Western Arctic Cyclones and Equilibrium between the Atmospheric Boundary Layer and the Sea Surface     

R. L. Raddatz  R. J. Galley  B. G. Else  T. N. Papakyriakou  M. G. Asplin  L. M. Candlish 《大气与海洋》2014,52(2):125-141

The data-collection campaign for the 2008 International Polar Year–Circumpolar Flaw Lead System Study saw the Canadian Coast Guard Ship (CCGS) Amundsen, a research icebreaker, overwinter in high-concentration unconsolidated sea ice in Amundsen Gulf. Environmental monitoring continued into the open-water season. During this period, the Amundsen registered five relatively deep mean sea-level pressure minima (less than 100?kPa). Three were selected for further analysis based on season and the nature of the underlying ocean or sea-ice surface: (1) a winter pressure minimum over unconsolidated sea ice, (2) a spring pressure minimum which likely contributed to the break-up of the sea-ice cover on Amundsen Gulf, and (3) a summer pressure minimum over open water. The characteristics of these pressure minima and the impact of their passage on the atmospheric boundary layer and on the sea-ice cover as they crossed Amundsen Gulf were examined. Several features were revealed by the analysis. (1) The winter and summer pressure minima were migratory cyclones accompanied by Arctic frontal waves with characteristics very similar to the polar frontal waves associated with the migratory cyclones found at more southerly latitudes, whereas the spring pressure minimum was attributed to an Arctic frontal trough of low pressure with the cyclonic centre remaining south of the Gulf. (2) The passage of the frontal-wave cyclone in winter and the frontal trough of low pressure in spring disrupted the equilibrium that had been established during more settled periods between the atmospheric boundary layer and the mosaic surface (leads, polynyas, and sea ice); however, equilibrium was quickly re-established. (3) In summer, the thermal structure of the lower atmospheric boundary layer persisted through the passage of the frontal-wave cyclone over the open-water surface. (4) The passage of the frontal-wave cyclone in winter and the frontal trough of low pressure in spring modified the mesoscale sea-icescape.  相似文献   

稳定同位素分馏蒸汽压效应的计算方法     

张继习  刘耘 《地球化学》2014,(1):1-10

稳定同位素分馏的蒸汽压效应（vaporpressureisotopeeffects,简称VPIE）,在地球化学和天体化学上有着非常重要的研究意义。大部分情况下,由于轻重同位素体具有不同的蒸汽压,在经历挥发和蒸发过程时,含有重同位素的物种挥发得慢,轻同位素物种挥发得快,最终结果导致凝聚相富集重同位素,气相含有较多的轻同位素。在地球化学上,VPIE直接同非常重要的地学参数——同位素平衡分馏系数仅联系在一起。本文应用Bigeleisen提出的方法,直接将VPIE和约化配分函数比（RPFR）相联系,只需要通过理论计算获得两种物质的简谐振动频率,就能够得到非高压情况下该物质的VPIE。本文以水和硫镉矿（CdS）为例,详细介绍了如何计算蒸发和气化过程VPIE的方法,并指出了其在天体化学和矿床学中的一些潜在应用。  相似文献   

东南极拉斯曼丘陵镁铁质麻粒岩的变质作用演化   总被引：5，自引：4，他引：1  

周信  仝来喜  刘小汉  王彦斌  陈义兵 《岩石学报》2014,30(6):1731-1747

拉斯曼丘陵（Larsemann Hills）位于东南极普里兹构造带的中部,研究该区麻粒岩的变质作用演化对于理解普里兹带的构造属性至关重要。通过对该区含石榴石镁铁质麻粒岩转石详细的岩相学观察表明,峰期前进变质阶段矿物组合（M1）由角闪石+斜方辉石+单斜辉石+斜长石+黑云母+钛铁矿±石英±磁铁矿组成,其峰期矿物组合（M2）为石榴石+斜方辉石+单斜辉石+角闪石+钛铁矿±磁铁矿±石英,而代表后期与降压有关的叠加变质组合（M3）为斜方辉石+斜长石+单斜辉石+黑云母+钛铁矿±磁铁矿。矿物化学分析,结果显示其中石榴子石和斜方辉石具有弱的成分环带特征。利用THERMOCALC软件在NCFMASHTO体系下对该麻粒岩进行了详细的热力学模拟,结合传统温压计和平均温压计算结果,得出不同阶段温压条件分别为650~750℃/5.5~6.5kb （M1）,850~950℃/8~8.5kb （M2）,800~900℃/5.5~7.5kb （M3）。其变质作用演化为典型的峰期后近等温减压的（ITD）顺时针P-T轨迹。通过区域上镁铁质麻粒岩的对比分析,我们认为该镁铁质麻粒岩可能来源拉斯曼丘陵基岩露头。结合已有的年代学资料,表明该镁铁质麻粒岩的峰期变质事件可能对应于晚元古代格林威尔期构造事件,而后期退变质作用与早古生代的泛非期构造事件有关,意味着泛非期普里兹带可能是陆内造山带。  相似文献   

