Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

Spinel–sapphirine–quartz bearing composite inclusion within garnet from an ultrahigh-temperature pelitic granulite: Implications for metamorphic history and P–T path     

Toshiaki Tsunogae  M. Santosh 《Lithos》2006,92(3-4):524-536

We report here a multiphase mineral inclusion composed of quartz, plagioclase, K-feldspar, sapphirine, spinel, orthopyroxene, and biotite, in porphyroblastic garnet within a pelitic granulite from Rajapalaiyam in the Madurai Granulite Block, southern India. In this unique textural association, hitherto unreported in previous studies, sapphirine shows four occurrences: (1) as anhedral mineral between spinel and quartz (Spr-1), (2) subhedral to euhedral needles mantled by quartz (Spr-2), (3) subhedral to anhedral mineral in orthopyroxene, and (4) isolated inclusion with quartz (Spr-4). Spr-1, Spr-2, and Spr-4 show direct grain contact with quartz, providing evidence for ultrahigh-temperature (UHT) metamorphism at temperatures exceeding 1000 °C. Associated orthopyroxene shows high Mg/(Fe + Mg) ratio ( 0.75) and Al₂O₃ content (up to 9.6 wt.%), also suggesting T > 1050 °C and P > 10 kbar during peak metamorphism.

Coarse spinel (Spl-1) with irregular grain morphology and adjacent quartz grains are separated by thin films of Spr-1 and K-feldspar, suggesting that Spl-1 and quartz were in equilibrium before the stability of Spr-1 + quartz. This texture implies that the P–T conditions of the rock shifted from the stability field of spinel + quartz to sapphirine + quartz. Petrogenetic grid considerations based on available data from the FMAS system favour exhumation along a counterclockwise P–T trajectory. The irregular shape of the inclusion and chemistry of the inclusion minerals are markedly different from the matrix phases suggesting the possibility that the inclusion minerals could have equilibrated from cordierite-bearing silicate-melt pockets during the garnet growth at extreme UHT conditions.  相似文献   

A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt     

沈上越冯庆来  魏启荣张志斌 张虎 《中国地球化学学报》2006,25(3):216-222

1IntroductionThe northern segment of the South LancangjiangBelt refers to the terrain about200km east of theYunxian-Lingcang granite in the South LancangjiangBelt(Fig.1).During the seventh Five-Year Plan peri-od,Mo Xuanxue et al.(1993)undertook the resear…  相似文献   

The chromite deposits associated with ophiolite complexes, Southeastern Desert, Egypt： Petrological and geochemical characteristics and mineralization     

Gehad M. Saleh 《中国地球化学学报》2006,25(4):307-317

1 Introduction The association of massive Fe-Ni-Cu sulfides andchromite is a very unusual feature of podiformchromitites occurring in mantle tectonites of ophioliticcomplexes. It has only been described in theSoutheastern Desert, Egypt, where sulfides a…  相似文献   

一种实现依比例街区自动合并的算法     

朱蕊  周滨  邰茜 《测绘学院学报》2005,22(1):58-61

针对依比例街区的图形特征，介绍了一种实现街区自动合并的有效算法，即利用数学形态学和模式识别对栅格数据进行追踪，然后提取街区轮廓线，编辑后就得到最终合并的街区。  相似文献   

大别山造山带前陆深地震反射剖面   总被引：18，自引：0，他引：18       下载免费PDF全文

董树文 高锐李秋生  刘晓春钱桂华黄东定  匡朝阳李三忠管烨  白金贺日政  李朋武 《地质学报》2005,79(5):595-601

在大别山南部和扬子地块前陆实施的深地震反射剖面(140 km)揭示出大别山造山带前陆地壳的精细结构。总体北倾的地壳内部结构与向北缓倾的叠瓦状莫霍面反射揭示出扬子陆块向北俯冲的行迹。莫霍面向北插入大别山造山带下与南大别山地壳内南倾反射震相叠置,构成交叉反射图像,刻画出扬子前陆与大别山造山带的碰撞构造面貌。  相似文献   

油气化探数据库系统     

赵跃伟  汤玉平  李沙园  任春 《物探与化探》2005,29(1):53-56

建立油气化探数据库是油气化探信息资源共享、科学管理、宏观决策的基础和依据,是油气化探数据处理及异常评价的基础。本系统采用动态自适应结构,收集、录入了几十年来我国油气化探数据,可以完成油气化探数据登录、管理、浏览、检索、报表、数据预处理。文章中论述了油气化探数据库的结构、特点及功能,反映了油气化探数据库研究领域的新进展和研究水平。  相似文献   

盐城凹陷朱家墩气田综合化探异常及其地质意义   总被引：1，自引：1，他引：1  

王国建  邓平  石美癸 《物探与化探》2005,29(2):131-134

用酸解烃、顶空气、吸附丝及甲烷碳同位素方法对盐城凹陷朱家墩气田进行了综合油气化探测量,建立了该区这几种方法指标的化探异常模式,在总结已知油气区异常规律的基础上,优化化探方法及指标组合并运用于未知区域,圈定了油气远景靶区。探讨了地表化探异常与石油地质特征的关系,为化探异常的地质解释提供了可借鉴的思路。  相似文献   

赣南银坑山铀矿点地球化学特征及其找矿意义     

张万良 《物探与化探》2005,29(3):220-223

银坑山铀矿点位于赣南九龙嶂火山盆地南东边缘,矿体呈脉状,水云母化、赤铁矿化明显。与围岩相比,矿石的Al₂O₃、SiO₂含量降低,Fe₂O₃(FeO)、MnO、CaO、S、Cl呈富集趋势,Mo、Ag、Th为主要伴生组分。从矿化蚀变组合特征看,银坑山矿点属岩浆热液型,且位于岩浆热液成矿系统的上部,深部具成矿前景。  相似文献   

陈家杖子金矿地球化学特征及其指示意义     

王喜宽  王宝林  廖蕾  段吉学  龙文华  张宝 《物探与化探》2005,29(4):308-311,315

陈家杖子金矿是通过1∶5万化探工作发现的斑岩型金多金属矿, 其地球化学异常特征可作为在该区寻找类似矿床标志。该矿东部还有形成多金属矿的潜力。在此类土壤覆盖区应采用土壤测量。该金矿的发现反映了在我国中西部地区利用常规方法来发现新矿床的巨大潜力。  相似文献