橄榄岩中尖晶石的O同位素继承性与晶体结构转换     

李一良  王峥嵘  郑永飞 《地球学报》1997,18(Z1):260-262

应用增量法计算的矿物对O同位素分馏曲线，得到正尖晶石-矿物对O同位素温度高于尖晶石在地幔中的熔点，而用反尖晶石-矿物对计算的O同位素温度低于尖晶石的熔点，较为合理。因此，地幔橄榄岩中镁铝尖晶石的O同位素组成可能继承了其母体反尖晶石特征，即使反结构尖晶石在发生相变作用变成正结构尖晶石时未发生O同位素再平衡。  相似文献   

Disequilibrium for Ca during growth of pelitic garnet   总被引：14，自引：1，他引：14  

C. B. CHERNOFF  & W. D. CARLSON 《Journal of Metamorphic Geology》1997,15(4):421-438

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.  相似文献   

A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland)   总被引：7，自引：0，他引：7  

C. MEYRE  C. DE CAPITANI  & J. H. PARTZSCH 《Journal of Metamorphic Geology》1997,15(6):687-700

A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi₂O₆), diopside (CaMgSi₂O₆) and hedenbergite (CaFeSi₂O₆) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H₂O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).  相似文献   

博斯腾湖的水盐平衡与矿化度   总被引：11，自引：5，他引：11  

成正才  李宇安 《干旱区地理》1997,20(3):43-49

博斯腾湖曾是中国内陆区最大的淡水湖，因人类活动影响约在１９６８年演变为微咸水湖。本文依据湖泊水平衡太矿化度基本原理，结合博斯滕湖实际，分析计算了该湖各个时期的水盐平衡与矿化度；经推地整理，提出了预测矿化度的计算式，经检验与实测值基本吻合。  相似文献   

流体的热力学前缘研究   总被引：12，自引：1，他引：12  

张哲儒 《地学前缘》1996,3(3):80-88

总结了当前国内外关于流体的热力学前缘研究领域如下：（１）流体体系的ｐ－Ｖ－Ｔ－ｘ相关系研究，主要对象是Ｈ２Ｏ－ＣＯ２－盐类多组分体系高温高压下相图的实验和理论研究。（２）矿物在流体中的溶解度及溶解后在流体中溶解类型的形式和热力学性质——平衡常数（或Ｇｉｂｂｓ自由能）及各种偏摩尔性质的研究。（３）流体热力学模型化研究，已研制出大量的计算机软件，包括多种矿物、溶解类型的热力学数据库和模拟热液平衡、矿物溶解性质、反应路径和水—岩相互作用的实用程序。（４）超临界流体的相关系和化学反应等有许多特殊的性质，对认识地球内部的演化将有重要意义。（５）新技术新方法的发展，使分析单个矿物包裹体成分变成了现实。  相似文献   

The mean and turbulence structure simulation of the monsoon trough boundary layer using a one-dimensional model withe-l ande-ε closures     

Kusuma G. Rao  V. N. Lykossov  A. Prabhu  S. Sridhar  E. Tonkacheyev 《Journal of Earth System Science》1996,105(3):227-260

An attempt has been made here to study the sensitivity of the mean and the turbulence structure of the monsoon trough boundary layer to the choice of the constants in the dissipation equation for two stations Delhi and Calcutta, using one-dimensional atmospheric boundary layer model withe-ε turbulence closure. An analytical discussion of the problems associated with the constants of the dissipation equation is presented. It is shown here that the choice of the constants in the dissipation equation is quite crucial and the turbulence structure is very sensitive to these constants. The modification of the dissipation equation adopted by earlier studies, that is, approximating the Tke generation (due to shear and buoyancy production) in theε-equation by max (shear production, shear + buoyancy production), can be avoided by a suitable choice of the constants suggested here. The observed turbulence structure is better simulated with these constants. The turbulence structure simulation with the constants recommended by Aupoixet al (1989) (which are interactive in time) for the monsoon region is shown to be qualitatively similar to the simulation obtained with the constants suggested here, thus implying that no universal constants exist to regulate dissipation rate. Simulations of the mean structure show little sensitivity to the type of the closure parameterization betweene-l ande-ε closures. However the turbulence structure simulation withe-ε. closure is far better compared to thee-l model simulations. The model simulations of temperature profiles compare quite well with the observations whenever the boundary layer is well mixed (neutral) or unstable. However the models are not able to simulate the nocturnal boundary layer (stable) temperature profiles. Moisture profiles are simulated reasonably better. With one-dimensional models, capturing observed wind variations is not up to the mark.  相似文献   

High Pressure-Differential Thermal Analysis and Ultrasonic Wave Amplitude Analysis of Ice-Water Equilibrium at 1.5-5.0GPa     

Xu Yousheng  Zheng Haifei  Xie Hongsen  Zhang Yueming  Xu Huigang  Guo Jie 《中国地球化学学报》1996,15(2):153-158

Water is the most active component in all geological systems.It has an important effect on the physical properties of minerals and melts.It also plays a key role in the evolution of the Earth.Accurate thermodynamics data on water are currently confined to pressures below 1.0GPa and temperatures below 900℃.Presented in this paper are new data available on the P-T properties of water at pressures up to 5.0GPa,develoged from differential thermal analysis and ultrasonic wave amplitude analysis.It has been found that there may exist another ternary point at 3.0GPa and that ultrasonic wave amplitude change of ice-water transition shows two inflection points above 2.0GPa, consistent with the two peaks of differential thermal curves above 2.0GPa .It may be a new phenomenon which needs further study.  相似文献   

从天山乌鲁木齐河源1号冰川变化估计近百年来该地区夏季升温   总被引：6，自引：6，他引：6  

王宁练  刘时银 《冰川冻土》1997,19(3):207-213

通过冰川波动历史来揭示气候变化是一种重要的方法。然而，以往有关这一方面的研究大都是一些定性的。文章试图依据冰种变化来定量的研究气候变化，并且通过近百年来天山乌鲁木齐河源１号冰川的变化，揭示出本世纪以来该河源地区夏季气温上升约０．２３￣０．２５℃，同时，对于该冰川不同长度规模时的气候敏感性也进行了讨论。  相似文献   

AN APPARENT TEMPERATURE MODEL BASED ON THERMAL EQUILIBRIUM          下载免费PDF全文

YU Bo  LIU Mei  YAO Kemin 《Acta Meteorologica Sinica》2004,18(1):117-128

In this paper,a comprehensive analysis and review of the advances in the research of human body comfort degree is made.Based on the studies of human thermal equilibrium theories contributed by previous researchers,different apparent temperature models corresponding to different environments are set up in accordance with the current situation and the characteristics of metabolism in different groups of people in China.After case studies and comparison with present dominant human body comfort degree statistical models,it is proved that the apparent temperature models have high rationality and wide adaptability.Furthermore,the comfort scaling standard according to apparent temperature is suggested,which is suitable for the middle latitude regions in China.  相似文献   

钱家店铀矿床U-Ra平衡系数特征研究   总被引：1，自引：0，他引：1  

张明瑜  夏毓亮  刘汉彬  田时丰  张泽贵 《铀矿地质》2004,20(6):364-369,329

本文探讨了可地浸砂岩型铀矿U-Ra平衡系数的计算方法，研究了钱家店砂岩型铀矿床U-Ra平衡系数的变化特征。这些成果为钱家店铀矿床放射性测井数据的修正、矿体边界的确定、铀矿资源量的计算提供了科学依据。  相似文献