Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

油压夯管锤蓄能器与活塞振动耦合性的数学解析          下载免费PDF全文

李国民 《探矿工程》2002,(1):52-54

蓄能器容积的变化与夯管锤的工作过程是紧密联系在一起的，由于活塞的前后运动以及在运动过程中的每一时刻所需要的油量不同的，理想状态就要通过蓄能器的容积变化来调节，就是说蓄能器的容积变化要与夯管锤的冲击振动相耦合。简要介绍了油压夯管锤结构原理，分别解释了油压夯管锤蓄能器与夯管锤的容积压力耦合。  相似文献   

FW-300型非开挖导向钻机给进机构的设计   总被引：4，自引：0，他引：4       下载免费PDF全文

郑午  吴晓军 《探矿工程》2002,(2):51-52

指出了对非开挖钻机给进机构的基本要求，着重介绍了FW－300型非开挖导向钻机机构的设计思想及主要部件设计。  相似文献   

GEOCHEMICAL EFFECTS OF MAJOR ELEMENTS DURING FLUID-ROCKS INTERACTION IN MARINWOBO FAULT IN THE SOUTH MARGIN AREAS OF ALTAI MOUNTAINS     

ZHAO Zhi-zhong ZENG Qiao-song BI Hua 《大地构造与成矿学(英文版)》2002,(2):68-75

There are four types of metamorphic rocks in the Marinwobo fault, i. e, cataclasite, mylonite,mictosite and migmatitic granite, and the formation of these rocks is due to the progressive metamorphism of the pyroclastics. The fluids play a very important role in the metamorphic process of these rocks in the Marinwobo fault, the most important feature is that the fluids not only result in the migration of the major elements of the deformation rocks, but also result in the volume loss of the deformation rocks in the deformation process. Thus the migration laws of the major elements in different stages of the progressive metamorphic process are discussed according to mass balance equations. Finally, the quantitative analysis of the mass loss and volume loss of the different rocks the in Marinwobo fault is discussed in this paper.  相似文献   

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析     

薛克勤  赵月凤  董清雷 《华北地质》2002,(Z1)

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。  相似文献   

中条山同善天窗铜矿类型及找矿新认识     

王昊  郭红党  薛克勤 《华北地质》2002,(Z1)

在总结同善构造—剥蚀窗内成矿地质条件的前提下 ,运用成矿系列理论 ,把区内具有多种表现形式的变基性火山岩型、变砂岩型、大理岩型三大类铜矿分成了八种亚类 ,认为诸类铜矿与区内广泛发育的新太古代基性岩存在着成生联系 ,铜矿的形成经历了一个复杂的过程。早期的海底火山喷发带来的铁、铜、硫等成矿物质 ,经过最初的海水富集、火山活动末期的热液作用富集以及后来区域变质叠加富集进而形成了这一系列矿床。同时提出了新的找矿思路、找矿方法及找矿靶区。  相似文献   

华北陆块北缘西段中元古代与裂谷作用有关的铁、稀土、多金属矿床特征及成因     

曹秀兰 《华北地质》2002,(Z1)

华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。  相似文献   

Preparation of a New Geological Survey of Japan Geochemical Reference Material: Coral JCp-1   总被引：2，自引：0，他引：2  

Takashi Okai  Atsushi Suzuki  Hodaka Kawahata  Shigeru Terashima  Noboru Imai 《Geostandards and Geoanalytical Research》2002,26(1):95-99

A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed.  相似文献   

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur     

Shunso ISHIHARA  Myung–Shik JIN  Yoshimichi KAJIWARA 《Resource Geology》2002,52(1):41-48

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.  相似文献   

Cu–Fe Bearing Zinc Sulfide from Laloki Stratabound Massive Sulfide Deposit, Papua New Guinea: Chemical Characterization     

Banda J. KULANGE  Yoshimichi KAJIWARA  Kosei KOMURO 《Resource Geology》2002,52(1):67-72

Abstract: A strange, unidentified, Cu-Fe bearing zinc sulfide occurs in the Laloki massive sulfide deposit, Papua New Guinea. The mineral is optically uniform in texture but is chemically variable and zoned even within a single grain. Copper contents vary from 0.1 up to 8.85 wt%. Iron reaches 18.31 wt% at maximum and decreases as Cu increases. It is remarkable, however, that the total Fe+Cu remains essentially unchanged between roughly 18 and 20 wt%. Zn and S are least variable, giving 45.85–47.84 wt% and 33.48–34.58 wt%, respectively. Other trace elements such as Cd and Mn are in general less than 0.2 wt%. It is strongly suggested that the mineral in question constitutes a unique Fe-Cu substitutional solid solution series belonging essentially to the Zn–Fe–Cu–S system.
The ideal chemical formula of the solid solution series can well be presented as Zn₁₀(Fe, Cu)₅S₁₅ or Zn₂(Fe, Cu)S₃, where Fe is always greater than Cu. It is intriguing that chalcopyrite blebs are recognizable restrictively only in nearby portions of the Cu-rich end member with the ideal composition close to Zn₁₀Fe₃Cu₂S_15. It has been confirmed by vacuum-sealed heating experiments that this mineral is decomposed to produce chalcopyrite and Fe-bearing normal sphalerite at temperatures below 200C. This would provide another evidence for the existence of such distinct phase as suggested here.  相似文献