铂族元素的表生地球化学研究进展   总被引：2，自引：0，他引：2  

皮道会  邓海琳  李朝阳  朱维光 《矿物岩石地球化学通报》2004,23(4):355-361

基性-超基性岩及黑色页岩等风化过程中铂族元素发生了活化和迁移。铂族元素在岩体附近土壤、植物和水体等表生介质中的迁移富集特征可以用来寻找岩浆型铂族元素矿床。黑色页岩风化过程中，Os的表生迁移对海洋^187Os／^188Os值上升有重要意义。此外，作为重金属元素，机动车铂族元素催化剂在环境中的释放，也会带来潜在的生态环境和人体健康问题。  相似文献   

渤南油田中部古近系沙河街组低渗透储层岩石学和成岩作用   总被引：2，自引：0，他引：2       下载免费PDF全文

李海燕  彭仕宓  黄述旺 《沉积与特提斯地质》2004,24(1):84-90

该区储层岩石类型主要为岩屑质长石砂岩，溶解作用是主要的建设性成岩作用，压实、自生矿物充填和胶结作用是主要的破坏性成岩作用，成岩阶段处于晚成岩A亚期。该区储层较高的孔隙度是晚成岩期强烈的溶解作用形成次生溶孔的结果，而储层砂岩较低渗透率的主要成因机理是成岩期各种自生矿物的充填和胶结作用；此外，溶蚀作用形成的孤立、互不连通的粒间孔也是形成低渗微细喉道储层的主要原因。有利孔隙组合为粒间溶蚀孔-原生粒间孔-粒内破碎缝，有利储层的分布受砂体分布、构造配置及成岩作用的联合控制。  相似文献   

扬子地台西南缘传统型铂族矿产地质特征          下载免费PDF全文

丁俊  杨家瑞 《沉积与特提斯地质》2004,24(3):1-14

传统型铂族矿产，系指与镁铁质岩浆成矿作用有关的铂族矿产资源。华力西运动时期，扬子地台西南缘沿超壳深断裂带发生的大陆裂谷作用，为来自上地幔的镁铁质(拉斑玄武岩质)岩浆的上涌和侵位提供了极为有利的前提条件。含铂基性超基性岩的时空分布，受到大陆裂谷作用的主要发生发展时期和裂谷活动带的控制。通过对典型矿床特征及其成矿作用的探讨，论述了扬子地台西南缘主要的铂族矿床类型；并从四维成矿的角度，阐述了对区域成矿规律的一些基本认识。  相似文献   

辽西北票—义县地区义县旋回火山岩的岩石化学特征   总被引：3，自引：1，他引：3       下载免费PDF全文

彭艳东  张立东  张长捷郭胜哲邢德和  贾斌  陈树旺  丁秋红 《中国地质》2004,31(4):356-364

辽西地区是中国中生代火山岩主要分布区之一。义县组分为4个岩性段。义县火山旋回可分为4个亚旋回。第一亚旋回分为4个小旋回。从早期至晚期，义县旋回火山岩逐渐由基性向中基性、中性和酸性演化，火山岩岩石组合为基性岩-中性岩-酸性岩组合，从北票-义县，火山活动显示了由老到新的迁移性。主要氧化物关系表明岩石的SiO2与K2O呈正相关，SiO2与MgO、CaO、FeO Fe2O3呈负相关。TAS图解反映了火山岩较高碱度的总体特征，硅-碱关系图和AFM图解反映了火山岩属于亚碱性系列中的钙碱性系列岩石，在SiO2-K2O关系图上，绝大部分样品落于高钾钙碱性系列区内，少量落于钾玄岩系列区，因此义县旋回火山岩以高钾钙碱性系列岩石为主，部分为钾玄岩系列，表明岩石富钾。义县旋回火山岩具有大陆板内火山岩的基本特征。  相似文献   

New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity     

N.G Obaje  H Wehner  H Hamza  G Scheeder 《Journal of African Earth Sciences》2004,38(5):339

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.  相似文献   

Charnockitic magmatism in southern India   总被引：2，自引：0，他引：2  

H. M. Rajesh  M. Santosh 《Journal of Earth System Science》2004,113(4):565-585

Large charnockite massifs cover a substantial portion of the southern Indian granulite terrain. The older (late Archaean to early Proterozoic) charnockites occur in the northern part and the younger (late Proterozoic) charnockites occur in the southern part of this high-grade terrain. Among these, the older Biligirirangan hill, Shevroy hill and Nilgiri hill massifs are intermediate charnockites, with Pallavaram massif consisting dominantly of felsic charnockites. The charnockite massifs from northern Kerala and Cardamom hill show spatial association of intermediate and felsic charnockites, with the youngest Nagercoil massif consisting of felsic charnockites. Their igneous parentage is evident from a combination of features including field relations, mineralogy, petrography, thermobarometry, as well as distinct chemical features. The southern Indian charnockite massifs show similarity with high-Ba-Sr granitoids, with the tonalitic intermediate charnockites showing similarity with high-Ba-Sr granitoids with low K₂O/Na₂O ratios, and the felsic charnockites showing similarity with high-Ba-Sr granitoids with high K₂O/Na₂O ratios. A two-stage model is suggested for the formation of these charnockites. During the first stage there was a period of basalt underplating, with the ponding of alkaline mafic magmas. Partial melting of this mafic lower crust formed the charnockitic magmas. Here emplacement of basalt with low water content would lead to dehydration melting of the lower crust forming intermediate charnockites. Conversely, emplacement of hydrous basalt would result in melting at higher {ie565-01} favoring production of more siliceous felsic charnockites. This model is correlated with two crustal thickening phases in southern India, one related to the accretion of the older crustal blocks on to the Archaean craton to the north and the other probably related to the collision between crustal fragments of East and West Gondwana in a supercontinent framework.  相似文献   

