Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field   总被引：2，自引：2，他引：2  

LAI Xingyun  YU Bingsong  CHEN Junyuan  CHEN Xiaolin  LIU Jianqing  MEI Mingxiang  JING Weiguang & CHENG Suhua School of Earth Sciences  Mineral Resources  China University of Geosciences  Beijing  China  Key Laboratory of Lithospheric Tectonics  Deep-level Process  Exploration of Ministry of Education  Beijing  China 《中国科学D辑(英文版)》2005,48(1):21-31

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,  相似文献   

Petrographic Characteristics and Alteration Geochemistry of Granite-hosted Tungsten Mineralization at Degana, NW India     

Pankaj K. Srivastava  Sukhchain 《Resource Geology》2005,55(4):373-384

Abstract. Vein type tungsten mineralization at Degana is genetically and spatially associated with the Degana Granite. The deposit is characterized by pervasive wall rock alteration around the mineralized quartz veins. Laterally three different alteration zones, greisen, silicification and potassic zones, are marked based on the field features, mineral assemblages and geo-chemical characteristics. In the present paper, systematic mineralogical and chemical variation in these alteration zones is reported. Thick mono-mineralic (zinnwaldite) selvages around the veins characterize the deposit. Plagioclase and alkali feldspar are low in the greisen zones while K-feldspar shows more increase than plagioclase in the potassic zone. Quartz is uniformly high in all the alteration zones, but it shows an anomalous value in the silicification zone. Al₂O₃ concentration shows initial depletion in greisen zone with gradual increase away from the contact. MgO and FeO are higher in greisen zone than silicification and potassic zones. The potassic zone is characterized by the depletion of Na₂O and higher value of K₂O.
The common presence of topaz and fluorite as both primary and secondary minerals and fluorine-bearing micas suggest fluorine partitioning in substantial amount between granitic melt and coexisting aqueous fluid phase and higher HF activity during the evolution of hydrothermal fluid. The mutual relationship of the fluorine minerals (topaz and fluorite) in the different alteration zones suggests an increase in the Ca²⁺ activity and decrease of H+ activity during the fluid evolution from greisenization towards alkali-metasomatised granite and the fluid is assumed to change from low to high activity ratio of Ca²⁺/H+.  相似文献   

An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan     

Yasumasa Ogawa  Naotatsu Shikazono  Daizo Ishiyama  Hinako Sato  Toshio Mizuta 《Mineralium Deposita》2005,39(8):813-821

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz  相似文献   

Late Quaternary lake evolution in the Gaxun Nur basin,central Gobi Desert,China, based on quartz OSL and K‐feldspar pIRIR dating of paleoshorelines     

《第四纪科学杂志》2017,32(3):347-361

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Sedimentary evidence and luminescence and ESR dating of Early Pleistocene high lake levels of Megalake Tengger,northwestern China     

Fan Yuxin  Li Zhenjun  Yang Guangliang  Yi Shuangwen  Zhang Qingsong  Liu Wenhao  Mou Xuesong 《第四纪科学杂志》2020,35(8):994-1006

The timing of high lake-level stands during the Late Pleistocene in western China remains controversial. Here we report new results from Megalake Tengger based on a study of palaeo-shorelines and a drill core from Baijian Lake in the northwestern Tengger Desert. Multiple dating methods, based on luminescence signals (quartz optically stimulated luminescence, K-feldspar post infrared-infrared stimulated luminescence) and electron spin resonance signals of quartz, were used to date beach sands from palaeo-shoreline profiles at altitudes of ~1310 m (+20 m above lake level), ~1320 m (+30 m) and ~1350 m (+60 m), and from the top 20 m of sandy sediments from the drill core obtained from the modern beach of Baijian Lake. The dating results show that high lake-level stands associated with the previously reported Megalake Tengger (~1310–1320 m) occurred during the late Early to Middle Pleistocene, which is much earlier than previously reported. In addition, no geomorphological evidence of shorelines and sedimentary evidence from the drill core profile were found to support the previously reported Late Pleistocene lake levels. Our results indicate that the exact age of the previously reported ‘high lake level event’ in a large part of northwestern China during the Late Pleistocene needs to be re-evaluated.  相似文献   

藏南马扎拉金锑矿床围岩蚀变及矿化特征     

代作文  李光明  丁俊  李应栩  董磊  黄勇  曹华文 《地质论评》2016,62(S1):27-28

马扎拉金锑矿位于西藏自治区山南地区措美县东南部古堆乡,东临隆子县,南近错那县,区域上位于藏南拆离断裂（陈智梁等,1996）以北的特提斯喜马拉雅（或称特提斯喜马拉雅）褶皱造山带（许志琴等,2006）南部,属于隆子逆冲推覆断裂的前缘。自2014年开始,成都地质调查中心作为扎西康整装勘查的主要实施单位接受了西藏雪域矿业开发有限公司的委托,在矿区开展地质找矿工作,现已基本查明了金锑矿体围岩蚀变和矿化特征。  相似文献   

