太原盆地农田区大气降尘对土壤重金属元素 累积的影响及其来源探讨   总被引：1，自引：0，他引：1  

赖木收  杨忠芳  王洪翠  周继华  王建武 《地质通报》2008,27(2):240-245

通过研究太原盆地大气干湿沉降中重金属元素的含量分布特征及年输入通量,讨论其对土壤中重金属元素累积的影响。同时采用富集因子法探讨降尘物质的来源。研究结果表明,降尘中重金属元素As、Cd主要来源于人为活动,Pb的来源可能是人为源和自然源。而Hg则主要来源于自然源。  相似文献   

滇西沘江流域水体中重金属元素的地球化学特征   总被引：6，自引：1，他引：5  

李瑞萍  王安建  曹殿华  王高尚  李以科  耿诺 《地质通报》2008,27(7):1071-1078

通过测定流经兰坪金顸铅锌矿区的沘江水体中Pb、Zn、Cd、As的含量和底泥中重金属元素的化学形态的含量,分析了重金属元素的分布和化学形态的变化。结果表明,沘江水遭到了Cd污染,底泥已经成为重金属元素的蓄积库,以国家土壤环境质量标准（Ⅲ级）衡量,Pb、Zn、Cd和舡分别超标3．4倍、15．8倍、106倍和2．6倍。沘江水中重金属元素含量的峰值在矿山附近的下游,而底泥中重金属元素的峰值在矿山下游30-50km的地方,矿业活动、水流变缓、pH等水体环境条件的变化都能影响水和底泥中重金属元素的含量。底泥中的Pb以碳酸盐结合态为主,Zn和Cd以铁锰氧化物结合态为主,而As以残渣态为主。Pb、Cd、Zn三种元素的环境有效态含量比较高,对沘江流域生态环境具有潜在的巨大的危害。  相似文献   

Spatial distribution features and environment effect of heavy metal in intertidal surface sediments of Guanhe estuary, Northern Jiangsu Province     

Jiaxiang Huang  Yong Yin  Jun Xu  Xiaobing Zhu 《Frontiers of Earth Science》2008,2(2):147-156

In northern Jiangsu coastal zone area, Guanhe River is the biggest river and has the best navigation conditions among rivers which flow into the Yellow Sea. The grain sizes show gradual increase from the high intertidal zone to lower intertidal zone. The heavy metal values have slight changes along both sides of the river mouth, but show an evident change perpendicular to the tidal flat. In the latter case, they show a good correlation with grain size fluctuation, that is, the heavy metal values gradually decline when the grain size increases from the high intertidal zone to the lower intra-tidal zone. Analyses of the heavy metal elements show that on the Guanhe estuary surface sediment, the content of the elements Hg, As and Cu is above background values; Pb and Zn contents are rather close to the background values; and Cd content is less than the background values. The element Hg comes out to be harmful in a medium level to ecological environment, while the elements of Cr, As, Cu, Pb, Zn and Cd fall in a safe range of MPL. On the whole, Guanhe estuary tidal flat is not very harmful to the ecology in terms of the heavy metals. __________ Translated from Marine Geology & Quaternary Geology, 2007, 27(5): 23–32 [译自: 海洋地质与第四纪地质]  相似文献   

黑龙江省鸡西盆地南、北两带城子河组精细对比     

王金山 《中国煤炭地质》2008,(8):5-9

鸡西盆地被平麻断裂分割成南、北两个条带,多数研究者将南带1煤之下的海相层叠伏于北带海相层或底砾岩之下,称为“城子河组下段”或“石河北组”。利用事件地层学的原理,分析盆地内城子河组早期盆地裂陷、海侵、火山喷发、聚煤等重大事件在地层精细对比方面的意义,甄别出了盆地中重大事件的地层记录．以等时层为基础建立对比框架。通过大量钻井资料追溯对比,认为盆地中坳陷部位的渴湖海湾沉积是南北两带的沉积过渡类型,根据微体古生物研究,南北两带海相层中的沟鞭藻类化石面貌基本一致,南北带的海相层应是同一层位,初步实现了盆地内南、北两个条带城子河组的精细对比,为恢复盆地古地理环境奠定了可靠的基础。  相似文献   

Formation of the mid-fifteenth century Kuwae caldera (Vanuatu) by an initial hydroclastic and subsequent ignimbritic eruption     

Claude Robin  Michel Monzier  Jean-Philippe Eissen 《Bulletin of Volcanology》1994,56(3):170-183