Metamorphic evolution of garnet-bearing ultramafic rocks from the Gongen area, Sanbagawa belt, Japan   总被引：2，自引：0，他引：2  

M. Enami  T. Mizukami  K. Yokoyama 《Journal of Metamorphic Geology》2004,22(1):1-15

Garnet‐bearing ultramafic rocks including clinopyroxenite, wehrlite and websterite locally crop out in the Higashi‐akaishi peridotite of the Besshi region in the Cretaceous Sanbagawa metamorphic belt. These rock types occur within dunite as lenses, boudins or layers with a thickness ranging from a few centimetres to 1 metre. The wide and systematic variation of bulk‐rock composition and the overall layered structure imply that the ultramafic complex originated as a cumulate sequence. Garnet and other major silicates contain rare inclusions of edenitic amphibole, chlorite and magnetite, implying equilibrium at relatively low P–T conditions during prograde metamorphism. Orthopyroxene coexisting with garnet shows bell‐shaped Al zoning with a continuous decrease of Al from the core towards the rim, consistent with rims recording peak metamorphic conditions. Estimated P–T conditions using core and rim compositions of orthopyroxene are 1.5–2.4 GPa/700–800 °C and 2.9–3.8 GPa/700–810 °C, respectively, implying a high P/T gradient (> 3.1 GPa/100 °C) during prograde metamorphism. The presence of relatively low P–T conditions at an early stage of metamorphism and the steep P/T gradient together trace a concave upwards P–T path that shows increasing P/T with higher T, similar to P–T paths reported from other UHP metamorphic terranes. These results suggest either (1) down dragging of hydrated mantle cumulate parallel to the slab–wedge interface in the subduction zone by mechanical coupling with the subducting slab or (2) ocean floor metamorphism and/or serpentinization at early stage of subduction of oceanic lithosphere and ensuing HP–UHP prograde metamorphism.  相似文献   

Occurrence of Halogen-rich Phlogopite in Late Cenozoic Volcanic Rocks in the Japanese Arcs     

Akira Imai 《Resource Geology》2004,54(2):153-166

Abstract. Halogen-rich phlogopite occurs in the groundmass of andesite and dacite lavas from Late Tertiary to Quaternary volcanoes associated with native sulfur and limonite deposits (Shiretoko-Iwozan, Hachimantai, Adatara, Omeshidake, Masaki) and hydrothermal ore deposits (Harukayama, Muineyama, Hishikari) in Japan. The F contents of the halogen-rich phlogopite range from 3.6 to 5.7 wt%, corresponding to atomic F/(F+C1+OH) ratios ranging from 0.45 to 0.69. On the other hand, the Cl contents of the halogen-rich phlogopite are around 0.2 wt%. The atomic Mg/(Mg+Fe) ratios range from 0.69 to 0.83.
The fluorine intercept value [IV(F)] defined by Munoz (1984) of the phlogopites ranges from 0.79 to 3.17, and the chlorine intercept value [IV(Cl)] ranges from -7.11 to -7.77. The observed IV(F) of the phlogopites broadly overlap the range of the IV(F) for biotites from porphyry copper deposits. On the other hand, the observed IV(Cl) are significantly lower than the IV(Cl) for biotites from porphyry copper deposits. Whereas the F contents of the phlogopite appear more prominent compared to the Cl contents, the calculation of halogen intercept values revealed that the phlogopites are enriched in Cl with respect to the element distribution effect of Mg-Fe substitution. Since the degree of Cl enrichment of the phlogopite is more significant compared to that of biotite in porphyry copper deposits, the phlogopites are considered to have formed under the condition of significantly high activity of halogens. Hydrothermal ore deposits may be formed in magmatic hydrothermal system associated with volcanoes where halogen-rich phlogopite is formed by hypersaline fluid.  相似文献   

北京延庆北部地区后城组火山岩岩石化学特征与成因探讨   总被引：3，自引：0，他引：3  

汪洋  姬广义 《城市地质》2004,16(1):16-25

根据TAS图解 ,北京延庆北部地区后城组火山属于玄武粗安岩 流纹岩 (和粗面岩 )的双峰式组合。该套火山岩不属于典型的钾玄岩系列 ,在基性岩和中性岩中总体上以碱性系列和向碱性系列过渡的高钾钙碱性系列、钾玄岩系列为主 ,流纹岩类属于富钾质的拉斑系列。该套火山岩轻稀土元素明显富集。玄武粗安岩类岩石没有负铕异常或负铕异常不明显 ,而流纹岩存在明显的负铕异常。延庆北部地区后城组火山岩形成于燕山运动早期或中期阶段的造山变形事件趋于结束时的后碰撞构造环境中。  相似文献   

Pressure State in Deep Crust and Formation Depth of UHP Metamorphic Rocks     

Lü Guxian 《中国地质大学学报(英文版)》2004,15(2):135-144

INTRODUCTIONSincethediscoveryofeclogiteswithcoesiteanddia mondinclusionsrelatedtothecontinent continentcollision orogenyenvironment,theultrahigh pressuremetamorphism(UHPM )intheDabie Suluhasarousedgreatinterestinmanygeologists (Liouetal .,1994 ;Xuetal.,1992 ) .Experimentalstudieshaveprovedthatsuchmineralsasdia mond ,coesiteandomphaciteoccurredat 2 - 5GPa (andatthecorrespondingtemperatures) (Stevenetal.,1982 ;MirwaldandMasonne ,1980 ) .However,itdoesnotmeanthatthemetamorphicrockscanbe…  相似文献