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81.
In this paper a semiparametric approach is introduced to decompose an ARFIMA model in the long memory and short memory unobserved components. The procedure is based on the DECOMEL method which produces a statistical decomposition by minimizing the Euclidean distance between the spectrum of the aggregated series and the sum of the parametric spectra of the components. The extension to long memory stationary models is achieved defining an approximate model where the fractional operator is replaced by the ratio of two polynomials of order one. The feasibility and performance of the proposed procedure are discussed through a case study. 相似文献
82.
石油中饱合烃类的喇曼特征 总被引:6,自引:0,他引:6
本文试通过一些饱合烃类标样的喇曼分析,总结出石油中饱和烷烃组分的最大喇曼特征是在2700~2970 cm-1区域有一系列强烈的喇曼效应,有三种情况:1)直链烷烃类是以—CH3链基对称喇曼效应(约2872 cm-1)最强;2)带异构骨架链烷烃类是以—CH链基喇曼效应(约2911 cm-1)最强;3)环烷烃类是以—CH2链基对称喇曼效应(约2857 cm-1)最强。另外异构骨架在748 cm-1处有一强的喇曼效应,烷烃环基在804 cm-1处有一个强的喇曼效应。并发现不同的烃或烃混合物,若结构基团相同,喇曼谱图也相同;在混合烃组分(或烃类包裹体)的喇曼谱图中2905~2921 cm-1间喇曼峰应是—CH基团,而不能单作甲烷存在的证据。 相似文献
83.
Seismic Moment Tensor Resolution on a Local Scale: Simulated Rockburst and Mine-induced Seismic Events in the Kopanang Gold Mine, South Africa 总被引:2,自引:0,他引:2
Seismic records contain information about the effect of the source as well as the effect of wave propagation through the rock
mass. The effect of wave propagation is usually not well known as only simplified models of geological structures are available.
Therefore, the information about the source retrieved by inverting seismograms may include errors due to incomplete knowledge
of the rock mass along the propagation path, which in turn cause a distortion in the calculated moment tensor (MT). The distortion
of the MT on a local scale was observed by inverting records of a simulated rockburst conducted at the Kopanang gold mine
in South Africa. A dominant isotropic component of the explosive characteristics was found from the inversion. The deviatoric
components retrieved from the blast are spurious. A test of their stability indicated that they are not significant, assuming
an uncertainty above 5% for velocities and 10% for attenuation within the homogeneous model available for the mine. Thus,
the retrieval of the MT from records of local networks in mines using a homogeneous model of the rock mass seems to be feasible.
However, the homogeneous model of the rock mass can only be applied to close stations, within a few kilometers of the source.
The seismic records from distant stations were too complex to be modelled by a homogeneous rock mass. Records of six mine-induced
seismic events recorded at the Kopanang gold mine were also inverted. A vertical linear dipole along the pressure (P) axis
was found for three of the events, suggesting a pillar burst. The mechanism of two events contains an isotropic implosion
together with a nearly vertical dip-slip, and seems to indicate a combination of a cavity collapse with a down dip-slip along
a nearly vertical fault. One event corresponds to a dipole along the tensional (T) axis. However, it is vertical, thus its
association with tensile faulting of the hangingwall is uncertain. 相似文献
84.
Distribution and Geochemical Implication of Aromatic Hydrocarbons across the Meishan Permian-Triassic Boundary 总被引:5,自引:0,他引:5
INTRODUCTIONThe Permian-Triassic ( Tr/P) boundary , datedto be (251 .4±0 .3) Ma ago ,is marked by the mostdrastic mass extinction of organisms in the Phanero-zoic .In order to explore the pattern and the cause ofthe mass extinction,extensive research has been fo-cused on biostratigraphy , isotopic chronostratigra-phy , event stratigraphy , ecostratigraphy and se-quence stratigraphy (Payne et al .,2004 ; Reichowetal .,2002 ; Yin et al .,2001 ;Jin et al .,2000 ;Zhanget al .,1996 ,1995 ;… 相似文献
85.
基于虚拟观测的病态问题解法 总被引:2,自引:0,他引:2
在大地测量数据处理领域中,处理病态问题的主要方法有:岭估计方法、奇异值分解法(SVD)、Tik-honov正则化方法等,但是这些方法大多数是强调数学上的意义,没有充分联系大地测量的实际情况,因此不利于在测绘领域病态问题本质的理解和研究。为使病态问题的求解具有实际的物理意义,提出了基于虚拟观测的岭估计方法。该方法将先验约束条件作为一类互相独立的虚拟观测值,从而把病态问题转化为测量平差问题,然后运用Helmert方差估计法来确定岭参数。该方法还可以得到的参数之间的权矩阵,用它来代替虚拟观测值的权矩阵,重新对参数进行计算,则实现了该方法向广义岭估计的推广。实际算例分析的结果表明该方法不仅计算简单而且能保证结果精确。 相似文献
86.
87.
88.
对现代松粉的在热模拟过程中生成的甲烷,乙烷,丙烷及干酪根碳同位素分析表明,低温阶段(250℃以下)松粉热模拟生成的甲烷相对较高温阶段生成的甲烷更富集^13C,松粉热模拟残余干酪根松粉原样稍微富集^12C,反映低温阶段的热模拟产物主要来源于相对富集^13C的松粉原生质,高温阶段(300℃以上)松粉热模拟生成的甲烷,乙烷,丙烷的δ^13C值随温度升高而富集^13C,松粉热模拟残余干酪根的碳同位素组成没 相似文献
89.
Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source. 相似文献
90.
Pelagic tar, dissolved/dispersed petroleum hydrocarbons and plastic distribution in the Cretan Sea, Greece 总被引:1,自引:0,他引:1
During the first cruise of R/V ‘Philia’ in July 1997 within the framework of the TALOS programme supported by the Greek Ministry of Physical Planning and Public Works, the sampling of floating tar, litter and sea water for dissolved/dispersed petroleum hydrocarbons (DDPH) was carried out in the Cretan Sea. Analysis of these data has allowed a first assessment of the status of floating marine pollution in the region. DDPH measurements showed a mean concentration of 0.145 μg/l of chrysene equivalents (n = 24). Tar and plastics concentrations were in the range of 1–4280 and 0–1160 μg/m2, respectively. Mean pelagic tar concentration was 318 μg/m2, more than two times higher than what was reported for the area in previous studies. Based on in situ hydrographic observations there is strong evidence that most of the floating tar enters the Cretan Sea through the Ionian Sea. 相似文献