塔中原油超高二苯并噻吩硫特征及其控制因素   总被引：1，自引：1，他引：0  

李素梅  张宝收  张海祖  盛世忠  赵明 《现代地质》2011,25(6):1108-1120

塔中相当部分原油具有高丰度芳香硫——二苯并噻吩(DBTs)特征,其在原油中的绝对丰度高达26 859μg/g,在芳烃中的相对丰度高达58.2%,主要分布在塔中I号构造带下奥陶统、塔中4(TZ4)和塔中1-6(TZ1-6)井区。采用综合地球化学研究途径,对该区原油的高DBTs特征及其主控因素进行初步探讨。分析表明,研究区母源岩较强地控制DBTs的丰度,纯泥岩、页岩中DBTs丰度不高,灰岩、云岩等烃源岩DBTs丰度偏高或超高;观察到在正常油窗范围内,烃源岩和相关原油随成熟度增加DBTs丰度增加,而塔中型高-过熟原油中DBTs丰度有先增加后减小的趋势,表明热成熟作用对该化合物有较强的控制作用;发现生物降解、水洗可使原油中DBTs丰度降低,但对塔中原油中DBTs影响较小;观测到塔中相当部分原油的DBTs含量与硫酸盐热化学还原作用——TSR的作用产物H2S、硫醇、长链烷基四氢噻烷有一定正相关性。对比研究认为,有多种因素控制塔中原油中DBTs丰度与分布,热成熟作用、TSR是导致塔中下奥陶统部分原油高DBTs特征的重要原因,前者可能是主要因素,特殊母源岩因素相对较少,尽管尚不能排除。TZ4井区等石炭系高DBTs原油主要来自深部地层,与下奥陶统抑或更深层高DBTS原油的混入有关。本研究对于该区深层油气勘探具有重要意义。  相似文献   

Geothermal Power Generation Potential in the Eastern Linqing Depression     

KANG Fengxin  ZHAO Jichu  TAN Zhirong  SUI Haibo  SHI Meng 《《地质学报》英文版》2021,95(6):1870-1881

China has been the leading country worldwide in direct geothermal utilization for a rather long time, which has contributed significantly to reducing carbon emissions. But the installed capacity of geothermal power generation in China is very small, and there are only a few geothermal power plants in China, specifically in Tibet, including the well-known Yangbajing geothermal power plant. Therefore, it is anticipated that more high-temperature geothermal resources will be discovered in order to promote China’s power generation. There is potential for high-enthalpy geothermal in the Eastern Linqing Depression in Shandong Province, where geothermal energy is stored in Ordovician and Cambrian carbonate strata. Based on the geothermal gradient in Cenozoic strata and the depth of the target geothermal reservoir, the temperature distribution pattern of the reservoir was analyzed, and two “sweet points” were identified in the Yucheng geothermal field and the Guanxian geothermal field, where the reservoir temperature is predicted to be higher than 200°C at a depth of less than 8000 m. Due to the low karst fissure ratio and the insufficient geothermal fluid in the geothermal reservoir, it is recommended that an enhanced geothermal system be set up, to increase the permeability of the natural fracture system in the carbonate formations and provide sufficient fluid for power generation through reinjection of used geothermal fluid. The power generation capacity of the two geothermal fields was estimated using a volumetric method, revealing a power generation capacity of 1621.02 MWe for the Yucheng geothermal field, and 1287.19 MWe for the Guanxian geothermal field.  相似文献   

Thermo-economic Investigation of an Enhanced Geothermal System Organic Rankine Cycle and Combined Heating and Power System     

WANG Lingbao  BU Xianbiao  LI Huashan 《《地质学报》英文版》2021,95(6):1958-1966

As a potentially viable renewable energy, Enhanced Geothermal Systems (EGSs) extract heat from hot dry rock (HDR) reservoirs to produce electricity and heat, which promotes the progress towards carbon peaking and carbon neutralization. The main challenge for EGSs is to reduce the investment cost. In the present study, thermo-economic investigations of EGS projects are conducted. The effects of geofluid mass flow rate, wellhead temperature and loss rate on the thermo-economic performance of the EGS organic Rankine cycle (ORC) are studied. A performance comparison between EGS-ORC and the EGS combined heating and power system (CHP) is presented. Considering the CO2 emission reduction benefits, the influence of carbon emission trading price on the levelized cost of energy (LCOE) is also presented. It is indicated that the geofluid mass flow rate is a critical parameter in dictating the success of a project. Under the assumed typical working conditions, the LCOE of EGS-ORC and EGS-CHP systems are 24.72 and 16.1 cents/kWh, respectively. Compared with the EGS-ORC system, the LCOE of the EGS-CHP system is reduced by 35%. EGS-CHP systems have the potential to be economically viable in the future. With carbon emission trading prices of 12.76 USD/ton, the LCOE can be reduced by approximately 8.5%.  相似文献   

