达拉布特镁铁质岩的Sr-Nd同位素及微量元素地球化学   总被引：1，自引：0，他引：1  

杨瑞瑛  刘丛强  高桥和也  增田彰正 《地球学报》1997,18(Z1):92-94

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橄榄岩中尖晶石的O同位素继承性与晶体结构转换     

李一良  王峥嵘  郑永飞 《地球学报》1997,18(Z1):260-262

应用增量法计算的矿物对O同位素分馏曲线，得到正尖晶石-矿物对O同位素温度高于尖晶石在地幔中的熔点，而用反尖晶石-矿物对计算的O同位素温度低于尖晶石的熔点，较为合理。因此，地幔橄榄岩中镁铝尖晶石的O同位素组成可能继承了其母体反尖晶石特征，即使反结构尖晶石在发生相变作用变成正结构尖晶石时未发生O同位素再平衡。  相似文献   

Disequilibrium for Ca during growth of pelitic garnet   总被引：14，自引：1，他引：14  

C. B. CHERNOFF  & W. D. CARLSON 《Journal of Metamorphic Geology》1997,15(4):421-438

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.  相似文献   

A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland)   总被引：7，自引：0，他引：7  

C. MEYRE  C. DE CAPITANI  & J. H. PARTZSCH 《Journal of Metamorphic Geology》1997,15(6):687-700

A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi₂O₆), diopside (CaMgSi₂O₆) and hedenbergite (CaFeSi₂O₆) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H₂O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).  相似文献   

博斯腾湖的水盐平衡与矿化度   总被引：11，自引：5，他引：11  

成正才  李宇安 《干旱区地理》1997,20(3):43-49

博斯腾湖曾是中国内陆区最大的淡水湖，因人类活动影响约在１９６８年演变为微咸水湖。本文依据湖泊水平衡太矿化度基本原理，结合博斯滕湖实际，分析计算了该湖各个时期的水盐平衡与矿化度；经推地整理，提出了预测矿化度的计算式，经检验与实测值基本吻合。  相似文献   

锇粉中杂质元素分析方法研究   总被引：2，自引：0，他引：2  

孙亚莉  邹晓秋 《岩矿测试》1997,16(4):262-266

利用ＩＣＰ＿ＭＳ技术建立了锇粉中痕量杂质元素的分析方法。在浓ＨＮＯ３介质中，锇以ＯｓＯ４形式挥发除去，分离锇基体后，可直接测定的痕量元素达５０余种。取样量０．１ｇ，测定限为０．２～２４６ｎｇ／ｇ，可实现质量分数ｗ（Ｏｓ）为９９．９９９９％锇粉中杂质元素测定。结合ＩＣＰ＿ＡＥＳ测定Ｋ、Ｎａ、Ｃａ、Ｍｇ、Ａｌ、Ｆｅ、Ｓｉ和Ｐ，可实现锇粉原料及产品的纯度分析。  相似文献   

新疆阿拉尔花岗岩MFC过程的微量元素综合效应     

刘伟 《地质论评》1997,43(5):465-475

新疆阿拉尔花岗岩的微量元素比相关图显示了线性样点列与幂函数曲线形式的样点列相 复杂图型。该图型用简单混合或者单一结果分异模型都不能解释。本文建立了混合－结晶分异复合过程的微量元素综合效应模型。模型１：从初始混合线引起害虫函数曲线束形式的结晶分异线。特殊情况有结晶分异线简化为通过原点的直线束形式或者与初始混合线重合。  相似文献   

五台山西部狐狸山含金韧性剪切带的地球化学研究     

刘志宏  王安建  李晓峰  周继华 《吉林大学学报(地球科学版)》1996,(1)

狐狸山金矿区，在无蚀变作用参与的韧性变形过程中，岩石化学成分发生了明显的变化。但大多数微量元素含量变化不大，稀土元素配分模式基本不变，它们可以反映原岩的特点。蚀变糜棱岩型矿体与围岩相比，稀土配分模式、亲硫元素Ａｕ、Ａｇ、Ｃｕ和两性元素Ａｓ、Ｓｂ含量差别显著，尤其是Ａｕ含量，前者是后者的百倍～几万倍，金的成矿作用主要与韧性变形后期富金流体的蚀变作用关系密切。  相似文献   

华北地台南缘中元古代官道口群热水沉积硅质岩的地球化学特征   总被引：5，自引：0，他引：5       下载免费PDF全文

魏俊浩  王思源  吕国芳  潘振祥  马旭东 《地球科学》1996,(1)

在简要介绍了硅质岩基本地质特征的基础上，详细讨论了该套硅质岩的常量元素、微量元素以及氧同位素化学成分及组成．研究表明，该套硅质岩富集了与热水成因有关的Ａｇ、Ａｓ、Ｃｒ、Ｐｂ、Ｚｎ、Ｃｕ、Ｂ、Ｓｂ等微量元素和ＣａＯ、ＦｅＯ、Ｆｅ２Ｏ３等氧化物中常量元素，贫化了ＴｉＯ２、Ａｌ２Ｏ３、ＭｎＯ等氧化物中的常量元素．氧同位素组成及利用氧同位素估算的硅质岩的形成温度，均反映了热水沉积成因的特点  相似文献   

湖相介形虫壳的稳定同位素和微量元素在古气候研究中的应用   总被引：2，自引：3，他引：2  

夏娟娟 《第四纪研究》1996,16(4):345-352

本文介绍了测定实验室养殖的介形虫Candonarawsoni和水的氧同位素分馏系数，结果表明，这个种属的介形虫壳的氧同位素组成是它所生成环境水的氧同位素组成和水温的函数。因此，介形虫壳的氧同位素组成是一个很好的水化学环境指示计。本文研究了Candonarawsoni的脱壳温度范围，发现它可以在很宽温度范围内脱壳及生长新壳。由于季节温度变化很大，所以用介形虫壳的地球化学指标研究古环境的变化时，每个样品都要采集较多的个体介形虫壳，以使其分析结果能代表年平均温度。  相似文献