云南富宁县水合口矿化蚀变信息提取和找矿预测     

刘峰  朱杰勇  白光顺  孙滨 《矿产与地质》2016,(3):450-454

云南富宁水合口金矿位于滇东南文山―富宁成矿带,属于著名的滇黔桂"金三角"地区。利用landsat 8OLI遥感影像对研究区进行1∶100 000矿化蚀变信息提取,结合区域地质和化探异常等多元信息进行找矿预测,表明矿化蚀变、断裂构造交汇处和地球化学异常空间叠加部位为有利找矿地区,圈定了5个找矿远景区,为研究区开展下一步找矿提供了科学依据。  相似文献   

兴蒙造山带—华北克拉通地球化学走廊带沉积物主成分的含量与空间分布研究     

唐坤  王学求  迟清华 《地球学报》2016,37(6):733-744

选取兴蒙造山带—华北克拉通地球化学走廊带上沉积物的SiO_2、Al_2O_3、CaO、MgO、Na_2O、K_2O、TFe_2O_3、FeO、TiO_2、MnO、P_2O_5、CO_2、H_2O~+、pH十四个指标,研究其在不同二级构造单元、地理景观、土壤类型、降雨量等级下的含量与空间分布特征,并讨论该地球化学走廊带上化学蚀变指数。结果表明:在兴蒙造山带—华北克拉通地球化学走廊带上,作为沉积物主体的SiO_2、Al_2O_3两者含量为明显负相关而空间分布表现出此消彼长的特征;CaO、MgO、CO_2高含量分布区则与碳酸盐岩地层或含碳酸盐矿物的土壤有关,而MgO的高含量还与走廊带上镁铁质基性-超基性岩有一定关系,表明了这三个指标的高含量受特定岩性或矿物的影响较大;Na_2O、K_2O含量除了受继承的基岩影响外,还受到后期的风化作用和气候及自身地球化学性质等复杂因素综合影响,对Na_2O来说尤为如此;TFe_2O_3、MnO、TiO_2、P_2O_5相对于在地质背景复杂地段,经过冲积平原的沉积物混匀后,含量差异更小;相对干冷的内蒙古半干旱草原的气候条件有利于FeO存在,使得其相对燕山地区含量差异较TFe_2O_3要小,在章丘以南相对温暖湿润地区更易被氧化而导致其含量整体较低;北方干冷气候条件下,沉积物H_2O~+含量普遍较低,局部高含量位于碳酸盐岩地层或第四系分布区;走廊带上的pH值反映了沉积物偏碱性的特征,而在章丘以南的地区随着降雨量的增加,相对温暖湿润的气候条件,沉积物pH值表现为中性-偏弱酸性;兴蒙造山带—华北克拉通地球化学走廊带沉积物的CIA值反映出在寒冷、干燥气候条件下低等的化学风化程度,兴蒙造山带沉积物平均风化程度相对华北克拉通沉积物的平均风化程度差异变化相对要小,显示兴蒙造山带的降雨量与温度等风化影响因素变化较小。作为反映元素的地球化学亲和性的量化指标,离子电位可以更好地帮助理解沉积物元素的含量和空间分布差异。  相似文献   

新疆博格达山北麓白杨河剖面页岩地球化学特征及其地质意义     

赵仕华 《岩石矿物学杂志》2016,35(2):255-264

通过博格达山北麓白杨河剖面芦草沟组页岩的地球化学特征的综合研究,讨论了芦草沟组页岩的元素富集特征和沉积环境以及源区物源特征和构造背景。结果表明:1研究区页岩P元素极为富集,这受控于页岩中凝灰质火山灰夹层的广泛发育;2对比于世界页岩微量元素分布,白杨河页岩相对富集Li、B、Pr、Tb、Dy、Ho、Er、Tm和Lu元素,其他元素相对亏损;3白杨河剖面页岩地化参数揭示芦草沟组自下而上气候由温湿向干热转变,进而引起水体由淡水向咸水的转变和还原程度的进一步加强;4物源区遭受低级-中等风化程度,物源类型主要为长英质火成岩,其次为铁镁质火成岩;5物源区大地构造背景以大陆岛弧-活动大陆边缘构造背景为主。  相似文献   

基于变动范围法(RVA)的信江水文改变及生态流量研究   总被引：2，自引：0，他引：2       下载免费PDF全文

刘贵花  朱婧瑄  熊梦雅  王点  齐述华 《水文》2016,36(1):51-57

选择信江下游梅港站1950~2010年日径流量,根据流域大型水库界牌枢纽运行时间将梅港站径流序列分为建库前(1953~2001)和建库后(2002~2010)两个时段。采用变动范围法(Range of Variability Approach,简称:RVA)分析水库运行对下游梅港站流域生态水文指标改变度,并分析了信江下游生态流量。研究表明:33个水文指标有22个发生中高度改变,11个指标发生低度改变,其水文综合改变度为0.51,属于中度改变;梅港站生态流量值均在RVA阈值内,基本能够保持河流稳定流量,但2月、7~9月及12月河道生态流量大于RVA下限。可适量增大水库下泄水量,降低对下游河段生态系统的威胁。  相似文献