气相色谱指纹法在海上油污染源鉴别中的应用   总被引：4，自引：0，他引：4  

陈伟琪  张珞平 《海洋科学》2003,27(7):67-70

通过一个具体案例,探讨了气相色谱指纹法在海上油污染源鉴别中的应用。该鉴别方法基于样品的正构烷烃气相色谱指纹分析,选择既能表征油种固有特性,又受风化影响较小的正十七烷(n-C17)、正十八烷(n-C18)、姥鲛烷(phy)、植烷(phy)和正二十烷(n-C20)等特征烷烃作为判据,可信度大,而且整个操作流程短(一般不超过半天),较简便易行。  相似文献   

渤海、黄海、东海沉积物中矿物组合的研究   总被引：12，自引：2，他引：12  

陈丽蓉 《海洋科学》1989,13(2):1-8

本文对黄海、渤海、东海以及长江、黄河、辽河表层沉积物中的轻、重矿物进行了研究。分析资料表明,调查区内共有三种类型的矿物:陆源矿物、自生矿物和海底火山喷发形成的火山型矿物。根据轻、重矿物组合的差异,可把调查区分成8个矿物区。其物质来源主要为黄河与长江。黄河物质主要沉积在黄海、渤海;长江物质沉积在东海陆架区,而冲绳海槽则发现有海底火山喷发物质与浊流沉积。  相似文献   

台湾海峡表层沉积物中重矿物特征及其物质来源   总被引：15，自引：0，他引：15  

陈华胃 《台湾海峡》1993,12(2):136-144

台湾海峡重矿物平均分布0.95%,其分布由西岸向东岸递减;由北部经台湾浅滩朝粤东方向缓慢递减。碎屑矿物46种,以角闪石、绿帘石、磁铁矿、钛铁矿、褐铁矿和片状矿物为主,它们占重矿物含量的67%。据主要重矿物含量将海峡分成8个矿物组合区。碎屑矿物来自海峡两岸基岩,通过河流搬运入海,有部分片状矿物为海峡以北的物质随浙闽沿岸流进入海峡而沉积。其海绿石是台湾西岸、澎湖岛第三系或第四系含海绿石岩层剥蚀后搬运入海沉积而成的。台湾浅滩的残留沉积物为晚更新世低海面时期的河口滨海相沉积物。由于处在开放的海洋环境,至今没有接受现代沉积。残留沉积物中的磁铁矿、钛铁矿、锆石等重矿物相对富集,含量高于近源海域,有可能赋存浅海砂矿。  相似文献   

A technique for conducting seismic refraction experiments on the ocean bed using bottom shots     

R. E. Kirk  K. Robertson  R. B. Whitmarsh  P. R. Miles 《Marine Geophysical Researches》1991,13(2):153-160

A technique has been devised for firing arrays of bottom shots on the ocean bed in depths upto 4000 m or more. Ten kilogram explosive charges are dropped from the surface while the shooting ship is navigated acoustically. They are detonated at preset times by an electronic timer which initiates an electrical detonator, detonating cord and cast PETN/TNT explosive. Ranges to ocean bottom seismographs, and the shot instants, can be calculated from the arrival-time differences of the direct and surface-reflected water waves. The accuracy, which is dependent on water-depth and range, was better than 22 m in range and 14 msec in shot instant for our experiments.  相似文献   

耗散源函数及LAGFD-WAM海浪数值模式的改进   总被引：3，自引：0，他引：3       下载免费PDF全文

袁业立  华锋  潘增弟  孙乐涛 《海洋与湖沼》1993,24(4):367-376

本文是在LAGFD-WAM海浪模式方法基础上,根据破碎波统计理论给出了LAGFD耗散源函数形式。同时对LAGFD-WAM模式进行了改进并与WAM模式作了三种典型风场下的对比实验和实测结果检验,取得了较好的结果。  相似文献   

思林水电站通航建筑物高边坡稳定分析和评价     

徐力群  沈振中  俞凯加  吕军 《岩土力学》2008,29(Z1):42-46

应用ANSYS结构分析软件,模拟了思林水电站通航建筑物高边坡的地形、地质条件以及开挖的过程,建立边坡开挖的有限元计算分析模型,分析边坡在自然状态、分级开挖以及锚杆支护加固等工况下的应力、变形及其整体稳定性.定义单元的局部安全系数,得到了边坡开挖加固后稳定安全系数的分布.根据计算成果,指出现设计加固措施可以保证边坡稳定,无需增加其他工程措施.  相似文献   

