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11.
J. M. Macpherson 《新西兰海洋与淡水研究杂志》2013,47(1):25-39
Okarito Lagoon (43° 11′S, 170° 14′E) is a small (20 km2) shore‐parallel, predominantly subtidal estuary, deepest near the landward end, and linked to the sea by two subtidal channels incised through shallow subtidal and intertidal flats which occupy the southern third of the lagoon. Tides at sea vary from 2.1m (spring) to 1.2 m (neap), but in the lagoon the tidal range is constant through the lunar cycle and varies from 0.80 m at the entrance to 0.17 m in the upper lagoon. Tidal water level and flow asymmetries in the subtidal channels are separated by a 1.7 h phase difference. Variations in the net discharge through the inlet result from changing flow cross‐sections rather than from variations in current velocities. Both the tidal‐averaged volume and the tidal compartment of the lagoon vary through the lunar cycle, from maxima at spring tides to minima at neap tides. Freshwater inflows vary from less than 11 m3.s‐1 to more than 750 m3.s‐1. During storms, water level in the lagoon rises rapidly by 2–3 m, then declines to normal over several days. Three water masses, two with salinity and turbidity largely controlled by antecedent rainfall, normally occur in the lagoon. Suspended sediment concentrations in both freshwater inflows and lagoon waters are normally low but increase during floods. Most sediment is supplied by the Waitangi‐taona River or by erosion of tidal channel margins. The lagoon is floored with organic‐rich mud and sandy mud, deposited predominantly from suspension. Surface sediment is consistently muddier than subsurface sediment, probably reflecting an increase in the mud supply since diversion of the Waitangi‐taona River in 1967. Comparisons of the estimated sediment yield and water inflow effects of the 1967 river diversion with short‐term observations during selective logging suggest that the effects of logging on sediment yield, water balance of the lagoon, and dissolved solids inputs will be small compared with changes caused by diversion of the Waitangi‐taona River. 相似文献
12.
Elisabete S. Braga Vitor C. Chiozzini Gláucia B.B. Berbel João C.C. Maluf Valquíria M.C. Aguiar Marcela Charo Daniel Molina Sílvia I. Romero Beatriz B. Eichler 《Continental Shelf Research》2008
Nutrient distributions observed at some depths along the continental shelf from 27°05′S (Brazil) to 39°31′S (Argentina) in winter, 2003 and summer, 2004 related to salinity and dissolved oxygen (mL L−1) and saturation (%) data showed remarkable influences of fresh water discharge over the coastal region and in front of the La Plata estuary. In the southern portion of the study area different processes were verified. Upwelling processes caused by ocean dynamics typical of shelf break areas, eddies related to surface dynamics and regeneration processes confirmed by the increase of nutrients and the decrease of dissolved and saturation oxygen data were verified. High silicate concentrations in the surface waters were identified related to low salinities (minimum of 21.22 in winter and 21.96 in summer), confirming the importance of freshwater inputs in this region, especially in winter. Silicate concentration range showed values between 0.00 and 83.52 μM during winter and from 0.00 to 41.16 μM during summer. Phosphate concentrations worked as a secondary trace of terrestrial input and their values varied from 0.00 to 3.30 μM in winter and from 0.03 to 2.26 μM in summer; however, in shallow waters, phosphate indicated more clearly the fresh water influence. The most important information given by nitrate concentrations was the presence of water from SACW upwelling that represents a new source of nutrients for marine primary production. Nitrate maximum values reached 41.96 μM in winter and 33.10 μM in summer. At a depth ∼800 m, high nitrate, phosphate and silicate concentrations were related to Malvinas Current Waters, Subantarctic Shallow Waters and Antarctic Atlantic Intermediate Waters (AAIW). Dissolved oxygen varied from 3.41 to 7.06 mL L−1 in winter and from 2.65 to 6.85 mL L−1 in summer. The percentage of dissolved oxygen saturation in the waters showed values between 48% and 113% in winter and from 46% to135% in summer. The most important primary production was verified in the summer, and situations of undersaturation were mainly observed below 50 m depth and at some points near the coast. The anti-correlation between nutrients and dissolved oxygen which showed evident undersaturation also revealed important potential sites of remineralization processes. The nutrient behaviours showed some aspects of the processes that occur over the Southwestern South Atlantic continental shelf and in their land–sea interfaces between Mar del Plata and Itajaí. 相似文献
13.
