotland. Using this approach is was possible to define quantitatively for the first time the presence of the Vedde Ash tephra layer on the British Isles.  相似文献   

贵金属资源的应用及开发   总被引：1，自引：1，他引：0  

唐杰  张凯 《世界地质》1998,17(4):98-102

将贵金属的应用,资源分布,生产和贵金属的分析化学结合在一起进行了综述,由于贵金属资源的短缺性及考虑可持续发展战略,特别介绍了贵金属资源的二次回收问题,并对其将来的发展作了一定的评价和展望。  相似文献   

A Spectrum-Independent Procedure for Correcting Eddy Fluxes Measured with Separated Sensors   总被引：1，自引：0，他引：1  

Johannes Laubach  Keith G. McNAUGHTON 《Boundary-Layer Meteorology》1998,89(3):445-467

We investigate flux underestimates in eddy correlation measurements that are caused by horizontal separation of the sensors. A common eddy correlation setup consists of a sonic anemometer and a humidity sensor which, because of its bulk, must be placed some distance away from the sonic path, leading to a flux loss (of latent heat). Utilizing an additional fast temperature sensor placed near the humidity sensor, we develop a procedure for correcting for this loss. The procedure simultaneously corrects the sensible heat flux for the difference between true temperature and sonic temperature. Our correction procedure, which does not depend on the shape of the cospectrum, is then compared to the widely-used procedure following Moore (1986), which assumes a cospectral model ('Kansas Model). Both correction methods are applied to data collected within the internal boundary layer over a rice paddy, downwind of arid land. Under conditions of good fetch, they were found to agree well. Under poor fetch conditions, the model-based correction tended to be too small, while the spectrum-independent combined correction was robust. The latter is thus recommended for situations where the cospectral shape can be expected to deviate from the 'Kansas shape.  相似文献   

对流层平流层气溶胶粒子的形态和化学组成   总被引：13，自引：1，他引：12  

许黎  樊小标  石广玉  岩坂泰信  奥原靖彦  原圭一郎  龚知本  周军 《气象学报》1998,56(5):551-559

分析研究了１９９３年和１９９４年的８月、９月在香河地区上空采集的单个气溶胶粒子的形态及化学元素和化合物的组成。结果表明：１９９３年,在对流层大气中的气溶胶颗粒经常出现不规则形的粒子,可能是土壤粒子;而在平流层大气中的颗粒以具有“卫星”结构的硫酸粒子为主;硫酸铵粒子则经常出现在对流层的中、下部。香河地区上空颗粒物的化学元素组成比较复杂,单一化学元素组成的粒子较少,粒子主要含有Ｓｉ,Ｆｅ,Ａｌ和Ｓ等元素。气溶胶的化合物有硫酸盐、硅酸盐、硝酸盐和磷酸盐等  相似文献   

On the galactic motion     

F. M. F. El-Sabaa  H. H. Sherief 《Celestial Mechanics and Dynamical Astronomy》1990,49(3):233-247

A certain potential function is studied as a possible model for the galactic potential. Some solutions are obtained. Also the numerical study of some of the orbits and their stability is carried out.  相似文献   

Separation of ocean features from multifrequency full-polarization SAR imagery     

YANG Jingsong  XIAO Qingmei  HUANG Weigen  FU Bin  CHEN Peng 《海洋学报(英文版)》2008,27(Z1):155-158

Different ocean features usually appear in synthetic aperture radar (SAR) images simultaneously. This makes the image compli- cated and hard to understand. Because of lower signal-to-noise rate , it is much more difficult to separate different ocean features than to separate different land features. A completely novel method is presented to separate ocean features from multifrequency po- larimetric SAR imagery. AIRSAR data from Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA) are used in the case studies and good results are achieved.  相似文献