Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists   总被引：2，自引：0，他引：2  

YANG  JIAN-JUN; POWELL  ROGER 《Journal of Petrology》2006,47(10):2047-2071

Pressure–temperature grids in the system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O and its subsystems have been calculatedin the range 15–45 kbar and 550–900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressure–temperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H₂O-carriersin subducting slabs. Depending on bulk composition and pressure–temperaturepath, amphibole may or may not be a major H₂O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H₂O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists  相似文献   

The Physico-Chemical Properties of a Subducted Slab from Garnet Zonation Patterns (Sesia Zone, Western Alps)   总被引：3，自引：0，他引：3  

KONRAD-SCHMOLKE  MATTHIAS; BABIST  JOCHEN; HANDY  MARK R.; O'BRIEN  PATRICK J. 《Journal of Petrology》2006,47(11):2123-2148

Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high P–Tconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed P–T paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling  相似文献   

Ca-rich Garnet-Clinopyroxene Rocks at Hujialin in the Su-Lu Terrane (Eastern China): Deeply Subducted Arc Cumulates?   总被引：3，自引：0，他引：3  

YANG  JIAN-JUN 《Journal of Petrology》2006,47(5):965-990

Layers of Ca-rich garnet–clinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the Su–Lu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards Fe–Ti gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crust–mantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped P–T pathsfor the garnet–clinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnet–clinopyroxene rocks; Su–Lu terrane; UHP metamorphism  相似文献   

中国大陆科学钻探工程主孔榴辉岩的岩石学研究   总被引：19，自引：0，他引：19       下载免费PDF全文

张泽明张金凤  许志琴刘福来杨经绥  肖益林沈 昆 《中国地质》2005,32(2):205-217

中国大陆科学钻探工程5000m主孔位于苏鲁超高压变质带南部。该钻孔0～2000m主要由榴辉岩、片麻岩、石榴石橄榄岩和少量片岩和石英岩组成。累积厚度达1000多米的榴辉岩具有不同的矿物组成、不同的矿物含量和不同的全岩化学成分,可划分成富Si的石英榴辉岩、富Ti的金红石榴辉岩、富Al的多硅白云母和蓝晶石榴辉岩、富Mg的双矿物榴辉岩和具有正常玄武岩成分的普通榴辉岩。榴辉岩的原岩包括基性层状侵入岩和变质表壳岩。榴辉岩全岩成分对石榴石和绿辉石中某些化学组分的含量有明显控制,而且直接影响到变质条件估算的准确性。扩散成分环带的广泛发育表明超高压矿物在早期退变质过程中发生了成分再平衡。这一事实以及具有成分生长环带石榴石变斑晶的存在,为榴辉岩形成在更高温度(>940℃)和更高压力(>4.5GPa)条件下提供了有力的证据。  相似文献   

一次“高影响天气”的弱降雪过程的数值研究   总被引：11，自引：2，他引：11       下载免费PDF全文

蒋建莹史历  倪允琪 《应用气象学报》2005,16(2):231-237

该文对2001年12月7日下午北京的一次弱降雪天气过程进行了诊断分析和数值模拟研究。诊断结果表明:北京地区由于受500 hPa小槽东移及850 hPa东移小高压后部带来的来自东海和南海的偏南暖湿气流共同影响，造成降雪。数值模拟结果显示:MM5模式对这次降雪过程具有较好的模拟能力，不仅模拟出了北京地区的降雪量，而且对这次过程大尺度背景场的演变、触发机制和水汽源有很好的表述。利用诊断分析和数值模拟结果，对这次弱降雪过程引起交通大阻塞的可能因素进行了探讨，说明建立城市预警系统的迫切性。  相似文献   

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change   总被引：3，自引：0，他引：3  

Marc J. Metzger  Rik Leemans  Dagmar Schrter 《International Journal of Applied Earth Observation and Geoinformation》2005,7(4):253-267

