土壤中铅铜锌镉的吸附特性   总被引：5，自引：0，他引：5  

李玉萍刘晓端  宫辉力 《岩矿测试》2007,26(6):455-459

以徐州王庄矿（WZK）、奎河（KH）、背景-1（BG-1）和背景-2（BG-2）等4个土壤样品为供试对象，加入不同浓度梯度的铅、铜、锌、镉离子，通过静态实验研究了铅、铜、锌、镉的吸附特性。结果表明，土壤对4个重金属的吸附量与加入到土壤中的重金属离子浓度呈正相关性，它们之间大部分满足线性相关关系。在4个土壤样品中加入铅、铜、锌、镉离子的初始浓度比为10：10：10：1时，平衡浓度为Czn〉Ccu〉CPh〉Ccd，吸附量为Scd〉SPh〉Scu〉Szn，4个土壤样品对铅、铜、锌、镉离子的吸附能力依次为WZK〉KH〉BG-2〉BG-1。在所选实验条件下，土壤对铅、铜、锌、镉的吸附能力受土壤中铅、铜、锌、镉的含量、土壤有机质含量、阳离子交换量、土壤饱和含水量和土壤的pH值影响较大。  相似文献   

Organic fraction of the total carbon burial flux deduced from carbon isotopes across the Permo-Triassic boundary at Meishan,Zhejiang Province,China     

Huang Junhua  Luo Genming  Bai Xiao  Tang Xinyan 《Frontiers of Earth Science》2007,1(4):425-430

By combining the carbon cycle model with the records of carbonate and organic (kerogen) carbon isotope, this paper presents the calculation of the fraction of organic carbon burial (f _org) of beds 23–40 at the global boundary stratotype section and point (GSSP) of the Permian-Triassic boundary at Meishan, Zhejiang Province. The resulting calculation produces two episodes of f _org maxima observed to occur at beds 23–24 and 27–29, which respectively corresponds to the two episodic anoxic events indicated by the flourish of green sulfur bacteria. Two episodic f _org minima occurred at beds 25–26 and 32–34, generally coincident with the flourish of cyanobacteria (bed 26 and upper part of beds 29 to 34) as shown by the high value of 2-melthyhopnoanes. It appears that the f _org is related to the redox conditions, with greater f _org values observed under the reductive condition. The relationship between f _org and the total organic carbon (TOC) content was complex. The f _org value was low at some beds with a high TOC content (such as bed 26), while high observed at some beds with a low TOC content (e.g. bed 27). This association infers the important contribution of primary productivity to the TOC content. The original organic burial could be thus calculated through the configuration of the function of the primary productivity and f _org, which can be used to correct the residual TOC measured today. This investigation indicates that compiling the organic-inorganic carbon isotopes with the carbon cycle model favors to understand the fraction of organic carbon burial, providing information for the reconstruction of the coupling among biota, environments and organic burial. Journal of China University of Geosciences, 2007, 32(6): 767–773 [译自: 地球科学—中国地质大学学报]  相似文献   

Principal stages in evolution of Precambrian organic world: Communication 1. Archean and Early Proterozoic     

V. N. Sergeev  M. A. Semikhatov  M. A. Fedonkin  A. F. Veis  N. G. Vorob’eva 《Stratigraphy and Geological Correlation》2007,15(2):141-160

Expounded in this work are the results of critical consideration of published and original data on biologic nature and appearance chronology of different groups of Archean and Lower Proterozoic (3.5–1.65 Ga) paleontological remains known from geological record. Conclusions are substantiated by morphological analysis of structurally preserved microfossils, their facies distribution, and by inferable genesis and principal evolutionary trends of Archean stromatolites. A special attention is paid to variations of organic and carbonate carbon isotope composition in sedimentary successions with paleontological remains and to recent information about discovered, most ancient biomarkers of large groups of organic world. As a result of this approach, a detailed model of Precambrian organic world evolution is suggested.  相似文献   

