Groundwater transformation of a low-sulfur to a high-sulfur coal, the Harlem coal of the northern Appalachian basin     

L.L. Chyi 《International Journal of Coal Geology》1997,33(4):317-331

The Harlem coal is postulated to have been deposited in raised-bog settings. It was initially deposited as low-sulfur peat, but groundwater of a later origin altered portions of it to high-sulfur coal. The total sulfur content of 172 samples from 31 locations on a moisture- and ash-free basis have a quadrimodal distribution with two major modes at 0.75% S and 2.0%S. Multiple sampling and analyses at specific mine sites indicate that the addition of sulfur of a later origin occurred either laterally adjacent to sandstone channels or vertically adjacent to faults. Significant sulfur addition also occurred above clay partings at these sites. The original low-sulfur nature is preserved where the coal bed is isolated from descending groundwater by a thick impervious layer. Trace-element analyses show high concentrations of mobile elements such as Na and Mn in the high-sulfur coals.  相似文献   

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas     

Sharon S. Crowley  Peter D. Warwick  Leslie F. Ruppert  James Pontolillo 《International Journal of Coal Geology》1997,34(3-4)

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.  相似文献   

对煤中锗矿化若干问题的思考——以临沧锗矿为例   总被引：8，自引：0，他引：8  

胡瑞忠  毕献武 《矿物学报》1997,17(4):364-368

本文在综述煤中锗矿化国内外研究现状的基础上，以临沧锗矿为例，深入讨论了在煤系地层中形成超大型独立锗矿床的特殊条件。结果表明，煤是锗成矿极有利的围岩，煤能否富集锗主要取决于有无富锗流体与煤相互作用。  相似文献   

四川南部晚二叠世构造对煤类分布的影响     

袁培生 《四川地质学报》1997,(3)

深成煤化作用是川南地区煤化作用的主导因素，本文着重阐明了构造对煤类分布的影响。  相似文献   

南极中山站近岸海冰生态学研究Ⅲ.冰藻优势种的季节变化及其与冰下浮游植物的关系          下载免费PDF全文

何剑锋  陈波 《极地研究》1997,9(3):22-31

自１９９２年４月１２日至１２月３０日对中山站以西内拉峡湾海冰和冰下水柱中藻类优势种组成和丰度进行了测定。４月份和１１月中旬至１２月中旬冰柱和水柱（０～５０ｍ）藻类丰度高达１０８～１０９ｃｅｌｓ／ｍ２。冰藻的普遍或季节性优势种主要包括Ａｍｐｈｉｐｒｏｒａｋｊｅｌｍａｎｉ、Ｂｅｒｋｅｌｅｙａｒｕｔｉｌａｎｓ、Ｎａｖｉｃｕｌａｇｌａｃｉｅｉ、Ｎｉｔｚｓｃｈｉａｂａｒｋｌｅｙｉ、Ｎ．ｃｙｌｉｎｄｒｕｓ、Ｎ．ｌｅｃｏｉｎｔｅｉ和Ｎｉｔｚｓｃｈｉａｓｐ．。由于藻类结合入冰后自身的演替，春－夏季海冰剖面中所记录的优势种组成并不能准确反映冰底优势种的季节演替过程。从冰底和水表藻种组成的对比表明，两者仅在春末冰底冰藻水华期间具有较强的相似性。秋、春季冰底冰藻水华的形成以现场生长为主，夏初冰藻释放入水后对冰下浮游植物的播种作用不明显。  相似文献   

山东淄博地区晚古生代成煤环境演替     

王嘹亮  米家榕 《吉林大学学报(地球科学版)》1996,(3)

