XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit     

Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   

Metal contamination in southern Brazil vineyard softs     

《中国地球化学学报》2006,25(B08):120-120

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Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods     

Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.  相似文献   

Application of HCA and PCA in the discrimination of not polluted tubular wells from tubular wells with incidence of anthropogenic pollution in Western Amazon Region     

《中国地球化学学报》2006,25(B08):165-165

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Groundwater and highways interaction: past and present experiences of highway construction in Slovenia     

Mihael Brencic 《Environmental Geology》2006,49(6):804-813

During the planning, designing, construction, operation and maintenance of highways, groundwater can be of important environmental and constructional constraint that can significantly influence the safety operation of traffic and of big influence on the operational costs of highways. To classify and conceptualize the relation between groundwater and highways, three important groups of problems can be determined: groundwater protection from highway influences, protection of highway from groundwater and economic use of groundwater for highway operation. In the present study, groundwater management strategies are represented during all life cycles of highways. Greater emphasis is given to groundwater protection and field hydrogeological investigations for proper groundwater management related to the highway. The approach adopted in Slovenia and the role of hydrogeology is given as an illustration.  相似文献   

早涝碱咸综合治理与生态环境良性循环     

方生陈秀玲  范振铎万宝林 《地下水》2005,27(1):1-5,9

华北平原东部淡水资源短缺，旱涝碱成灾害限制了农业生产的可持续发展。海河的治理，解决了排洪排涝排咸出路。春季开发利用地下水包括微咸水和半咸水抗旱灌溉。夏季利用伏雨洗盐排咸，增大降雨入渗，减少径流流失，防治渍涝灾害，把降雨转化为地下水资源。秋冬引蓄河水，回灌地下水补源。以土壤与潜水的地层空间作为调节大气降水、土壤水、地下水、地表水的地下水库，以调控地下水埋深在临界动态为指标，最大限度地把时空分布不均的天然降雨转化为可持续利用的水资源。地表水地下水联合运用，促使水资源采补平衡，降雨灌溉淋洗脱盐强于干旱蒸发积盐过程，地下水淡化强于矿化过程。实现旱涝碱咸综合治理，水土资源可持续利用，经济社会可持续发展，生态环境良性循环。  相似文献   

论运城市地下水超采与保护策略     

卢莉莉 《地下水》2005,27(3):154-155

本文论述了2002年运城市地下水超采状况及其引起的环境地质等一系列问题.并遵循可持续发展的思想,提出了地下水资源保护的几点意见.  相似文献   

北京市地下水动态监测示范工程的建设和应用     

杨忠山  薛伟  周东 《地下水》2005,27(5):384-387

北京市地下水动态监测示范工程是北京市科委的重大项目,从1999年开始建设,到2004年4月全面完成.本文详细介绍了该项目的建设及开发内容,以及在北京市地下水动态监测工作中的应用情况.  相似文献   

山西省地下水资源开发利用的对策     

狄丕勋 《地下水》2005,27(6):466-469

本文基于可持续发展的思想,论述了山西省地下水开发利用现状及存在的问题,分析了地下水的开发利用潜力,提出了地下水资源开发、利用应采取的对策.  相似文献   

电导率成像系统在西部地下水勘查中的应用   总被引：3，自引：0，他引：3  

曹福祥  尹秉喜  朱庆俊 《物探与化探》2005,29(4):323-325

介绍了电导率成像系统的基本原理、技术特点和适用范围, 结合西部地区不同类型地下水勘查的应用实例, 说明了方法的有效性。  相似文献