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51.
用XRF和ICP-AES方法分别测试了湖北辽瓦店遗址地层样品的氧化物含量和地球化学元素含量,恢复了遗址地层中夏代文化层、东周文化层和明清文化层记录的环境变化和人类活动特征。结果表明:1)夏代文化层时期,气候温暖湿润,生态环境良好,人类活动与自然环境和谐度高,有原始的手工业活动记录。2)东周时期气候开始进入干旱期,干旱程度在上东周文化层中部逐渐加深(LOI=6.98%),到了上东周文化层顶部气候进入暖湿期。该层Cu含量的异常高值(0.31mg/g)和出土的青铜器表明本文化层反映了青铜社会的繁荣期,而P含量的高值(22.73mg/g)和动物骨屑则反映了该期人们驯养、捕猎动物的普遍性。3)明清时期的气候趋于干凉,明代文化层中部有短暂暖湿期,后又进入冷干期。清代文化层中下部有暖湿特征,之后重新进入干冷期。该层Ca(均值101.5mg/g),Mg(均值60.27mg/g),Zn和Pb的高含量表明遗址曾有过制陶(瓷)业的历史。另外,Mg和Ca含量的高值与耕作区、墙壁灰浆、生活垃圾堆积等人类活动相关。Ca和Mg含量在近现代层逐步升高揭示了人类活动逐渐增强的事实。地层的平均粒径自上东周文化层(<142cm)开始出现振荡,暗示汉江洪水和季节性山洪发生的频率不断增加,表明恶劣环境条件虽然促进了人类生产力水平的提高,但原始生态系统却遭到破坏,人类活动对自然环境的正反馈效应日益凸显。 相似文献
52.
通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。 相似文献
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56.
Hang Li Dahua Li Tangfu Xiao Libin He Zengping Ning Jialong Sun Changsheng Zhu Yan Shuang 《中国地球化学学报》2008,27(1):21-27
The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment. 相似文献
57.
Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters 相似文献
58.
大金山铅锌矿位于泰宁一政和北东东向铜多金属成矿带上,是该成矿带主要的矿种之一,也是闽北地区一个较有价值的矿床。矿床产于早元古代南山组上段,受燕山期北东东向构造控制,属中低温热液充填交代型矿床。 相似文献
59.
河南桐柏围山城层控金银成矿带同位素地球化学 总被引:8,自引:2,他引:6
河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。 相似文献
60.
Elisa Sacchi Gian Maria Zuppi Luca Pizzino Fedora Quattrocchi Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319
The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics
had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining
the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already
been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related
fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and
discharging groundwaters belonging to the Na–HCO3 and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline
Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform
(MCP). The high CO2 contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of
a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the
origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate
that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the
second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains.
The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today.
At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as
two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection
linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly
variable δ13CTDIC values suggest the presence of two distinct CO2 sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO2 and He indicates an increased mantle signature in uprising CO2-rich fluids. 相似文献