In the mid-fifteenth century, one of the largest eruptions of the last 10 000 years occurred in the Central New Hebrides arc, forming the Kuwae caldera (12x6 km). This eruption followed a late maar phase in the pre-caldera edifice, responsible for a series of alternating hydromagmatic deposits and airfall lapilli layers. Tuffs related to caldera formation ( 120 m of deposits on a composite section from the caldera wall) were emitted during two main ignimbritic phases associated with two additional hydromagmatic episodes. The lower hydromagmatic tuffs from the precaldera maar phase are mainly basaltic andesite in composition, but clasts show compositions ranging from 48 to 60% SiO₂. The unwelded and welded ashflow deposits from the ignimbritic phases and the associated intermediate and upper hydromagmatic deposits also show a wide compositional range (60–73% SiO₂), but are dominantly dacitic. This broad compositional range is thought to be due to crystal fractionation. The striking evolution from one eruptive style (hydromagmatic) to the other (magmatic with emission of a large volume of ignimbrites) which occurred either over the tuff series as a whole, or at the beginning of each ignimbritic phase, is the most impressive characteristic of the caldera-forming event. This strongly suggests triggering of the main eruptive phases by magma-water interaction. A three-step model of caldera formation is presented: (1) moderate hydromagmatic (sequences HD 1–4) and magmatic (fallout deposits) activity from a central vent, probably over a period of months or years, affected an area slightly wider than the present caldera. At the end of this stage, intense seismic activity and extrusion of differentiated magma outside the caldera area occurred; (2) unhomogenized dacite was released during a hydromagmatic episode (HD 5). This was immediately followed by two major pyroclastic flows (PFD 1 and 2). The vents spread and intense magma-water interaction at the beginning of this stage decreased rapidly as magma discharge increased. Subsequent collapse of the caldera probably commenced in the southeastern sector of the caldera; (3) dacitic welded tuffs were emplaced during a second main phase (WFD 1–5). At the beginning of this phase, magma-water interaction continued, producing typical hydromagmatic deposits (HD 6). Caldera collapse extended to the northern part of the caldera. Previous C¹⁴ dates and records of explosive volcanism in ice from the south Pole show that the climactic phase of this event occurred in 1452 A.D.  相似文献   

华南二叠－三叠系的事件地层与生物地层界线   总被引：10，自引：1，他引：9  

王成源 《地层学杂志》1994,18(2):110-118,145

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。  相似文献   

Heavy metals in stream sediments from copper and gold mining areas in southern Brazil     

Maria Heloisa D. Pestana  Milton L.L. Formoso  Elba C. Teixeir 《Journal of Geochemical Exploration》1997,58(2-3)

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Effects of heavy metals on the survival ofDiacypris compacta (Herbst) (Ostracoda) from the Coorong,South Australia     

Anna Brooks  Rehema M. White  David C. Paton 《International Journal of Salt Lake Research》1995,4(2):133-163

The hypermarine southern Coorong is threatened by proposals to drain relatively fresh surface water and groundwater from adjacent agricultural areas into the Coorong. These influent waters carry moderate loads of heavy metals. Acute toxicity of heavy metals toDiacypris compacta, an abundant ostracod in the Coorong, was measured in the laboratory at 18°C in a static system using Coorong water (pH 7.8 salinity 50 ppt). At 4 days (96 h) the mean values of LC₅₀ for copper, zinc, lead and, cadmium respectively were 0.8, 2.1, 3.1 and 4.3 mg L^–1, and at 8 days the respective mean LC₅₀ s were 0.4, 0.7, 2.2 and 1.1 mgL^–1. The effect of two or three metals on mortality was additive in some cases and synergistic in other cases, but generally less than additive. However, in all cases mortality was greater in the presence of two or three metals than in the presence of a single metal. According to ANZECC (1992) guidelines, maximum acceptable concentrations of heavy metals should be no higher than 0.01 x the lowest LC₅₀ value. Using the lowest LC₅₀ values forDiacypris compacta obtained at 8 days, maximum acceptable concentrations in the Coorong would be 4, 5, 9 and 22 gL^–1 for copper, zinc, cadmium and lead respectively, the values for zinc and copper failling below those recommended by ANZECC (1992) for marine waters. Reported concentrations of copper and zinc in surface water and groundwater in areas adjacent to the Coorong sometimes exceed these values, hence drainage of these waters into the Coorong represents a significant hazard to the Coorong biota.  相似文献   

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China     

Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.  相似文献   

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site     

Taoze LIU Yuangen YANG Bangyu LIU Xiangyang BI Feili LI 《中国地球化学学报》2006,25(B08):41-42

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.  相似文献