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.  相似文献   

近十年来我国气候变暖影响研究的若干进展   总被引：51，自引：12，他引：51       下载免费PDF全文

王馥棠 《应用气象学报》2002,13(6):755-766

近年来，我国政府和科技界十分关注气候王馥棠变暖对我国经济发展可能影响的评估, 开展了许多重大项目和课题的研究。该文仅就气候变暖对我国自然植被、农业、森林、水资源、能源利用和区域海平面上升等领域影响评估研究的若干有意义的初步结果简要归纳和评述如下:取自不同GCM模型的未来气候变化情景下的影响评估模拟表明，我国的特征性自然植被类型将会发生明显的变化。同当前气候（1951~1980年）下的模拟分布相比，到2050年我国几乎所有地方的农业种植制度均将发生较大变化；气候变暖将导致复种指数增加和种植方式多样化，但降水与蒸散之间可能出现的负平衡和土壤水分胁迫的增加以及生育期的可能缩短，最终将导致我国主要作物的产量下降。气候变暖对我国水资源最明显的影响将会发生在黄淮海流域，这个区域的水资源供需短缺将大大提高。同时，气候变暖将改变我国室内取暖和降温的能源需求关系:北方冬季取暖的能源消耗将减少, 而南方夏季降温的能源消耗将会增加。海平面的上升将使我国三个主要沿海低洼脆弱区，即珠江三角洲、长江三角洲和黄河三角洲，面临部分遭受海水淹没的威胁。  相似文献   

赣北中元古界双桥山群低变质强变形行为与格林威尔期造山作用   总被引：4，自引：1，他引：4  

秦松贤  章泽军  张志  赵温霞  蔡雄飞  顾延生 《地质科技情报》2002,21(2):8-12

广泛分布于赣北地区的中元古界双桥山群，以低级区域变质作用、强烈构造变形、具陆内造山带构造变形特征；其成果系在华夏古陆与扬子古陆的碰撞拼接过程中，其应力向陆内传递的结果；时间大致在1100－800Ma，与全球格林威尔期造山作用相当。  相似文献   

High-T, low-P metamorphism in the Palaeoproterozoic Halls Creek Orogen, northern Australia: the middle crustal response to a mantle-related transient thermal pulse   总被引：1，自引：1，他引：1  

S. Bodorkos  M. Sandiford  N. H. S. Oliver  P. A. Cawood 《Journal of Metamorphic Geology》2002,20(2):217-237

High‐T, low‐P metamorphic rocks of the Palaeoproterozoic central Halls Creek Orogen in northern Australia are characterised by low radiogenic heat production, high upper crustal thermal gradients (locally exceeding 40 °C km^?1) sustained for over 30 Myr, and a large number of layered mafic‐ultramafic intrusions with mantle‐related geochemical signatures. In order to account for this combination of geological and thermal characteristics, we model the middle crustal response to a transient mantle‐related heat pulse resulting from a temporary reduction in the thickness of the mantle lithosphere. This mechanism has the potential to raise mid‐crustal temperatures by 150–400 °C within 10–20 Myr following initiation of the mantle temperature anomaly, via conductive dissipation through the crust. The magnitude and timing of maximum temperatures attained depend strongly on the proximity, duration and lateral extent of the thermal anomaly in the mantle lithosphere, and decrease sharply in response to anomalies that are seated deeper than 50–60 km, maintained for <5 Myr in duration and/or have half‐widths <100 km. Maximum temperatures are also intimately linked to the thermal properties of the model crust, primarily due to their influence on the steady‐state (background) thermal gradient. The amplitudes of temperature increases in the crust are principally a function of depth, and are broadly independent of crustal thermal parameters. Mid‐crustal felsic and mafic plutonism is a predictable consequence of perturbed thermal regimes in the mantle and the lowermost crust, and the advection of voluminous magmas has the potential to raise temperatures in the middle crust very quickly. Although pluton‐related thermal signatures significantly dissipate within <10 Myr (even for very large, high‐temperature intrusive bodies), the interaction of pluton‐ and mantle‐related thermal effects has the potential to maintain host rock temperatures in excess of 400–450 °C for up to 30 Myr in some parts of the mid‐crust. The numerical models presented here support the notion that transient mantle‐related heat sources have the capacity to contribute significantly to the thermal budget of metamorphism in high‐T, low‐P metamorphic belts, especially in those characterised by low surface heat flow, very high peak metamorphic geothermal gradients and abundant mafic intrusions.  相似文献   

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes   总被引：7，自引：0，他引：7  

M. Satish-Kumar  H. Wada  M. Santosh 《Journal of Metamorphic Geology》2002,20(3):335-350

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.  相似文献