渤海沉积物中甲烷氧化速率及同位素分馏规律研究     

陈宇峰  郑秀丽  李晶  贺行良  刘昌岭  孟庆国  秦德谛  张培玉 《岩矿测试》2018,37(2):164-174

渤海蕴藏着大量的油气资源,其主要成分是温室气体甲烷,自然环境下或人为因素的影响会引起其泄露与迁移,对环境造成负面的影响。但是,泄露与迁移过程中微生物会氧化绝大部分甲烷,而不同的环境条件会影响氧化过程中的速率及碳同位素分馏过程。为了更好地认识渤海沉积物中甲烷氧化规律和同位素分馏规律以及为进一步研究此区域的甲烷氧化提供参考,本文选取渤海沉积物作为进行实验室模拟降解实验原料,借助气相色谱和气相色谱-同位素比值质谱仪测定渤海沉积物中的甲烷氧化速率,确定了甲烷氧化碳同位素分馏系数ε。结果表明:渤海沉积物中甲烷氧化作用以好氧氧化占主导,氧化温度和气体流速是影响甲烷氧化速率的主要因素。在连续培养的模式下,当温度由28℃降至15℃时,甲烷的平均氧化速率降低60%±10%,即温度越低越不利于甲烷氧化作用的发生。而气体流速由50μL/min增加至150μL/min时,甲烷的平均氧化速率增加90%±10%,即增加气体流速有利于氧化反应速率的提高。实验还发现,甲烷碳、氢同位素的分馏效应主要受氧化温度制约,分馏程度与温度呈正相关。实验结论认为温度是影响甲烷氧化速率和同位素分馏规律的重要因素。  相似文献   

The improvement of an object-oriented classification using multi-temporal MODIS EVI satellite data     

《International Journal of Digital Earth》2013,6(3):219-236

Abstract

This paper investigates the contribution of multi-temporal enhanced vegetation index (EVI) data to the improvement of object-based classification accuracy using multi-spectral moderate resolution imaging spectral-radiometer (MODIS) imagery. In object-oriented classification, similar pixels are firstly grouped together and then classified; the produced result does not suffer the speckled appearance and closer to human vision. EVI data are from the MODIS sensor aboard Terra spacecraft. 69 EVI data (scenes) were collected during the period of three years (2001–2003) in a mountainous vegetated area. These data sets were used to study the phenology of the land cover types. Different land cover types show distinct fluctuations over time in EVI values and this information might be used to improve object-oriented land cover classification. Two experiments were carried out: one was only with single date MODIS multispectral data, and the other one including also the 69 EVI images. Eight classes were distinguished: temperate forest, tropical dry forest, grassland, irrigated agriculture, rain-fed agriculture, orchards, lava flows and human settlement. The two classifications were evaluated with independent verification data, and the results showed that with multi-temporal EVI data, the classification accuracy was improved 5.2%. Evaluated by McNemar's test, this improved was significant, with significance level p=0.01.  相似文献   

浅层地下水中氯代烷烃生物降解的地下水化学 响应规律研究     

郑昭贤  苏小四  王鼐  康博 《地球学报》2014,35(2):230-238

以东北某油田石油污染场地多期地下水化学监测数据为基础,分析氯代烷烃自然生物降解中充当第一基质、电子受体、中间产物的水化学组分及相关地球化学参数在污染晕演化的不同时段、不同部位的变化趋势,了解氯代烷烃生物降解的地下水化学响应特征,并以此为依据对污染场地浅层地下水氯代烷烃生物降解程度进行定性评价。结果表明:2010年6月,事故发生约1年之际,在ZK1—ZK3—ZK6纵向剖面上生物降解过程中充当电子受体的水化学组分(SO42–)、第一基质(CH2Cl2、CHCl3)和代表地下水环境的主要理化指标(pH、Eh)从上游到下游均呈递增规律,而相关还原产物(Fe2+、Mn2+、HCO3–)则呈递减规律,这也表明天然微生物降解具有一定的滞后性。2010年6月氯代烷烃天然生物降解评价表明ZK1属微生物降解证据充足;ZK3观测井属微生物降解证据有限;ZK6观测井属微生物降解证据不足。而2011年5月,事故发生约2年之际,封堵污染源后随污染晕中心的向下游迁移,ZK3观测井中生物降解作用逐渐明显,在ZK3—ZK6纵向剖面上地下水化学指标呈现上述响应规律,而ZK1观测井诸多水化学指标经上游未污染地下水的补充更新,逐渐趋向污染前的背景值。  相似文献   