沁水煤层气田高阶煤解吸气碳同位素分馏特征及其意义   总被引：3，自引：0，他引：3  

胡国艺  李谨  马成华  李志生  张敏  周强 《地学前缘》2007,14(6):267-272

沁水盆地是我国煤层气勘探开发的重要有利区,沁水煤层气田位于盆地东南部。对采自沁水煤层气田两口井的煤开展了罐解吸实验。结果表明,该地区煤层气解吸速率很快,96 h后解吸气量都达到了总解吸气量的60%~85%,720 h后解吸过程基本结束;解吸气量大,平均在18 m3/t以上。煤层气解吸过程中甲烷发生碳同位素分馏,δ13C1值变化与解吸率呈良好的线性关系,参考这种正相关关系曲线,定期监视煤层气降压排采过程中甲烷δ13C1值的变化情况,可以大致推测出该地区煤层气解吸率,从而预测煤层气的采出程度。跟踪测试沁水煤层气田A1和A1-3井在试采过程的甲烷δ13C1变化情况,推测现在采出的煤层气可能主要是煤层裂隙中以游离形式存在的煤层气,表明该区煤层气稳产性较好,资源前景广阔。  相似文献   

Stable isotope characteristics and origin of ore-forming fluids in copper-gold-polymetallic deposits within strike-slip pull-apart basin of Weishan-Yongping continental collision orogenic belt, Yunnan Province, China     

Wang Yong  Hou Zengqian  Mo Xuanxue  Dong Fangliu  Bi Xianmei  Zeng Pusheng 《Frontiers of Earth Science》2007,1(3):322-332

More than 140 middle-small sized deposits or minerals are present in the Weishan-Yongping ore concentration area which is located in the southern part of a typical Lanping strike-slip and pull-apart basin. It has plenty of mineral resources derived from the collision between the Indian and Asian plates. The ore-forming fluid system in the Weishan-Yongping ore concentration area can be divided into two subsystems, namely, the Zijinshan subsystem and Gonglang arc subsystem. The ore-forming fluids of Cu, Co deposits in the Gonglang arc fluid subsystem have δD values between −83.8‰ and −69‰, δ¹⁸O values between 4.17‰ and 10.45‰, and δ¹³C values between −13.6‰ and 3.7‰, suggesting that the ore-forming fluids of Cu, Co deposits were derived mainly from magmatic water and partly from formation water. The ore-forming fluids of Au, Pb, Zn, Fe deposits in the Zijinshan subsystem have δD values between −117.4‰ and −76‰, δ¹⁸O values between 5.32‰ and 9.56‰, and Δ¹³C values between −10.07‰ and −1.5‰. The ore-forming fluids of Sb deposits have δD values between −95‰ and −78‰, δ¹⁸O values between 4.5‰ and 32.3‰, and Δ¹³C values between −26.4‰ and −1.9‰. Hence, the ore-forming fluids of the Zijinshan subsystem must have been derived mainly from formation water and partly from magmatic water. Affected by the collision between the Indian and Asian plates, ore-forming fluids in Weishan-Yongping basin migrated considerably from southwest to northeast. At first, the Gonglang arc subsystem with high temperature and high salinity was formed. With the development of the ore-forming fluids, the Zijinshan subsystem with lower temperature and lower salinity was subsequently formed. Translated from Mineral Deposits, 2006, 25(1): 60–70 [译自: 矿床地质]  相似文献   

Spatial distribution characteristics of stable carbon isotope compositions in desert plant Reaumuria soongorica (Pall.) Maxim     

Ma Jianying  Chen Fahu  Zhang Huiwen  Xia Dunsheng 《Frontiers of Earth Science》2007,1(2):150-156

