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141.
142.
143.
Yue GAO Martine Leermakers Gabriel Billon Baghdad Ouddane Jean-claude Fisher Willy Baeyens 《中国地球化学学报》2006,25(B08):199-199
In polluted aquatic systems, toxic metals are often accumulated in bottom sediments. They are, however, not necessarily stored definitively because diagenetic processs can modify redox, pH and even the amount of complexing ligands, releasing the trace metals back into the pore waters and the water column. Especially the labile metal fraction in the pore waters is important since this is the bioavailable fraction determining the bio-toxicity of the sediments. The goal of our study was therefore to assess, with novel sampling techniques, this bioavailable metal fraction in the pore waters as well as the flux towards the overlying water column. High-resolution profiles of trace metals in pore waters of marine and riverine sediments were assessed by DET (diffusive equilibrium in thin films) and DGT (diffusive gradients in thin films) gel techniques. The DET technique uses a diffusive gel layer that equilibrates with the aquatic system and with this technique the concentrations of total dissolved trace metals are obtained directly. The DGT technique uses an acrylamide diffusive gel backed by a resin gel (Chelex) which binds trace metals. With the DGT technique only labile species of selected metals can be captured. According to the redox potential measurements, the marine sediments were suboxic (200 mV to -220 mV versus Ag/AgCl electrode), while the riverine sediments were completely anoxic (-160 mV to -220 mV versus Ag/AgCl electrode). This redox potential was apparently controlling the trace metals species in the pore waters: for example a strong correlation between Mn and Co was found in the riverine sediments (for DET and DGT sampling), while in the marine sediments trace metals presented various behaviors. 相似文献
144.
Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences. 相似文献
145.
Based on the high temperature data of June to August in 1961-2000 in North China, the high temperature weather processes are investigated, and a more complete data set for severe high temperature processes is created. The climatic characteristics of adverse high temperature weather in Beijing, Tianjin, Shijiazhuang, Jinan and Taiyuan are analyzed respectively. The major features of the East-Asia Subtropical High and Transformed Continental High are discussed. The outcomes indicate that the influence of both East Asia Subtropical High and Transformed Continental High on these weather events varies, by a larger margin, from one city to another over North China and they are also closely related to the relative humidity. It is found that the behaviours of East-Asia Subtropical High and Transformed Continental High are the major important systems that give rise to the summer high temperature weather over the region. Based on these findings, the 5-day, 10-day and monthly assessment models for such high impact events have been developed. The assessment outcomes prove to be useful in assessing severe high-temperature events in major cities of North China. 相似文献
146.
YANG Xuchao ZHANG Yili ZHANG Wei YAN Yuping WANG Zhaofeng DING Mingjun CHU Duo 《地理学报》2006,16(3):326-336
Using monthly average, maximum, minimum air temperature and monthly precipitation data from 5 weather stations in Mt. Qomolangma region in China from 1971 to 2004, climatic linear trend, moving average, low-pass filter and accumulated variance analysis methods, the spatial and temporal patterns of the climatic change in this region were analyzed. The main findings can be summarized as follows: (1) There is obvious ascending tendency for the interannual change of air temperature in Mt. Qomolangma region and the ascending tendency of Tingri, the highest station, is the most significant. The rate of increasing air temperature is 0.234 oC/decade in Mt. Qomolangma region, 0.302 oC/decade in Tingri. The air temperature increases more strongly in non-growing season. (2) Compared with China and the global average, the warming of Mt. Qomolangma region occurred early. The linear rates of temperature increase in Mt. Qomolangma region exceed those for China and the global average in the same period. This is attributed to the sensitivity of mountainous regions to climate change. (3) The southern and northern parts of Mt. Qomolangma region are quite different in precipitation changes. Stations in the northern part show increasing trends but are not statistically significant. Nyalam in the southern part shows a decreasing trend and the sudden decreasing of precipitation occurred in the early 1990s. (4) Compared with the previous studies, we find that the warming of Mt. Qomolangma high-elevation region is most significant in China in the same period. The highest automatic meteorological comprehensive observation station in the world set up at the base camp of Mt. Qomolangma with a height of 5032 m a.s.l will play an important role in monitoring the global climate change. 相似文献
147.
Brian Emmerson James Jackson Dan McKenzie Keith Priestley 《Geophysical Journal International》2006,167(3):1233-1272
148.
Geotechnical Properties of Low Calcium and High Calcium Fly Ash 总被引:1,自引:0,他引:1
In this paper, a comparative study has been made for physical and engineering properties of low calcium and high calcium Indian
fly ash. The grain size distribution of fly ash is independent of lime content. Fly ash particles of size >75 μm are mostly irregular in shape whereas finer fractions are spherical for low calcium fly ash. For high calcium fly ash, chemical
and mineralogical differences have been observed for different size fractions. Compared to low calcium fly ash, optimum moisture
content is low and maximum dry density is high for high calcium fly ash. Optimum moisture content is directly proportional
and maximum dry density is inversely proportional to the carbon content. The mode and duration of curing have significant
effect on strength and stress–strain behavior of compacted fly ash. The gain in strength with time for high calcium fly ash
is very high compared to that of low calcium fly ash due to presence of reactive minerals and glassy phase. 相似文献
149.
The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt 总被引:4,自引:0,他引:4
J. Sánchez España E. López Pamo E. Santofimia Pastor J. Reyes Andrés J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD)
waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters
were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously
recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and
precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5
(stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates
of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially
sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4=
anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous
free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely
scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH
< 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co,
Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB. 相似文献
150.
由于煤层气的解吸热效应,煤层气的运移过程是一个非等温过程。因此,温度场对煤层气渗流有着重要的影响。前人在研究煤层气渗流规律的研究中并没有同时考虑滑脱效应和温度场因素的影响,而在实际的深部开采中综合考虑滑脱效应和温度场的影响对研究深部煤层气运移规律有着重要的意义。因此本文建立了考虑滑脱效应及温度场的煤层气渗流数学模型,利用有限元数值方法研究了考虑滑脱效应和温度场耦合的煤层气运移规律;研究了考虑滑脱效应和温度场对压力场分布的影响;对考虑滑脱效应及温度场因素的煤层气产量进行了预测。得出了随着温度的升高煤储层的压力在降低,温度的升高对煤层气的产量有着负面的影响这一重要结论。 相似文献