胶东金矿研究进展及约束金物质来源的新思路     

李大鹏  ;程光锁  ;迟乃杰  ;李成学 《山东地质》2014,(12):1-7

作为全球最主要的金成矿带之一,胶东地区仅占全国国土面积的0．27％,黄金储量却约占全国的25％,特别是胶西北地区的金矿更是星罗棋布,引起了国内外地质学家的广泛关注,进行了大量的生产和科研工作。该文总结了近年来取得的关于胶东金矿在构造、岩浆、流体及成矿物质、富集机制等方面取得的研究进展,并且针对颇具争议的金成矿物质来源问题,提出了新的研究思路,并初步论证了其可行性。以期抛砖引玉,引起广大地学同仁对此科学问题的关注。  相似文献   

Authigenesis of vivianite as influenced by methane-induced sulfidization in cold-seep sediments off southwestern Taiwan     

《Journal of Asian Earth Sciences》2014

Authigenesis of iron-rich phosphate nodules occurs in iron-rich cold-seep sediments (MD052911 core) at Yung-An Ridge offshore southwestern Taiwan. Raman, FTIR, and quantitative X-ray energy-dispersive spectroscopic analyses indicate that the phosphate mineral is vivianite (or barićite) and shows Fe/Mg molar ratios spanning from ca. 0.6 to 4.0 and a general down core trend of increasing Fe/Mg ratios. The formation of vivianite is limited to a depth interval of 13–17 mbsf (meters below seafloor) and is most prominent at ∼16 mbsf in association with high dissolved iron concentrations and depleted dissolved sulfide below a peak sulfidization zone (enriched in mackinawite and greigite). Alternate growths of vivianite and iron monosulfides and compositional zoning with Mg enriched towards the peripheries of individual nodules occur in the transition from the zone of vivianite mineralization to the sulfidization zone. The crystallization of vivianite below the sulfidization front could have been favored by scavenging of downward diffusive dissolved sulfide from pore waters in the sulfidization zone. Alternate growths and overlapping of the zones of iron monosulfides and vivianite can be attributed to fluctuations of the sulfidization front and methane flux. The discovery of vivianite in the Yung-An Ridge sediments implies that authigenic vivianite can be an important sink for phosphorus burial in cold-seep sediments that have high reactive-iron contents and high sedimentation rates.  相似文献   

木里盆地侏罗系煤层气主控因素及成藏模式          下载免费PDF全文

田亚  杜治利  张文龙  陈夷 《中国地质调查》2014,6(4):88-94

我国天然气需求逐年上升,寻找常规天然气的接替能源已迫在眉睫。木里盆地中—下侏罗统煤炭资源丰富,煤层厚度大,煤层气资源潜力巨大。综合利用野外地质调查、样品分析测试、煤炭钻井录井及含气量现场解吸,对木里盆地木里组煤层赋存特征、成藏地质条件、主控因素及煤层气成藏模式进行了研究,结果表明: 木里盆地煤层厚度大,埋藏适中,以气煤和焦煤为主,整体处于中—高变质阶段,含气量较高,煤层气资源潜力良好; 煤层的变质程度及顶、底板的封盖能力控制了煤层气的富集; 木里盆地侏罗系煤层气主要有宽缓向斜富集和大型单斜构造富集2种成藏模式。煤层气主控因素分析及成藏模式研究为后续开展木里盆地的煤层气勘探开发提供了借鉴和依据。  相似文献   

Features of the Excess Adsorption Isotherms of High-Pressure Methane Adsorption on Coal and Simulation Model     

CUI Yongjun  ZHANG Dengfeng  ZHANG Qun  LIN Weigang  SONG Wenli  LI Yuhui  JIANG Wenping 《《地质学报》英文版》2010,84(6):1547-1554

<正>Four coal samples of different ranks are selected to perform the adsorption measurement of high-pressure methane(CH4).The highest equilibrium pressure of the measurement exceeds 20 MPa. Combined with the measuring results and theoretical analyses,the reasons for the peak or the maximum adsorption capacity appearing in the excess adsorption isotherms are explained.The rules of the peak occurrence are summarized.And then,based on the features of coal pore structure,the adsorption features of high-pressure gas,the microcosmic interaction relationship of coal surface and CH4 molecule,and the coalbed methane reservoir conditions,three theoretical assumptions on the coal adsorption high-pressure CH_4 are suggested.Thereafter,on the basis of these theoretical assumptions,the Ono-Kondo lattice model is processed for simplification and deformation. Subsequently,the equations modeling the excess adsorption isotherm of high-pressure CH_4 adsorption on coal are obtained.Through the verification on the measurement data,the fitting results indicate that it is feasible to use the Ono-Kondo lattice mode to model the excess adsorption isotherm of high-pressure CH_4 adsorption on coal.  相似文献   

