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91.
休瓦促钨钼矿区位于义敦地体南段,是该区域唯一存在晚三叠世、晚白垩世和新生代酸性侵入体直接接触形成复式岩体的矿区.目前尚未对该复式岩体的岩浆演化过程开展过系统深入研究,限制了对该矿区及区域构造事件和岩浆演化的认识.本文通过系统梳理前人研究成果,开展东矿段黑云母花岗岩,西矿段二长花岗岩、花岗斑岩地质年代学和地球化学分析,探... 相似文献
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随着同位素测试技术的发展,高温下重同位素分馏逐渐运用到地球化学领域.为了探索岩浆演化过程中是否会发生Cu同位素分馏,文章对西藏驱龙斑岩铜矿床同来源、不同演化阶段的两套岩浆岩(闪长岩包体和花岗闪长岩)进行了Cu同位素测试.测试结果显示,闪长岩包体的δ65Cu值集中在+0.08‰-+0.35‰之间,平均值为+0.25‰,花岗闪长岩的δ65Cu值为+0.42‰~+0.87‰,平均值为+0.60‰.△65Cu花岗闪长岩-闪长岩包体≈+0.4‰,并且δ65Cu值与样品w(SiO)变化存在一定的正相关性.结合地质学及同位素方面考虑,花岗闪长岩和闪长岩包体的Cu同位素组成差异可能是岩浆演化过程中发生了Cu同位素分馏所致.在驱龙矿区中新世岩浆演化过程中,随着岩浆去气作用,63Cu随HS-、Cl-等挥发分优先进入气相,导致残留岩浆熔体相对富集65Cu.此外,两者的Cu同位素组成差异也可能与岩浆演化过程中斜长石、角闪石、黑云母等矿物的不断结晶分离有关,矿物结晶分离时,基性矿物富集63Cu,而残余熔体则富集65Cu. 相似文献
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In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation. 相似文献
96.
LI Jijun LU Shuangfang WU Wei XUE Haitao XU Qingxi GENG Jie YU Yinghua 《《地质学报》英文版》2011,85(5):1203-1210
In order to discuss the role and influence of water during the generation of natural gas, the participation mechanism of water during the evolution of organic matter and its influences were summarized. In addition, we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system, which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter. The models were calibrated and then applied to the northeastern Sichuan Basin. By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions, several results were proved: (1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water; (2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices. 相似文献
97.
随着分析技术的进步,δ13C观测在全球碳循环研究中越来越受到重视。在讨论关于碳循环中δ13C的Suess效应、分布特征和同位素分馏等基本概念的基础上,结合现有的观测事实,介绍应用δ13C辨别碳的源汇问题的方法,通过比较不同KeelingPlot方法分析该方法在研究大气CO2背景特征中的意义。着重讨论δ13C在研究大气C... 相似文献
98.
Application of stable isotope techniques in studies of carbon and nitrogen biogeochemical cycles of ecosystem 总被引:1,自引:1,他引:0
Zhigao Sun Xiaojie Mou Xinhua Li Lingling Wang Hongli Song Huanhuan Jiang 《中国地理科学(英文版)》2011,21(2):129-148
Stable isotope techniques have been proved useful as tools for studying the carbon (C) and nitrogen (N) biogeochemical cycles of ecosystem. This paper firstly introduced the basic principles and the distribution characteristics of stable isotope, then reviewed the recent advances and applications of stable isotope in the C and N biogeochemical cycles of ecosystem. By applying the 13 C natural abundance technique, ecologists are able to understand the photosynthetic path and CO 2 fixation of plants, the CO 2 exchange and C balance status of ecosystem, the composition, distribution and turnover of soil organic C and the sources of organic matter in food webs, while by using the 13 C labeled technique, the effects of elevated CO 2 on the C processes of ecosystem and the sources and fate of organic matter in ecosystem can be revealed in detail. Differently, by applying the 15 N natural abundance technique, ecologists are able to analyze the biological N 2 -fixation, the N sources of ecosystem, the N transformation processes of ecosystem and the N trophic status in food webs, while by using the 15 N labeled technique, the sources, transformation and fate of N in ecosystem and the effects of N input on the ecosystem can be investigated in depth. The applications of both C and N isotope natural abundance and labeled techniques, combined with the elemental, other isotope ( 34 S) and molecular biomarker information, will be more propitious to the investigation of C and N cycle mechanisms. Finally, this paper concluded the problems existed in current researches, and put forward the perspective of stable isotope techniques in the studies on C and N biogeochemical cycles of ecosystem in the future. 相似文献
99.
本文对广东湛江湖光岩地区厚度分别为4 m和7 m的两个不同喷发时代玄武岩形成的风化壳样品进行Fe同位素分析,分析结果显示:厚度4m风化壳样品Fe同位素组成δ57Fe范围为0.17‰~0.57‰;厚度7 m风化壳样品Fe同位素组成δ57Fe范围为0.20‰~0.68‰,相对于标准物质IRMM-014,不同深度风化壳样品均显示Fe的重同位素富集.两风化壳剖面自下而上,随风化程度增大,风化壳样品中Fe同位素分馏程度也呈现逐渐增大的趋势,表明风化壳样品中Fe的重同位素富集趋势与风化壳的发育程度正相关,风化壳土壤中Fe同位素组成是反映土壤风化程度的指标.另一方面,风化过程可将地球外部圈层(岩石圈、水圈、生物圈)有机结合起来,风化壳土壤Fe同位素组成变化是表生植物和水淋滤共同作用的结果,对化学风化过程中Fe同位素研究,将会极大地补充表生过程中同位素地球化学的知识,同时Fe同位素可作为表生过程中物质的循环、环境的变化等过程中有力的示踪/指示技术手段加以应用. 相似文献
100.
Isabel Margarida Horta Ribeiro Antunes Ana Margarida Ribeiro Neiva João Manuel Farinha Ramos Paulo Bravo Silva Maria Manuela Vinha Guerreiro Silva Fernando Corfu 《Chemie der Erde / Geochemistry》2013
In the Segura area, Variscan S-type granites, aplite veins and lepidolite-subtype granitic aplite-pegmatite veins intruded the Cambrian schist-metagraywacke complex. The granites are syn D3. Aplite veins also intruded the granites. Two-mica granite and muscovite granite have similar ages of 311.0 ± 0.5 Ma and 312.9 ± 2.0 Ma but are not genetically related, as indicated by their geochemical characteristics and (87Sr/86Sr)311 values. They correspond to distinct pulses of magma derived by partial melting of heterogeneous metapelitic rocks. Major and trace elements suggest fractionation trends for: (a) muscovite granite and aplite veins; (b) two-mica granite and lepidolite-subtype aplite-pegmatite veins, but with a gap in most of these trends. Least square analysis for major elements, and modeling of trace elements, indicate that the aplite veins were derived from the muscovite granite magma by fractional crystallization of quartz, plagioclase, K-feldspar and ilmenite. This is supported by the similar (87Sr/86Sr)311 and δ18O values and the behavior of P2O5 in K-feldspar and albite. The decrease in (87Sr/86Sr)311 and strong increase (1.6‰) in δ18O from two-mica granite to lepidolite-subtype aplite-pegmatite veins, and the behaviors of Ca, Mn and F of hydroxylapatite indicate that these veins are not related to the two-mica granite. 相似文献