淄博地区本溪期—石千峰期沉积环境经历了障壁岛—泻湖—台地环境，三角洲环境，曲流河环境体系的演替。相应的泥炭形成环境有不稳定的局限泻湖泥炭坪，较开阔泻湖泥炭坪，中等稳定的开阔泻湖泥炭坪，三角洲平原分流河道两侧的泥炭沼泽，洪泛平原上的泥炭沼泽。成煤植物上，本溪期以Ｃｏｒｄａｉｔｅｓ，Ｌｅｐｉｄｏｄｅｎｄｒａｌｅｓ，Ｎｅｕｒｏｐｔｅｒｉｓ为主，太原期华夏植物群发展，Ｌｅｐｉｄｏｄｅｎｄｒｏｎ，Ｃｏｒｄａｉｔｅｓ继续发育，真蕨纲和种子蕨纲占越来越重要的地位。山西期以Ｏｄｏｎｔｏｐｔｅｒｉｓｓｐ．，Ａｎｎｕｌａｒｉａｏｒｉｅｎｔａｌｉｓ，Ｐｅｃｏｐｔｅｒｉｓｏｒｉｅｎｔａｌｉｓ，Ｐ．ｎｏｒｉｎｉ为主。自煤系形成至今，本区经历了海西印支期的普遍沉降埋藏、燕山期的普遍抬升局部断陷、喜山期的剥蚀、新构造运动期的差异沉降等阶段。古构造、古气候对本区成煤环境有重要的控制作用。  相似文献   

三角洲平原上网结河的发育与聚煤作用   总被引：4，自引：4，他引：4  

陈代钊  张鹏飞 《沉积学报》1996,14(3):103-112

龙潭组上段（２４＃煤顶板到１２＃煤）是盘县地区含煤最好的层段，对该区西北部本段地层的研究表明其中发育有网结河体系。河道沉积由多层叠置的鞋带状砂体组成，湿地沉积主要由菱铁质泥质岩夹薄层板状细砂岩（决口扇沉积）和煤组成。河流的发育和聚煤作用都显示幕式性，可能主要受海平面变化的控制。网结状河道被认为是海侵期对低位下切河谷充填过程中经侧向冲裂水道并相互连通形成的；稳定、连续的厚煤层发育于河道大范围废弃后的海侵晚期，其次是高水位早期。  相似文献   

煤中黄铁矿的成因研究   总被引：14，自引：0，他引：14  

唐跃刚  任德贻 《地质论评》1996,42(1):64-70

本文在系统地研究四川晚二叠世高硫煤中黄铁矿矿物学的基础上，运用微区电子探针、中子活化、Ｘ光电子能谱和硫同位素等多 种方法综合地研究煤中黄铁矿的结构、成分、价态及同位素等成因标型特征，对黄铁矿标型特征进行了成因探讨，有效地判别了成岩期形成的Ｉ型脉状黄铁矿及后生热液Ⅱ型脉状黄铁矿。同时提出直接沉淀系列（自形晶→集合→聚晶）和复杂成因（微粒、莓粒→圆球→结核→团块）等两大类成因演化模式。它不仅对不同类型  相似文献   

面向21世纪的煤化工   总被引：8，自引：0，他引：8  

魏贤勇  高晋生 《华北地质矿产杂志》1996,11(1):1-8

煤炭是中国的主要能源和资源，但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑，应该大力开发温和化高效煤的新工艺，使煤炭资源逐步由能源型利用转化为材料型利用，近年来，我们在煤的溶剂萃取，脱硫降灰机理，煤相关模型化合物反应，煤焦油中稠环芳香族化合物的分离精制，功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作，结合这些研究工作，本文介绍了煤化工的  相似文献   

印尼中加里曼丹波拉湾煤勘探区的构造解析     

杨雄庭  王泽安 《湖南地质》1996,15(4):234-238

本文从区域构造背景出发，根据波拉湾煤勘探区地表及钻孔资料综合分析，建立了逆冲断层Ｆ１、Ｆ２及其配套的ｆ１、ｆ２……构造，理顺了错综复杂的构造格局，将推覆构造理论成功地用于援外生产实践。  相似文献