Heavy metals in Oka river sediments (Urdaibai National Biosphere Reserve, northern Spain): lithogenic and anthropogenic effects 总被引：2，自引：0，他引：2
The Oka River basin is located in the Urdaibai National Biosphere Reserve, North Spain. In order to obtain a preliminary
view of its environmental conditions, nitric acid extractable Fe, Mn, Zn, Pb, Cu, Cr, Ni and Co, organic matter content (L.O.I.),
geochemical fractionation of heavy metals and mineralogical composition were analysed in surficial sediments (fraction <63 μm)
collected in October 1991. Relatively high concentrations of metals occurred in a sampling site upstream, due to a local natural
enrichment controlled by weathering of volcanic rocks. Geochemical fractionation confirmed the lithogenic origin of metals,
which were mainly associated to the detrital phase. The significant increase of heavy metals found in some samples collected
in the municipal area of Gernika suggested a pollution effect, related to anthropogenic wastes. Large amounts of metallic
slags have been found mixed with the sediments upstream from this locality. Nevertheless, in view of their composition, it
is unlikely that these slags constitute a significant source of heavy metals in the studied area. In a second sampling in
October 1997 an apparent decreasing trend in some heavy metal levels was noted, particularly for Pb and Cu. Nowadays, enrichment
factors relative to background values confirm moderate anthropogenic influence on Zn, Pb, Cu, Cr and Ni concentrations. However,
heavy metal levels in the Oka river sediments are much lower than those detected in other major rivers of the Basque Country
(Nervión, Urumea, Deba).
Received: 7 July 1997 · Accepted: 4 July 1998 相似文献
14.
A small watershed (160 km2) located in the Massif Central (France) has been chemically, isotopically and hydrologically studied through its dissolved load, bed sediments and soils. This watershed is underlain by basaltic bedrock and associated soils in which the vegetation is dominated mainly by meadows.Dissolved concentrations of major ions (Cl, SO4, NO3, HCO3, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been determined for two different hydrologic periods on the main stream of the Allanche river and its tributaries.The major objectives of this study were to characterize the chemical and isotopic signatures of each reservoir occurring in the watershed. Changes in chemical and isotopic signatures are interpreted in terms of fluctuations of the different components inputs: rainwater, weathering products, anthropogenic addition.Water quality may be influenced by natural inputs (rainwater, weathering processes) and anthropogenic additions (fertilizers, road salts, etc.). Precipitation serves as a major vehicle for dissolved chemical species in addition to the hydrosystem and, in order to constrain rain inputs, a systematic study of rainwaters is carried out over a one year period using an automatic collector. Corrections of rainwater addition using chloride as an atmospheric input reference were computed for selected elements and the Sr/Sr ratio. After such corrections, the geochemical budget of the watershed was determined and the role of anthropogenic additions evaluated through the relationship between strontium isotopes and major and trace element ratios. Thus, 10% of Ca and Na originate in rainwater input, 40 to 80% in fertilizer additions and 15 to 50% in rock weatheringThe cationic denudation rates for this watershed are around 0.3 g s–1 km2 during low water discharge and 0.6 g s–1 km2 in high water stage. This led to a chemical denudation rate of 5.3 mm/1000 years.For solid matter, the normalization of chemical species relative to parent rocks shows the depletion or enrichment in soils and sediments. The use of K and Ca as mobile reference illustrates the weathering state of soils and sediments relative to parent rocks. This weathering state for bed sediments range from 15 to 45% for the K normalization and from 2 to 50% for the Ca normalization. For the soils, the weathering state ranges from 15 to 57% for the K normalization and from 17 to 90% for the Ca normalization. 相似文献
15.
《Chemie der Erde / Geochemistry》2014,74(4):691-704
Milazzo Peninsula soils and substrates are extremely variable, composed of acidic, mafic and ultramafic metamorphic rocks, carbonatic sedimentary rocks, and sometimes volcanic rocks, thus contributing to a mixed influence on their chemical composition. Moreover, the region is highly polluted due to atmospheric releases from anthropogenic activities, such as refinery industry. In addition, emissions of airborne particles from volcanic eruptions are also likely to fall to the ground and provide trace elements to the soils. The purpose of this study is to distinguish between anthropogenic and geogenic sources contributing to the concentrations of metals in soils by studying their distribution in major and trace elements in relation to substrates. As regards geogenic sources, the major elements composition of soils comes firstly from metamorphic rocks, secondly from carbonates, and to a minor extent from volcanic rocks. Enrichment factors calculations relative to substrate rocks, and using Th as reference element, show that the soils are enriched in As, Pb, Zn, and Ni. Rare earth elements (REEs) patterns normalized to substrate rocks exhibit enrichment in light REEs and a positive anomaly in Gd, indicating anthropogenic contributions in the soil composition. REE ratios and trace elements were plotted to investigate the relationships between anthropogenic sources and substrates in soils compositions. The graphs of La/Ni vs La/Gd and La/Ce vs La/Nd show that soils plot on a line toward substrate rocks on one side, and toward an end member which is represented by a spent catalyst and atmospheric particles emitted by refinery activities. Plots of La vs Cr, and V vs La show similar trends, whereas plots of Zn vs Ni and Pb vs V suggest that another end member, which is unidentified, contributes to soil enrichment in Zn and Pb. A binary mixing model applied to the most Zn enriched soil suggests that anthropogenic inputs from refinery emissions may have contributed to 16% of the anomalies in La/Gd. These results suggest that the trace element composition of Milazzo's peninsula soils partly bears the signature of atmospheric emissions of the refinery. 相似文献
16.