In order to investigate the distribution characteristics of stable carbon isotope ratios (δ ¹³C) in the desert plant Reaumuria soongorica, the δ ¹³C values of leaves were measured in 407 individuals of 21 populations. Soil physicochemical properties including soil water content, soil total dissolved solids, soil total nitrogen, soil total phosphorus and soil organic content were also analyzed in order to survey the major factors influencing δ ¹³C values on spatial variation. Leaves and soil samples were simultaneously collected from the ten major distribution areas in Northwest China at altitudes from 394 m to 1 987 m above sea level, at latitudes from 36°10′N to 44°33′N, and at longitudes from 81°43′E to 106°37′E. These ten areas include Shihezi, Baicheng, Yiwu areas in Xinjiang Uygur Autonomous Region; Anxi, Zhangye, Baiyin, Lanzhou areas in Gansu Province; Shapotou, Yinchuan areas in Ningxia Hui Autonomous Region; and Alashan County in Inner Mongolia Autonomous Region. The results show that the δ ¹³C value of R. soongorica ranges from −22.77‰ to −29.85‰ with an average of −26.52‰. Foliar d13C values in R. soongorica are not significantly correlated with altitude, latitude or longitude, and a spatial distribution trend of d13C values of R. soongorica is not obvious on a large scale. However, when d13C values of two R. soongorica populations under the same climate conditions are compared, δ ¹³C values increase obviously from east to west and from north to south. As none of the soil total dissolved solids, soil total nitrogen, soil total phosphorus, and soil organic content shows a uniform trend from east to west and from north to south, we suppose that the small-scaled spatial distribution pattern of δ ¹³C values of R. soongorica is mainly controlled by the soil water content. Translated from Quaternary Sciences, 2006, 26(6): 947–954 [译自: 第四纪研究]  相似文献   

Zircon age and Nd–Hf isotopic composition of the Yunnan Tethyan belt,southwestern China     

Fukun Chen  Xiang-Hui Li  Xiu-Li Wang  Qiu-Li Li  Wolfgang Siebel 《International Journal of Earth Sciences》2007,96(6):1179-1194

The Baoshan block of the Tethyan Yunnan, southwestern China, is considered as northern part of the Sibumasu microcontinent. Basement of this block that comprises presumably greenschist-facies Neoproterozoic metamorphic rocks is covered by Paleozoic to Mesozoic low-grade metamorphic sedimentary rocks. This study presents zircon ages and Nd–Hf isotopic composition of granites generated from crustal reworking to reveal geochemical feature of the underlying basement. Dating results obtained using the single zircon U–Pb isotopic dilution method show that granites exposed in the study area formed in early Paleozoic (about 470 Ma; Pingdajie granite) and in late Yanshanian (about 78–61 Ma, Late Cretaceous to Early Tertiary; Huataolin granite). The early Paleozoic granite contains Archean to Mesoproterozoic inherited zircons and the late Yanshanian granite contains late Proterozoic to early Paleozoic zircon cores. Both granites have similar geochemical and Nd–Hf isotopic charateristics, indicating similar magma sources. They have whole-rock T _DM(Nd) values of around 2,000 Ma and zircon T _DM(Hf) values clustering around 1,900–1,800 and 1,600–1,400 Ma. The Nd–Hf isotopic data imply Paleoproterozoic to Mesoproterozoic crustal material as the major components of the underlying basement, being consistent with a derivation from Archean and Paleoproterozoic terrains of India or NW Australia. Both granites formed in two different tectonic events similarly originated from intra-crustal reworking. Temporally, the late Yanshanian magmatism is probably related to the closure of the Neotethys ocean. The early Paleozoic magmatism traced in the Baoshan block indicates a comparable history of the basements during early Paleozoic between the SE Asia and the western Tethyan belt, such as the basement outcrops in the Alpine belt and probably in the European Variscides that are considered as continental blocks drifting from Gondwana prior to or simultaneously with those of the SE Asia.  相似文献   

