Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28   总被引：1，自引：0，他引：1  

Jean S. Kane 《Geostandards and Geoanalytical Research》2002,26(1):7-29

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.  相似文献   

火焰原子吸收法测定化探样品中的银铜铅锌     

潘自平 《贵州地质》2003,20(3):192-194

样品经硝酸、氢氟酸、高氯酸分解，制成硝酸溶液，经巯基棉层析柱过滤富集Ag，并用2mol／LHBr溶液洗脱，用火焰原子吸收法测定洗脱液中的Ag和滤液中的Cu，Pb，Zn。用该法测定化探样品中银和铜铅锌，检出限低，结果准确度和精密度均令人满意。  相似文献   

大港油田盐山-庆云地区油气运移富集规律的研究     

何政才  姚锦其  董树政  王国华 《矿产与地质》2003,17(1):49-53

盐山-庆云地区具多凸多凹、地质条件复杂、多向供油（气）的特点。油气化探异常发育不平衡，具有成带分布、局部富集的特征。西部主要的轻烃（CH4）异常强，东部则是重烃（C2H6、C3H8）异常最发育，由西向东轻烃逐渐下降，重烃不断增加，非烃指标（Hg、△C）异常与重烃异常基本相拟，Ks、Fe^2 异常规律不明显。根据烃类指标的分带性，轻、重烃异常规律和富集特征划分为气显示带，油显示带和油气显示带。中部地区的即油气显示带是油气最有远景的地段。  相似文献   

油气化探中甲烷碳同位素应用、存在问题与对策研究   总被引：5，自引：2，他引：5  

黎绍杰 《矿产与地质》2003,17(1):54-58

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。  相似文献   

全球地球化学填图   总被引：19，自引：10，他引：19       下载免费PDF全文

谢学锦 《中国地质》2003,30(1):1-9

作指出了1973年至今世界上50余项地球化学填图计划中普遍存在的缺陷大都涉及分析问题。1988－1992年实施的国际地质对比计划IGCP259项目旨在使全世界地球化学填图方法标准化。在此项目中对分析问题提出了若干规定，主要是要求今后的填图计划应统一分析71种元素，痕量及超痕量元素的检出限必须低于相应的地壳丰度值及采用中国的GSD和加拿大的STSD标样系列，以使全球数据可以对比，在其后开始延续至今的全球地球化学填图计划IGCP360，旨在用极低密度采样早日覆盖全球大陆，讨论了正在实行的两种极低密度采样方案，并提出通过极低密度采集地极少量样品示范性实现IGCP259项目对分析要求的具体建议。  相似文献   

矿床地球化学预测方法——以甘肃省地球化学块体为例   总被引：7，自引：1，他引：7       下载免费PDF全文

李通国  李文胜刘建宏赵彦庆白云来 《中国地质》2003,30(2):192-198

笔者应用地球化学块体理论，对全省化探数据进行综合分析处理。圈出14种元素地球化学块体173个，其中地球化学巨省25个，地球化学省148个。总结地球化学块体在空间上的分布规律。通过研究地球化学块体内部结构，追踪大型至特大型矿床可能存在的地点。利用块体内已探明的金属储量，计算其成矿率，预测其他元素或其他地段的金属资源总量，固定成矿远景区，确定巨型矿床找矿靶区7处。通过不同级别地球化学块体与成矿区带的关系研究，对重要地球化学块体、子块体与成矿亚带、矿田进行对比，对地球化学块体内区域矿产资源潜力作出评价。  相似文献   

滇东铂钯地球化学勘查及异常评价   总被引：4，自引：1，他引：4  

夏庆霖  陈永清  赵鹏大 《地质通报》2003,22(9):704-707

利用滇东地区1∶20万水系沉积物化探的组合副样,按8km×8km面积重新组合,采用C-OES法定量分析其Pt、Pd含量,在此基础上圈定了4种主要类型Pt、Pd异常:①与中古元古代昆阳群黑色页岩建造有关的Pt、Pd异常;②与上震旦统—下寒武统黑色页岩建造有关的Pt、Pd异常;③与二叠纪峨眉山玄武岩建造有关的Pt、Pd异常;④与其他沉积建造有关的Pt、Pd异常。并对该地区Pt、Pd地球化学异常进行了评价,为进一步开展Pt、Pd资源评价提供科学依据。  相似文献   

陕西双王金矿床东段矿体地质特征及成矿预测   总被引：1，自引：0，他引：1       下载免费PDF全文

张军 《地质找矿论丛》2003,18(3):190-194

陕西省太白县双王金矿床属大型低品位角砾岩型金矿，矿床东段的矿体赋存层位是古道岭组，矿体产于角砾岩带中，含金角砾岩带的形成与断裂构造有关，其热液活动可划分5个阶段，Ⅱ1，Ⅲ2亚阶段为主要成矿阶段。矿体矿化规律、矿体特征、矿体成因具有独特性。文章对未探明地段进行了成矿预测，提出找矿靶区，并在部分地段已经得到验证。  相似文献   

骑田岭北部地区锡多金属矿成矿特征及找矿潜力分析   总被引：5，自引：0，他引：5  

胡志科  龚述清  刘阳生 《华南地质与矿产》2003,(1):49-55

在介绍骑田岭北部地区成矿地质环境的基础上，概述了区内两种主要矿床类型－－矽卡岩型钨钼矿及热液充填交代型锡铅锌矿的成矿地质特征，进而总结了区内矿床的成矿规律和预测标志。认为该区矿质来源丰富，矿体严格受岩体和构造控制，据此提出了进一步找矿方向的建议。  相似文献   

The Paleo－Environmental Significance of Sr and Ca Contained in Acid－Soluble Fraction of Plateau Loess Deposits in Xining Basin     

谭红兵  马海州  鹿化煜  张西营  魏海珍 《中国地球化学学报》2003,22(2):156-163

The Xining Basin,located on northeastern Qinghai-Xizang Plateau,is adjacent to the Qaidam Bsim and Gobi-desert.Therefore,thick,integrated deposits of loess or paleo-sol sequence were well developed.As is well known,there is much paleo-environmental information recorded in loess and plaeo-sol.So if we deal with paleo-environmental index from different an gles ,especially from loess geochemistry,some important and detailed paleo-environmental evolutional information will be acquired.Based on this,the authors determined the contents of Sr and Ca contained in acid-soluble fraction from the bottom to the top of the Panzishan section.This section was obtained through making a well about 17 m in depth,including S1 paleo-sol that was developed during the last interglacial period.According to the results,it is found that variations in contents of Sr and Ca are well correlated with conversion of loess and paleo-sol.In loess deposits,the contents of Sr and Ca are higher than those in paleo-sol deposits.It is known that loess was deposited under cold-dry climate conditions and paleo-sol was developed during warm-humid climate episodes.It is concluded that due to their mobile behaviors,under cold-dry climate conditions,Sr and Ca are stagnant during weak weathering,but under warm-humid climate conditions,Sr and Ca are easily leached and transported in aqueous solution.Therefore,they can be utilized as indicatiors of climate changes.Moreover,variations in contents of Sr and Ca are more sensitive than susceptibility.The mobile behaviors of Sr and Ca contained in acid-soluble fraction can serve as a new quantitative index to evaluate paleo-environmental changes on the plateau.  相似文献