Organic geochemical studies of a recent Inner Great Barrier Reef sediment—I. Assessment of input sources     

Philip M. Shaw  R.B. Johns 《Organic Geochemistry》1985,8(2):147-156

The concentration of solvent-extractable (SE) and bound hydrocarbons, ketones, alcohols, sterols, monocarboxylic acids, hydroxyacids and α,ω-dicarboxylic acids of a surface sample (0–2.5 cm) from a recent carbonate tropical sediment taken at 60ft (18m) depth north-west of the Low Isles, North Queensland, are reported in detail. n-Alkanes are a minor constituent in the SE and bound hydrocarbon fractions with the major component being unresolved complex hydrocarbon material which is not an anthropogenic input. 6,10,14-Trimethylpentadecan-2-one derived from chlorophyll, as well as phytol, were identified as major components of the ketone and alcohol constituents. No chlorophyll pigments or pigmented degradation products were present, implying degradation before incorporation into the sediment. This conclusion is consistent with evidence for higher-plant input in which all sensitive lipids have been degraded before incorporation. SE and bound fractions have been studied in detail and show considerable differences probably arising from the importance of viable biomass in the SE fraction. Inputs to the sediment are determined as higher plants, algae, bacteria, fungi and meiofauna in descending order of importance.  相似文献   

水准测量往返测较差方差之估计     

冯延明 《武汉大学学报(信息科学版)》1987,(4)

现有文献中以水准测量往返测较差为统计量估计较差方差已提出许多观点和公式,但对于较差误差模型既没有回答其正确性,也缺乏严密可行的参数估计方法。本文将方差分量的最小范数二次无偏估计(MINQUE)法用于较差方差估计,并提出了以近代回归分析原理为基础的较差误差模型统计检验与比较选择的基本方法。这些估计、分析方法既简单易行又严密合理。最后通过对部分一等水准实测数据试算分析,也初步证实了它们的实际效益。  相似文献   

New aromatic biomarkers and possible maturity indicators found in New Albany Shale extracts     

Mei-In M. Chou  Karl V. Wood 《Organic Geochemistry》1986,9(6)

Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C₄₀H₆₆) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C₄₀H₄₈) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation.  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

塔里木盆地北部油气运移二维二相数值模拟分析   总被引：3，自引：0，他引：3       下载免费PDF全文

范土芝  刘鹏生 《地球科学》1995,20(3):322-327

油气运移和聚集过程实际上是油（气）水饱和度知疏导层的变化过程，盆地中油（气）二相流动问题的研究就是对这一过程的定量描述，本项研究是在前人工作基础上，考察压实作用造成骨架变形来推导新的二维二相流动方程，它容描述异常压力演化与二相流动于一式，在模拟方法上采用有限分析的数值方法，这应用于新疆塔里木盆地北部地区，展示了该区异常压力、含水饱和度弥散状扩散效应以及流速场在地质历史时期动态模拟演化特征；指出了该  相似文献   

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea   总被引：9，自引：0，他引：9  

Bouloubassi I  Fillaux J  Saliot A 《Marine pollution bulletin》2001,42(12):1335-1346

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.  相似文献   

多维地震动各方向相关性对拱坝动应力的影响     

吴健  金峰  徐艳杰 《地震工程与工程振动》2005,25(2):50-54

本文将随机振动的虚拟激励法与拱坝-地基动力相互作用FE-BE-IBE时域模型结合，发展了一个可以考虑多维随机地震动作用下的拱坝动力响应计算模型，并用Monte Garlo方法对模型进行了验证，计算结果表明，地震动分量的相关性对结构的动力响应存在一定影响，合理考虑地震动各方向分量的相关性可以更好地计算实际地震作用下的拱坝动力响应。  相似文献   

Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter   总被引：2，自引：5，他引：2  

María del Rosario Sienra  Nelson G. Rosazza  Margarita Prndez 《Atmospheric Research》2005,75(4):267-281

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.  相似文献   

Seismic fragility methodology for highway bridges using a component level approach     

Bryant G. Nielson  Reginald DesRoches 《地震工程与结构动力学》2007,36(6):823-839

Bridge fragility curves, which express the probability of a bridge reaching a certain damage state for a given ground motion parameter, play an important role in the overall seismic risk assessment of a transportation network. Current analytical methodologies for generating bridge fragility curves do not adequately account for all major contributing bridge components. Studies have shown that for some bridge types, neglecting to account for all of these components can lead to a misrepresentation of the bridges' overall fragilities. In this study, an expanded methodology for the generation of analytical fragility curves for highway bridges is presented. This methodology considers the contribution of the major components of the bridge, such as the columns, bearings and abutments, to its overall bridge system fragility. In particular, this methodology utilizes probability tools to directly estimate the bridge system fragility from the individual component fragilities. This is illustrated using a bridge whose construction and configuration are typical to the Central and Southeastern United States and the results are presented and discussed herein. This study shows that the bridge as a system is more fragile than any one of the individual components. Assuming that the columns represent the entire bridge system can result in errors as large as 50% at higher damage states. This provides support to the assertion that multiple bridge components should be considered in the development of bridge fragility curves. The findings also show that estimation of the bridge fragilities by their first‐order bounds could result in errors of up to 40%. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Acceleration response modification factors for nonstructural components attached to inelastic moment‐resisting frame structures     

Ragunath Sankaranarayanan  Ricardo A. Medina 《地震工程与结构动力学》2007,36(14):2189-2210

A statistical analysis of the peak acceleration demands for nonstructural components (NSCs) supported on a variety of stiff and flexible inelastic regular moment‐resisting frame structures with periods from 0.3 to 3.0 s exposed to 40 far‐field ground motions is presented. Peak component acceleration (PCA) demands were quantified based on the floor response spectrum (FRS) method without considering dynamic interaction effects. This study evaluated the main factors that influence the amplification or decrease of FRS values caused by inelasticity in the primary structure in three distinct spectral regions namely long‐period, fundamental‐period, and short‐period region. The amplification or decrease of peak elastic acceleration demands depends on the location of the NSC in the supporting structure, periods of the component and building, damping ratio of the component, and level of inelasticity of the supporting structure. While FRS values at the initial modal periods of the supporting structure are reduced due to inelastic action in the primary structure, the region between the modal periods experiences an increase in PCA demands. A parameter denoted as acceleration response modification factor (R_acc) was proposed to quantify this reduction/increase in PCA demands. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献