不同变质变形煤储层孔隙特征与煤层气可采性   总被引：3，自引：0，他引：3  

范俊佳  琚宜文  侯泉林  谭静强  卫明明 《地学前缘》2010,17(5):325

煤储层孔隙是煤层气的主要聚集场所和运移通道,煤储层孔隙结构不仅制约着煤层气的含气量,而且对其可采性也有重要影响。文中选取淮北煤田和沁水盆地不同矿区有代表性的煤样,通过对研究区不同变质与变形煤样的宏微观构造观测、镜质组反射率与孔隙度测试以及压汞实验分析,研究了不同变质变形煤储层孔隙结构特征及其对煤层气可采性的制约。研究结果表明,按照不同的变质变形特征将研究区煤储层主要划分为5类,即:高变质较强至强变形程度煤储层(Ⅰ类)、高变质较弱变形程度煤储层(Ⅱ类)、中变质较强变形程度煤储层(Ⅲ类)、中变质较弱变形程度煤储层(Ⅳ类)及低变质强变形程度煤储层(Ⅴ类)。不同变质变形煤储层的孔隙结构具有以下特征:Ⅰ类和Ⅱ类煤储层吸附孔占主导,Ⅰ类煤储层孔隙连通性差,Ⅱ类煤储层因后期叠加了构造裂隙,孔隙连通性变好;Ⅲ类煤储层中孔、大孔增多,但有效孔隙少,孔隙连通性变差;Ⅳ类煤储层吸附孔较多,中孔、大孔中等,且煤储层内生裂隙发育,孔隙具有较好的连通性,渗透性明显变好;Ⅴ类煤储层吸附孔含量较低,中孔较发育,大孔不太发育,有效孔隙少,孔隙连通性差。由此,变质程度高且叠加了一定构造变形的煤储层(Ⅱ类)以及中等变质程度变形较弱且内生裂隙发育的煤储层(Ⅳ类),其煤层气有较好的渗透性,可采性较好。  相似文献   

α卡法和高密度电法在采空区探测中的应用     

高玉娟  卢放 《西安地质学院学报》2010,(3):316-318

在治理采空区塌陷等地质灾害时,采空区位置的探测显得尤为重要。根据采空区和围岩间的导电性差异,结合地质资料,采用α卡法和高密度电法相结合的综合地球物理勘探方法,开展采空区位置的探测研究。研究表明：未充水的采空区出现α射线强度脉冲读数和视电阻率异常高值是探测采空区的地球物理前提条件;利用α卡法和高密度电法相结合的手段对采空区进行探测,效果良好,结论可靠。  相似文献   

东营凹陷民丰洼陷深层天然气储层流体包裹体油气地质研究   总被引：9，自引：0，他引：9  

陈勇  林承焰  张善文  宋国奇  周振柱  于雯泉  郑洁 《沉积学报》2010,28(3):620-625

通过流体包裹体岩相学观察,分析了民丰洼陷深层天然气储层流体包裹体的类型、形态、产状、颜色等特征。烃类包裹体镜下特征显示民丰洼陷深层天然气的油气演化程度达到高成熟度阶段,而烃类包裹体拉曼光谱分析表明民丰洼陷深层天然气成藏过程可能与富甲烷烃类流体有关。基于油—水共生包裹体体系中盐水包裹体的测温分析,结合民丰洼陷埋藏史和热史分析,认为民丰洼陷深层天然气有两个成藏期。第一期成藏主要在东营期,但贡献不大;第二期成藏时间主要集中在明化镇期。第二期成藏对最终的天然气藏具有主要贡献,成藏时间主要集中在距今10 Ma之后。储层包裹体拉曼光谱分析结果显示,烃类流体与二氧化碳流体共存,证实天然气成藏过程中存在酸性流体。由于酸性流体溶蚀了早期成岩形成的方解石胶结物,从而使得民丰洼陷深层储层次生孔隙发育,有利于天然气成藏。  相似文献   