WANG Xiao-yan CAO Li-ping 《中国地理科学(英文版)》2005,15(4):297-302
1 IN T R O D U C T IO NM ostofthepastw aterm anagem enthasfocused on pointsource pollution,w ith less attention to nonpointsourcepollution.A fterpointsourcesofpollution have been al-ready heavily controlled, nonpoint source pollution(N PSP) has becom e th… 相似文献
17.
O. Martins 《水文研究》1988,2(1):19-29
Water quality analyses for the Niger River for the 1980/81 hydrological year are presented. The samples were collected from the main river at Lokoja, and from two main tributaries, the Kaduna and the Benue Rivers. Different water types were distinguished by the concentrations of major ions. The type Ca > Na > Mg > K - HCO3 > SO4 > Cl was represented at all stations during at least part of the year. Chloride was found to dominate the sulphate ion in the Kaduna and Niger, while the Benue maintained a higher concentration of sulphate relative to chloride all year round. Distinct patterns of seasonal variation in the ion concentrations were observed, particularly for the samples collected at Lokoja. Low ion concentrations were prominent during periods of high discharge, while low flow periods coincided with high dissolved ion concentrations. The contribution of rainwater to the total dissolved solids in the river waters was assessed indirectly using rainwater chemistry data from the Gulf of Guinea. The estimated rainwater contribution to the Lower Niger amounts to 5.15 mg 1?1. Geochemical weathering calculations involving reactions of the four major minerals of granitic rocks - anorthite, biotite, albite, and K-feldspar - with carbon dioxide and water, can account for the average water composition of the Lower Niger. The proportion of the ionic components was also related to the occurrence of the respective element in the minerals. 相似文献
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19.
Elsa Arellano-Torres Astrid J. Mora-Rivera Paola Vázquez-Romero Enrique H. Nava-Sánchez Juan José Kasper-Zubillaga M. Socorro Lozano-García 《第四纪科学杂志》2020,35(3):479-491
We study the marine and terrestrial contributions in the Gulf of California (GC) to understand the relationship between continental climate and oceanographic variability over the last 28 ka. In Core AII125-8-JPC-20, we examine aeolian and riverine inputs as nutrients for biological productivity. We use biogenic silica (%opal), total organic carbon (%TOC) and calcium carbonate (%CaCO3) as proxies for primary productivity, and lithic fraction distributions as proxies for terrigenous transport. At the core site, biogenic and lithic components are in phase at millennial-scale in response to regional climate conditions. During the Late Pleistocene, the GC shelf area was above sea level and the western margin showed transient episodes of increased fluvial inputs. Episodic increases in %opal and reduced %TOC suggest upwelling events but ineffective C-export to the sediment. During stadial events (Heinrich 2, Heinrich 1, Younger Dryas), regional declines in %opal, but increases in %CaCO3 and TOC, suggest efficient C-export by carbonate organisms. During most of the Holocene, dust inputs are higher. Episodic increases in %TOC suggest higher C-accumulation, although this is not controlled by siliceous or calcareous organisms. In the GC, besides upwelling and current advection, nutrient inputs driven by terrestrial climate have an impact on the biological C-pump. © 2020 John Wiley & Sons, Ltd. 相似文献
20.
Maryna Strokal He Yang Yinchen Zhang Carolien Kroeze Lili Li Shengji Luan Huanzhi Wang Shunshun Yang Yisheng Zhang 《Marine pollution bulletin》2014
We analyzed the potential for eutrophication in major seas around China: the Bohai Gulf, Yellow Sea and South China Sea. We model the riverine inputs of nitrogen (N), phosphorus (P) and silica (Si) to coastal seas from 1970 to 2050. Between 1970 and 2000 dissolved N and P inputs to the three seas increased by a factor of 2–5. In contrast, inputs of particulate N and P and dissolved Si, decreased due to damming of rivers. Between 2000 and 2050, the total N and P inputs increase further by 30–200%. Sewage is the dominant source of dissolved N and P in the Bohai Gulf, while agriculture is the primary source in the other seas. In the future, the ratios of Si to N and P decrease, which increases the risk of harmful algal blooms. Sewage treatment may reduce this risk in the Bohai Gulf, and agricultural management in the other seas. 相似文献