Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

Design of shallow foundations under tensile loading for transmission line towers: An overview     

M.P. Pacheco  F.A.B. Danziger  C. Pereira Pinto   《Engineering Geology》2008,101(3-4):226-235

Tensioned foundations are common in civil engineering applications such as transmission towers, harbors, offshore structures, basement slabs under pressure, industrial equipment, etc. Procedures for the design of tensioned foundations are discussed in this paper, including specific recommendations for more common transmission tower foundations. Starting from a distinction between shallow and deep modes of failure, the paper presents the most common failure mechanisms for shallow failure in tension, including procedures for calculation of foundation tensile capacity under vertical and inclined loading. Emphasis is given to the influence of the strength of the compacted backfill compared to the strength of the natural soil, including presentation of results of full-scale loading tests.  相似文献   

基于群桩基础沉降估算确定压缩层厚度的探讨     

宁文务 《探矿工程》2008,35(8):44-46

在现行规范中,由于桩基沉降估算模式的不同,压缩层厚度的确定方法也不完全相同。对这些方法进行归纳、总结,并通过具体的工程实例,对由不同估算模式确定的压缩层厚度及沉降估算结果进行探讨与分析,认为对于工程场地地质资料掌握较为翔实的情况下,压缩层厚度可采用变形比法确定,否则,宜根据应力比法确定。  相似文献   

广州地区深基坑支护形式研究     

王岭  王睿 《探矿工程》2008,35(11):42-47

介绍了广州地区基坑支护近年来的主要类型及其适用范围,并在分析选型各影响因素的基础上,总结出设计选型的要点。  相似文献   

水平定向钻进非开挖铺管技术市场分析     

袁明昕 《探矿工程》2008,35(10):49-51

重点分析了近几年我国水平定向钻进铺管钻机和施工市场的发展趋势,结合国外的水平定向钻进市场发展分析,总结了我国水平定向钻进技术与市场的发展态势。  相似文献   

采用钻孔倾斜仪监测滑坡深部水平位移方法和仪器的研究     

汤国起  周策 《探矿工程》2008,35(12):19-22

介绍了目前滑坡深部水平位移钻孔倾斜仪人工监测方法存在的问题,钻孔深部位移自动化监测通信方法的选择。地质滑坡灾害监测中广泛使用钻孔倾斜仪,介绍了CZ-2型钻孔倾斜仪的构成及现场测试方法。  相似文献   

基于Mindlin理论Winkler地基参数的Kalman滤波识别     

张剑  叶见曙  唐修生 《岩土力学》2008,29(2):425-430

提出了Winkler地基参数的Kalman滤波识别方法。引入Mindlin理论后,推导了Winkler地基上板的控制微分方程。利用Fourier变换,推求了Winkler地基上简支板的Fourier闭式解。推导了Winkler地基参数的Kalman滤波方程,研究了Winkler地基参数的Kalman滤波识别的具体计算步骤。研究表明,运用Kalman滤波理论进行Winkler地基参数的识别,能有效地估计Winkler地基参数;Winkler地基参数的滤波收敛速度和精度受地基参数初始值选取和位移实测资料的影响,且Kalman滤波理论也可用于其他地基模型地基参数的识别。  相似文献   

钱二块铀矿床采铀注液结垢趋势的理论分析与预测   总被引：1，自引：0，他引：1  

薛海凤  朱建华  刘红研  齐建华 《铀矿地质》2008,24(1):48-56,64

用离子系数矩阵法对钱二块铀矿床地浸采铀试验注液中存在的独立离子反应进行了确定,由溶度积规则及反应平衡原理,借助Matlab编程,估算出了钱二块铀矿床地浸采铀试验注液可能会生成的沉淀物种类及数量,为防治结垢提供了一定的理论依据.  相似文献   

胶州湾海水微表层粘度及其在海-气通量计算中的作用     

张安慧  张正斌  刘莲生  林彩 《中国海洋大学学报(自然科学版)》2002,32(3):456-462

物质海 -气通量计算新建议中将物质海 -气通量计算公式 F=K(CL- b Cg)中的 CL 用CL ( SML ) 代替。本文着重于对公式中质量迁移系数 K的讨论。在测定了海水微表层、次表层水粘度并同时测定了其它一些化学参量基础上 ,得出如下结论 :海水粘度与盐度、碱度有一定相关性 ;微表层与次表层海水的粘度变化小于 3%。因此 ,海水微表层效应影响 K值 ,与海水微表层效应影响物质浓度相比 ,可以不考虑。  相似文献   

Imaging of Buried Archaeological Materials: The Reflection Properties of Archaeological Wood   总被引：1，自引：0，他引：1  

Stephanie H.L. Arnott  Justin K. Dix  Angus I. Best  David J. Gregory 《Marine Geophysical Researches》2005,26(2-4):135-144

Effective marine archaeological site management demands detailed information on not only the spatial distribution of artefacts but also the degradation state of the materials present. Although sonar methods have frequently been used in an attempt to detect buried wooden shipwrecks they are currently unable to indicate their degradation state. To assess the sensitivity of acoustic measurements to changes in the degradation state of such material, and hence the potential for sonars to quantify degradation, laboratory measurements of compressional wave velocity, as well as bulk density for oak and pine samples, in varying states of decay, were undertaken. These data enabled the calculation of theoretical reflection coefficients for such materials buried in various marine sediments. As wood degrades, the reflection coefficients become more negative, resulting in the hypothesis that the more degraded wood becomes, the easier it should be to detect. Typical reflection coefficients of the order of −0.43 and −0.52 for the most degraded oak and pine samples in sand are predicted. Conversely, for wood exposed to seawater the predicted reflection coefficients are large and positive for undegraded material (0.35 for oak, 0.18 for pine) and decrease to zero or slightly below for the most degraded samples. This indicates that exposed timbers, when heavily degraded, can be acoustically transparent and so undetectable by acoustic methods. Corroboration of these experimental results was provided through comparison with high resolution seismic reflection data that has been acquired over two shipwrecks.  相似文献