新疆阿尔泰铁木尔特铅锌矿床流体包裹体研究及地质意义   总被引：6，自引：3，他引：3  

耿新霞  杨富全  杨建民  黄承科  刘锋  柴凤梅  张志欣 《岩石学报》2010,26(3):695-706

铁木尔特中型铅锌矿是阿尔泰山南缘克兰盆地内的重要VMS型矿床。矿床赋存于上志留统-下泥盆统康布铁堡组上亚组第二岩性段,容矿岩石为大理岩、绿泥石英片岩、变钙质粉砂岩、夕卡岩。矿体呈似层状和透镜状。矿床的形成经历了喷流沉积期、叠加改造期和表生期。石英、长石、方解石和石榴子石中包裹体类型主要为液体包裹体,在石英中另出现了气体包裹体、纯气体包裹体、含子矿物多相包裹体、含液体CO2的三相包裹体和两相CO2包裹体。喷流沉积期成矿流体均一温度变化于150～330℃,其峰值是165℃和285℃,成矿流体盐度(NaCleq)为4%～16%,流体密度为0.77～0.97g/cm3,流体阳离子主要以Na+为主,次之为K+,阴离子以Cl-为主,其次是SO42-,气相成分主要是H2O和CO2。叠加改造期均一温度范围是150～480℃,峰值为285℃,盐度(NaCleq)为2.2%～17.08%和33.93%～47.2%,流体密度变化于0.61～1.03g/cm3之间,流体阳离子主要以Na+为主,次为K+、Mg2+、Ca2+,阴离子以Cl-为主,其次是SO42-,气相成分主要是H2O和CO2,其次为N2、CH4,含有少量C2H6。  相似文献   

安徽庐枞盆地井边铜矿床的成矿时代及其找矿指示意义   总被引：10，自引：5，他引：5  

张乐骏  周涛发  范裕  袁峰  马良  钱兵 《岩石学报》2010,26(9):2729-2738

庐枞盆地是长江中下游多金属成矿带中一个重要的多金属矿集区,盆地内发育有多个不同规模的脉状铜矿床。目前对这些脉状铜矿床的成矿时代和构造背景等方面的研究工作还较少。本文以盆地中目前最具代表性的井边铜矿床为研究对象,分别对矿床中的安山斑岩次火山岩体和主成矿阶段石英中流体包裹体采用了LA-ICP-MS锆石U-Pb同位素定年和Ar-Ar同位素定年,获得了安山斑岩LA-ICP-MS锆石U-Pb年龄为133.2±1.7Ma,石英流体包裹体Ar-Ar等时线年龄为133.3±8.3Ma,反等时线年龄为133.3±8.2Ma。这一结果与实际的矿床地质特征和区内岩浆岩已有的同位素年代学数据完全吻合,因而井边铜矿床的形成时代为早白垩世,与盆地中砖桥旋回侵入岩浆活动有关。这一矿化事件与长江中下游地区第二期(135～127Ma)大规模成岩成矿作用相对应,并对应于区域拉张的构造背景。通过本次研究工作,不仅为深入理解庐枞盆地内铜矿化的规律提供了资料,同时也为该区的下一步铜矿找矿工作提供了依据。  相似文献   

Fluid inclusion study of the Plomositas–Los Arcos polymetallic epithermal vein tract, Plomosas district, Sinaloa, Mexico     

Eduardo Gonzlez-Partida  Antoni Camprubí  Francisco Gonzlez-Snchez  Jaime Snchez-Torres 《Journal of Geochemical Exploration》2006,89(1-3):143

The most important deposit in the Plomosas–Rosario district, Sinaloa, is the vein tract named Plomositas–Plomosas–Los Arcos. These are NNW–SSE striking veins hosted in rocks of the Lower Volcanic Supergroup (LVS), and also in rocks at the bottom of the Upper Volcanic Supergroup (UVS). Both supergroups belong to the Sierra Madre Occidental. These veins evolved from an early intermediate sulfidation stage (1), rich in base metal sulfides, to a low sulfidation stage (2), rich in silver sulfides and sulfosalts. There is also a 45 m-wide stockwork with native silver and gold. Stage 1 is found in the deeper portion of the veins whereas stage 2 is found in the most shallow portion of the deposit. These stages record fluid inclusion salinities ranging from 7 to 12 wt.% NaCl equiv., and from 0.2 to 3.5 wt.% NaCl equiv., respectively. Homogenization temperatures range from 120 °C for surface samples to 200 °C at a depth of 320 m. The low homogenization temperatures recorded, and the dispersion of veins within host rocks as veinlets, suggest that this deposit formed at shallow depths and was probably blind.  相似文献