Buckling of Piles under Liquefied Soil Conditions     

K. Shanker  P. K. Basudhar  N. R. Patra 《Geotechnical and Geological Engineering》2007,25(3):303-313

The paper pertains to the analysis of piles embedded in liquefiable soils to predict its’ critical buckling load under partial to full loss of lateral support over a portion of the pile length. The analysis is based on extension of Mindlin solution for a point load acting inside a semi infinite elastic half space. Degenerated solutions obtained by using the developed method compares very well with reported results. Parametric studies showed that the depth of liquefiable soil, degradation of soil strength on liquefaction, slenderness ratio, pile stiffness factor and end conditions have significant influence on the buckling behavior of the piles.  相似文献   

水盐梯度下黄河三角洲湿地植被空间分异规律的定量分析   总被引：11，自引：1，他引：11  

贺强  崔保山  赵欣胜  付华龄  熊雄  冯光海 《湿地科学》2007,5(3):208-214

三角洲湿地植被的形成和分布同时受水深、土壤含盐量两个环境因子的作用。采用模糊数学排序方法分析了黄河三角洲湿地植被在水深、土壤含盐量两个环境梯度下的空间分异规律。结果表明,由TWINSPAN划分而得到的8个植被类型在模糊数学排序图中有各自的分布范围,界线明显。以穗状狐尾藻(Myriophyllum spica-tum)等水生植物为优势种的群落分布在排序图的左上部,为黄河三角洲湿地高水深、低盐分地区;以柽柳(Tam-arix chinensis)、翅碱蓬(Suaeda heteroptera)等典型盐生植物为优势种的群落分布在排序图的右下部,为黄河三角洲的低水深、高盐分地区;其他以芦苇(Phragmites australis)、荻(Triarrhena sacchariflora)、旱柳(Salix matsudana)等为优势种的群落分布在排序图的中部。利用Gini-Simpson指数,在模糊数学排序图中分析了植物物种多样性随水深、土壤含盐量梯度的空间变化,结果表明,高水深、低盐分和低水深、高盐分地区植物物种多样性均较低,而二者过渡区域植物物种多样性较高。  相似文献   

腾格里沙漠东南缘白刺灌丛地土壤性状的特征   总被引：7，自引：0，他引：7  

贾晓红  李新荣  陈应武 《干旱区地理》2007,30(4):57-564

腾格里沙漠东南缘白刺灌丛地土壤颗粒组成中仍以细沙粒(0.25～0.05 mm)含量占主要成分(80%～99%),除固定沙堆土0～5 cm土壤粉沙粒含量高于堆间低地外,沙堆土不同深度粉沙粒含量(0.05～0.002 mm)均低于堆间低地;沙堆不同部位的土壤含水量有一致的变化趋势且差异不大,沙堆0～60 cm土层含水量低于堆间低地,60 cm以下的土壤含水量不仅高于0～60 cm,并且高于堆间低地。发育于草甸盐土上的堆间低地20 cm以下水分含量变化基本保持在较高的水平,发育于盐化半固定风沙土上的堆间低地水分含量在20 cm以下呈急剧降低趋势。白刺沙堆上土壤剖面土壤水分含量的这种变化和堆间低地20 cm处较高的含水层,将会为灌丛植物在年内气候干旱期的生命维持提供着重要水源保证。土壤容重白刺沙堆大于堆间低地,土壤剖面堆间低地的容重基本无变异,而沙堆上因为植物发育土壤容重有不同程度的差异。表征土壤肥力和保肥能力的阳离子代换量均是堆间低地大于沙堆上。堆间低地和沙堆上土壤全氮、有机质、电导率含量和pH值差异因白刺沙堆发育的生境不同而不同,处于半固定沙地生境的白刺沙堆并未形成灌丛的"沃岛效应",处于固定沙地生境的白刺沙堆有弱"沃岛效应"。因此,白刺沙堆地表物质的固定是该植物种生长的生境产生"沃岛效应"的前提。  相似文献