Characteristics of Clay Minerals in the Northern South China Sea and Its Implications for Evolution of East Asian Monsoon since Miocene   总被引：3，自引：0，他引：3  

万世明  李安春  胥可辉  尹学明 《中国地质大学学报(英文版)》2008,19(1):23-37

Clay mineral assemblages, crystallinity, chemistry, and micromorphology of clay particles in sediments from ODP Site 1146 in the northern South China Sea (SCS) were analyzed, and used to trace sediment sources and obtain proxy records of the past changes in the East Asian monsoon climate since the Miocene, based on a multi-approach, including X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray spectrometry (SEM-EDS). Clay minerals consist mainly of illite and smectite, with associated chlorite and kaolinite. The illite at ODP Site 1146 has very well-to-well crystallinity, and smectite has moderate-to-poor crystallinity. In SEM the smectite particles at ODP Site 1146 often appear cauliflower-like, a typical micromorphology of volcanic smecites. The smectite at ODP Site 1146 is relatively rich in Si element, but poor in Fe, very similar to the smectite from the West Philippine Sea. In contrast, the chemical composition of illite at ODP Site 1146 has no obvious differences from those of the Loess plateau, Yellow River, Yangtze River, and Pearl River. A further study on sediment source indicates that smectite originates mainly from Luzon, kaolinite from the Pearl River, and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The clay mineral assemblages at ODP Site 1146 were not only controlled by continental eathering regimes surrounding the SCS, but also by the changing strength of the transport processes. The ratios of (illite+chlorite)/smectite at ODP Site 1146 were adopted as proxies for the East Asian monsoon evolution. Relatively higher ratios reflect strongly intensified winter monsoon relative to summer monsoon, in contrast, lower ratios indicate a strengthened summer monsoon relative to winter monsoon. The consistent variation of this clay proxy from those of Loess plateau, eolian deposition in the North Pacific, planktonic, benthic foraminifera, and black carbon in the SCS since 20 Ma shows that three profound shifts of the East Asian winter monsoon intensity, and aridity in the Asian inland and the intensity of winter monsoon relative to summer monsoon, occurred at about 15 Ma, 8 Ma, and the younger at about 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at 15 Ma, 8 Ma, and 3 Ma.  相似文献   

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature   总被引：1，自引：0，他引：1  

刘邓  杨小芬  王红梅  李继红  苏念 《中国地质大学学报(英文版)》2008,19(5):526-533

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.  相似文献   

江苏固城湖流域1951-2000年农业非点源氮、磷输移的数值模拟研究   总被引：1，自引：0，他引：1       下载免费PDF全文

黄智华  薛滨  逄勇 《第四纪研究》2008,28(4):674-682

选择位于长江下游的固城湖流域作为研究区域,基于分布式流域水文模型SWAT,采用数值模拟的手段,反演了1951～2000年流域农业非点源氮、磷的输移规律。模拟结果与实测值的一致性反映了模型的良好模拟能力。比较两个时段的模拟结果发现,1981～2000年,流域农业非点源氮、磷年平均浓度和输移量分别为:总氮0.82mg/L和411.88×10³kg/a,总磷0.084mg/L和43.04×10³kg/a;远高于1951～1960年的氮、磷年平均浓度和输移量分别为:总氮0.22mg/L和49.55×10³kg/a,总磷0.036mg/L和7.67×10³kg/a。模拟主要反映了流域下垫面条件和农作物耕作模式对农业非点源氮、磷浓度及输移量的影响。  相似文献   

河南桐柏县破山银矿和银洞坡金矿的硫同位素研究   总被引：1，自引：0，他引：1  

李红梅  魏俊浩  黄祥芝 《现代地质》2008,22(1):18-23

河南桐柏县围山城金银成矿带的破山银矿和银洞坡金矿位于河前庄背斜的轴部和两翼,围岩为歪头山岩组,矿体受地层和构造的双重控制。两个矿床的矿石硫同位素δ34S值变化范围很窄,位于-1.8‰～5.3‰之间,具塔式效应,与围岩的硫同位素组成类似,具有深源硫的特征,由混合总体筛分可推测围岩提供了大部分硫源,破山银矿δ34S∑S为2.8‰左右。同时赋矿围岩的Au、Ag含量远远高于地壳丰度,因此可推断成矿物质主要来源于围岩歪头山岩组。  相似文献