The relationship between apparent equilibrium temperature and closure temperature with application to oxygen isotope geospeedometry     

Huaiwei Ni 《中国地球化学学报》2014,33(2):125-130

Oxygen isotope fractionation between coexisting minerals in slowly cooled rocks conveys information about their cooling history. By using the fast grain boundary （FGB） model to simulate closed-system diffusive ex- change of oxygen isotopes between coexisting minerals, I show that the apparent equilibrium temperatures （Tae） by the mineral pair with the largest isotopic fractionation （PLIF） always lies between the closure temperatures （To） of those two minerals. Therefore, when the rate of oxygen diffusion and hence Tc for the PLIF chance to be comparable （such as in the case of quartz and magnetite）, Tae will serve as a good approximation of To regardless of variation in mineral proportions. The specialty of the PLIF in constraining Tac within their Tc range can be generalized to other stable isotope systems and element partitioning. By approximating Tc with Tac and inverting Dodson＇s equation, the cooling rate of plutonic or metamorphic rocks can be inferred.  相似文献   

Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions     

HAN Xunian  GUO Yafei  WANG Shiqiang  DENG Tianlong 《《地质学报》英文版》2014,88(Z1):331-332

正1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is  相似文献   

三元体系CaCl₂?SrCl₂?H₂O的相平衡及其在钙锶分离中的应用          下载免费PDF全文

韩海军  吉祥  陈烽雄  李家乐  黄军榜 《盐湖研究》2022,30(4)

采用等温溶解平衡法研究了三元体系CaCl₂?SrCl₂?H₂O温度从323.15 K到353.15 K范围内的相平衡。基于该三元体系多温下的相平衡数据,设计开展了实验室模拟南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。实验室模拟钙锶分离实验结果表明,在323.15 K下时分离一次固相产品中的钙锶摩尔比可以从25.46:1降至1.73:1,SrCl₂的回收率为52.47 %,所得一次固相产品在323.15 K下溶解并再次蒸发。钙和锶的摩尔比从1.73:1降至1.1:1,SrCl₂的回收率为78.67 %。  相似文献   

The functional evolution and system equilibrium of urban and rural territories   总被引：2，自引：2，他引：0  

Fan  Jie  Li  Sisi  Sun  Zhongrui  Guo  Rui  Zhou  Kan  Chen  Dong  Wu  Jianxiong 《地理学报(英文版)》2022,32(7):1203-1224

Journal of Geographical Sciences - The coordinated development of urban and rural territorial systems has long been a scientific issue of concern in geography and socioeconomic development in...  相似文献   

A distributed thermodynamic model for energy and mass balance computation: FEST–EWB     

Chiara Corbari  Giovanni Ravazzani  Marco Mancini 《水文研究》2011,25(9):1443-1452

  相似文献   

P–T–t evidence for mechanisms of vertical tectonic motion in a contractional orogen: north-western US and Canadian Cordillera     

Whitney  Miller  & Paterson 《Journal of Metamorphic Geology》1999,17(1):75-90

The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km^?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs.  相似文献   

Modelling river water temperature using deterministic,empirical, and hybrid formulations in a Mediterranean stream     

Rafael Marcé  Joan Armengol 《水文研究》2008,22(17):3418-3430

River water temperature is a common target of water quality models at the watershed scale, owing to its principal role in shaping biogeochemical processes and in stream ecology. Usually, models include physically‐based, deterministic formulations to calculate water temperatures from detailed meteorological information, which usually comes from meteorological stations located far from the river reaches. However, alternative empirical approaches have been proposed, that usually depend on air temperature as master variable. This study explored the performance of a semidistributed water quality application modelling river water temperature in a Mediterranean watershed, using three different approaches. First, a deterministic approach was used accounting for the different heat exchange components usually considered in water temperature models. Second, an empirical approximation was applied using the equilibrium temperature concept, assuming a linear relationship with air temperature. And third, a hybrid approach was constructed, in which the temperature equilibrium concept and the deterministic approach were combined. Results showed that the hybrid approach gave the best results, followed by the empirical approximation. The deterministic formulation gave the worst results. The hybrid approach not only fitted daily river water temperatures, but also adequately modelled the daily temperature range (maximum–minimum daily temperature). Other river water features directly dependent on water temperature, such as river intrusion depth in lentic systems (i.e. the depth at which the river inflow plunges to equilibrate density differences with lake water), were also correctly modelled even at hourly time steps. However, results for the different heat fluxes between river and atmosphere were very unrealistic. Although direct evidence of discrepancies between meteorological drivers measured at the meteorological stations and the actual river microclimate was not found, the use of models including empirical or hybrid formulations depending mainly on air temperature is recommended if only meteorological data from locations far from the river reaches are available. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献