全文获取类型
收费全文 | 1053篇 |
免费 | 291篇 |
国内免费 | 603篇 |
专业分类
测绘学 | 8篇 |
大气科学 | 23篇 |
地球物理 | 116篇 |
地质学 | 1499篇 |
海洋学 | 130篇 |
天文学 | 5篇 |
综合类 | 119篇 |
自然地理 | 47篇 |
出版年
2024年 | 9篇 |
2023年 | 29篇 |
2022年 | 33篇 |
2021年 | 50篇 |
2020年 | 50篇 |
2019年 | 67篇 |
2018年 | 58篇 |
2017年 | 62篇 |
2016年 | 84篇 |
2015年 | 82篇 |
2014年 | 143篇 |
2013年 | 126篇 |
2012年 | 158篇 |
2011年 | 117篇 |
2010年 | 102篇 |
2009年 | 75篇 |
2008年 | 85篇 |
2007年 | 63篇 |
2006年 | 71篇 |
2005年 | 59篇 |
2004年 | 46篇 |
2003年 | 41篇 |
2002年 | 43篇 |
2001年 | 24篇 |
2000年 | 38篇 |
1999年 | 29篇 |
1998年 | 23篇 |
1997年 | 37篇 |
1996年 | 23篇 |
1995年 | 18篇 |
1994年 | 6篇 |
1993年 | 24篇 |
1992年 | 15篇 |
1991年 | 12篇 |
1990年 | 13篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1947条查询结果,搜索用时 31 毫秒
11.
应用^57Fe穆斯堡尔谱学的方法研究了四个不同生长期合浦珠母贝铁的化学状态和Fe^2 /Fe^3 的值,它们的Fe^2 和Fe^3 的相对含量分别为4.1%~29.4%和76.6%~95.9%,Fe^2 /Fe^3 值的变化为0.043~0.42。3个月龄的Fe^2 /Fe^3 值大于10个月龄,从10个月龄到22个月龄的Fe^2 /Fe^3 值呈增加的趋势,这可能反映了不同生长期合浦珠母贝对不同价态的铁的需求。 相似文献
12.
黄土中游离氧化铁是指示夏季风的替代性气候指标之一。使用经典的CBD法提取游离氧化铁实验过程烦琐,而且实验条件不同对浸提结果影响很大。本实验采用盐酸羟胺-盐酸体系在不同的温度下浸提黄土中的游离氧化铁。实验结果表明:温度对实验结果影响最大,盐酸浓度次之。与经典的CBD法进行对比,在一定的条件下可以代替CBD法,从而简化试验。 相似文献
13.
Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis 总被引:1,自引:1,他引:1
The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll
a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio
region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear
seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal
succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes
and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by
iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared
to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation
in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has
similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton
biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results
of difference in iron bioavailability in both regions.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
14.
利用Minolta CM-2002光谱光度计对南黄海陆架136个短柱样品20~25cm段的沉积物进行了颜色反射率数据测量,通过化学元素、粒度、磁化率等来确定影响沉积物颜色反射率变化的成分和因素,介绍了反射率光谱的一阶导数和因子分析的方法。分析结果表明,南黄海陆架沉积物颜色反射率受控于沉积物中的铁氧化物、有机质以及粘土矿物和钙质生物碎屑含量。主因子F1指示氧化环境,并与陆源物质相关,F2指示弱氧化环境,F3指示弱还原环境,主因子的波长范围分别是405~445 nm和495~595 nm,605~695 nm,445~485 nm。 相似文献
15.
16.
17.
Stephen B. Castor 《Resource Geology》2008,58(4):337-347
Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor. 相似文献
18.
酸性矿山废水中生物成因次生高铁矿物的形成及环境工程意义 总被引:10,自引:1,他引:9
酸性矿山废水(acid mine drainage,AMD)是一类pH低并含有大量有毒金属元素的废水。AMD及受其影响的环境中次生高铁矿物类型主要包括羟基硫酸高铁矿物(如黄铁矾和施威特曼石等)和一些含水氧化铁矿物(如针铁矿和水铁矿等),而且这些矿物在不同条件下会发生相转变,如施氏矿物向针铁矿或黄铁矾矿物相转化。基于酸性环境中生物成因次生矿物的形成会"自然钝化"或"清除"废水中铁和有毒金属这一现象所获得的启示,提出利用这些矿物作为环境吸附材料去除地下水中砷,不但吸附量大(如施氏矿物对As的吸附可高达120mg/g),而且可直接吸附As(III),还几乎不受地下水中其他元素影响。利用AMD环境中羟基硫酸高铁矿物形成的原理,可将其应用于AMD石灰中和主动处理系统中,构成"强化微生物氧化诱导成矿-石灰中和"的联合主动处理系统,以提高AMD处理效果和降低石灰用量。利用微生物强化氧化与次生矿物晶体不断生长的原理构筑生物渗透性反应墙(PRB)并和石灰石渗透沟渠耦联,形成新型的AMD联合被动处理系统,这将有助于大幅度增加处理系统的寿命和处理效率。此外,文中还探讨了上述生物成因矿物形成在AMD和地下水处理方面应用的优点以及今后需要继续研究的问题。 相似文献
19.
Chantal Guillard Hervé Delprat Can Hoang-van Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed. 相似文献
20.
Eric A. Betterton 《Journal of Atmospheric Chemistry》1993,17(4):307-324
An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)]
T
(2.5–5.0×10–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K
7 andK
8 can be interpreted as intrinsic constants for the coordination of HSO
3
–
by FeOH2+ and Fe3+, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×106 M–1 s–1 which is comparable to rate of reaction of FeOH2+ with SO
4
2–
. However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected. 相似文献