Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

RECENT TECTONIC DEFORMATION ANOMALY AND EARTHQUAKES IN GANSU-NINGXIA-QINGHAI AREA     

Wang Shuangxu  Zhang Xi  Zhang Sixin  Xue Fuping 《大地测量与地球动力学》2003,23(Z1)

1　IntroductionAccordingtogeologicalstructure ,theGansu Ningxia Qinghaiareabelongstothenortheastmar ginofQinghai Tibetblock .Thisareahasbeenpaidmuchattentionby geo specialistsinChinaandabroadbecauseofitssignificanttectonicmovement,itsintensiveseismicity ,anditsimportanceinearth quakehazardmitigation .IntheDevelopmentPro gramonNationalKeyBasicResearchesundertheProject“MechanismandPredictionofContinentalStrongEarthquakes”,themechanismsofcontinen talstrongearthquakesarestudied ,usinghypo…  相似文献   

Double–double radio galaxies: remnants of merged supermassive binary black holes     

F. K. Liu  Xue-Bing Wu  S. L. Cao 《Monthly notices of the Royal Astronomical Society》2003,340(2):411-416

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试论新世纪地理信息科学的发展   总被引：1，自引：0，他引：1  

黄雪樵  陈昱 《地球信息科学学报》2002,4(2):32-37

本文重点分析了当前国内外地理信息科学的形成与发展趋势和地理信息科学不断发展的历程 ,提出近期发展的前沿 ,以及当前地理信息产业化面临的一些重要问题。最后提出对地理信息科学发展的意见。  相似文献   

大同—阳高Ms6.1地震前兆综合加权信息熵的变化     

张昭栋  刘章增  赵会蓬 《大地测量与地球动力学》2002,22(1):51-55

利用“地震预报计算机专家系统”的思想对大同 -阳高 Ms6 .1地震前每一前兆异常事件进行综合评估 ,以每一异常的最可能发震时间来计算发震概率 ,利用地震前兆综合加权信息熵研究了系统熵值与地震的关系。对华北地区的地震前兆综合加权信息熵研究表明 ,在大同 -阳高 Ms6 .1地震前 ,信息熵出现了明显的减熵有序变化  相似文献   

轴对称稳恒磁场的一种解法     

孙新民  丁世荣 《地球科学与环境学报》1997,(2)

本文依据稳恒磁场中的高斯定理和安培环路定理，用迭代法推导出对称轴上的磁感应强度与空间任意一点磁感应强度的关系式，从而可得出轴对称稳恒磁场的无电流分布空间的解式。  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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中国1∶100万景观生态制图设计   总被引：5，自引：0，他引：5  

程维明  柴慧霞龙恩  刘海江张旸 《地球信息科学学报》2004,6(4):19-24

中国1∶100万景观生态图系借鉴国内外传统景观制图方法和制图规范,在遥感、地理信息系统先进技术的支持下,设计研制其制图方法、制图内容、样图和技术流程,同时提出初步的景观分类系统,为今后编制中国1∶100万景观生态图奠定基础。  相似文献   

粤东海涂土壤及其利用     

张希然 《云南地理环境研究》1990,2(1):72-81

粤东海岸东起闽粤交界的大埕湾,西迄深圳市的大鹏湾,岸线曲折,港湾较多,河溪人海泥沙在潮间带及紧邻5m 等深线以内形成大片海涂,土壤类型多样,以泥质和沙泥质土壤为主;除河口湾的土壤含盐量低外,其余较高;土壤有机质含量中等,钾素较丰富,磷素较低。因地处亚热带南缘,光、热和水资源条件较好,且多数海湾有深入内地的小海湾和潮沟,甚适合发展海水养殖与晒盐,韩江口的义丰河和海门龟头海大闸外等滩地尚有围垦价值。多处海湾潮滩沙土适合作海滨浴场,也有小片滩地红树林适合旅游观赏。  相似文献