聚驱后油藏剩余油分布数值模拟     

叶银珠  王正波 《吉林大学学报(地球科学版)》2012,(Z1):119-126

通常聚合物驱的最终采收率在50%左右,聚合物驱后剩余油具有相当的开采潜力。以大庆长垣北部多段多韵律聚驱主力油藏为例,采用化学驱油藏数值模拟技术,系统研究并总结了典型油藏聚驱后平面及纵向剩余油的分布特征。结果表明,聚驱后油藏剩余油的分布系统可划分为2大成因、3大区域和7个部位。其中:存在受地质因素制约的剩余油,如废弃河道中部、砂体尖灭区、相对孤立的薄差砂体;也有开发因素控制的剩余油,如厚油层顶部剩余油、注采不完善部位、注入井间与生产井附近以及聚驱后高渗层内的残余油。聚合物驱后油藏剩余油主要富集于3大区域内,究其原因则主要源于水驱和后续聚驱波及程度的不同。  相似文献   

浅谈煤矿地质测量工作的重要性     

张英琦  梁玉恩 《吉林地质》2012,(3):128-130

本文针对煤矿工作的特点,阐述了在矿井掘进和回采等工作中测量工作的重要性和测量步骤,并以论证了准确测量在安全生产工作中的重要性。  相似文献   

大变形黏土防渗层中的污染物迁移和转化规律研究   总被引：1，自引：0，他引：1  

李涛  刘利  丁洲祥 《岩土力学》2012,33(3):687-694

国内湖泊疏浚污染底泥堆场一般以较厚的黏土层作为主要防渗层,由于在上覆底泥作用下黏土层会发生较大的固结变形,因此,在研究黏土防渗层中的污染物运移和转化规律时,应该考虑土体变形的影响。基于Gibson一维大变形固结理论和饱和多孔介质中的污染物对流扩散方程,建立了二者耦合的可变形多孔介质中污染物的运移和转化模型,其中首次考虑了土体自重和生物降解作用的影响。利用所建立模型的数值解,研究了在可变形黏土防渗层中的污染物运移和转化规律,同时分析了模型中不同项和主要参数的作用和影响。研究结果表明,土体大变形对黏土防渗层中污染物的运移有着较复杂的影响,一方面土体变形会加速污染物的运移;另一方面土体固结带来的渗透性减小会增加污染物的穿透时间,二者的不同作用取决于众多的影响因素,如土层厚度和吸附作用等。研究结果对于评估天然黏土防渗层对污染物的阻隔作用有重要的指导意义。  相似文献   

探讨肘部固定夹板应用于CT增强患者的临床价值          下载免费PDF全文

汪令生  汪令成  吴德红  吴磊  陈义加  付传明 《CT理论与应用研究》2016,(2):197-202

目的:探讨肘部固定夹板应用于CT增强患者中的临床实际价值。对象与方法:将预做CT增强检查的120例患者,随机分为对照组(60例)和观察组(60例)。对照组所有患者在进行CT增强检查前肘关节部位不使用肘部固定夹板;观察组所有患者在进行CT增强检查前肘关节部位使用肘部固定夹板,比较两组患者碘对比剂渗漏的发生率及护理服务满意度。结果:对照组60例患者中发生渗漏10例,发生率为16.7%,护理服务满意度80%。观察组60例患者中发生渗漏2例,发生率3.3%,护理服务满意度95%。观察组碘对比剂渗漏的发生率明显低于对照组,而护理服务满意度优于对照组,两组比较差异具有统计学意义(P0.05)。结论:肘部固定夹板应用于CT增强患者时,明显降低了碘对比剂渗漏发生率,并提升了护理服务满意度。患者很容易接受,值得临床推广应用。  相似文献