应用激光诱导离解光谱自由定标法测定黄金首饰成分初探     

涂彩  袁心强 《地质科学译丛》2011,(4):1-6

利用激光诱导离解光谱自由定标法对一系列高纯度黄金样品进行定量分析与研究,初步证明了将此方法应用于黄金首饰成分测定的可行性。采用波长1 064nm的Nd∶YAG脉冲激光器激发黄金样品,波长范围为200～760nm的4CCD光纤光谱仪采集发射光谱,对Au元素质量分数范围为85.0%～99.6%的6件黄金标准样品进行激光诱导离解光谱测试。对所得黄金样品光谱中的Au,Cu,Ag三种元素分别选择合适的原子（离子）谱线代入自由定标法模型,通过所得参数拟合得到了所有元素原子（离子）的二维波尔兹曼平面曲线,并以此为基础进行元素的质量分数计算。激光诱导离解光谱自由定标法定量分析黄金样品中Au元素的质量分数与标准值的相对误差〈3%。  相似文献   

Si含量对镍基合金氧化保护膜影响机制的研究     

初蕾  刘英才  梁丹维  尹衍升  王昕 《中国海洋大学学报(自然科学版)》2011,(Z1):291-294

本文对镍基合金中Si在弱氧化环境下表面氧化成膜特性进行了研究。利用XRD、SEM、EDS等检测手段对试样进行了检测分析,结果发现:合金表面氧化膜的形成动力学对镍基合金的Si含量非常敏感。当合金元素Si的含量较高时,由于连续的非晶SiO2膜在表层氧化铬与奥氏体基体之间的富集阻碍了Cr离子的向外扩散,导致在奥氏体区之上形成了较薄的氧化铬膜;共晶组织区域由于不会形成连续的SiO2非晶膜,仍然可以作为Cr离子的快速扩散通道,使得在该组织区域形成大量的脊状氧化物。奥氏体组织之上的氧化膜厚度与基体的Si含量成反比。  相似文献   

以镁、锌、铝为主要合金元素的应用合金研究进展          下载免费PDF全文

李明珍  王世栋  叶秀深  李权  吴志坚  火焱Symbol`@@ 《盐湖研究》2015,(4):66-71

以镁、铝、锌为主要合金元素的镁铝合金材料是轻合金的基础,评述了镁合金和铝合金的优缺点及应用概况,介绍了Zn、RE、Mn、Cu等主要元素对合金微观组织、铸造性能、力学性能和抗腐蚀性能的影响。随着轻合金综合性能不断提高和改进,其应用前景更加广阔。  相似文献   

煤矿用钛合金无磁钻杆的中试研究          下载免费PDF全文

郭青  芦苇  肖丽辉 《探矿工程》2014,41(3):52-55

目前,国内外煤矿坑道水平定向钻探用无磁钻杆材料均选用铍铜QBe2（ C17200）,该合金材料的延伸率低,钻杆易出现断裂事故。为解决这一问题,研究了高强度钛合金钻杆,探讨了钻杆的材料选择及螺纹结构设计。试验了钻杆的加厚工艺,其强度达到了设计要求,并通过现场试验验证了钻杆的使用效果。  相似文献   

铬的迁移形式、成矿机理新探          下载免费PDF全文

郑大中  郑若锋 《地质找矿论丛》2012,27(1):1-8

通过对地球深部富氢流体、若干金属氢化物及合金氢化物的形成条件与性质、铬矿物的化学成分及其共生伴生矿物的研讨,结合铬铁矿成矿的地质背景,认为铬氢化物、铬合金氢化物是铬成矿的主要迁移形式。它们从地球深部富氢强还原环境随岩浆迁移至地壳浅部,由于H2,CO,CH4等逃逸、氧化,氧逸度大增,温度、压力下降,铬氢化物和铬合金氢化物分解、氧化、固化富集成铬矿床。  相似文献   

津巴布韦舒鲁圭透镜状铬铁矿成因          下载免费PDF全文

王铁军  刘晓阳  林锐华  杨秀峰 《地质找矿论丛》2012,27(4):485-490

通过对津巴布韦舒鲁圭透镜状铬铁矿地质背景、构造控矿特征、矿体赋存空间特征、蚀变岩组合、矿石结构构造特征的总结分析,提出舒鲁圭铬铁矿流体成矿假说,认为太古宙超基性杂岩侵入的同时,富含铬合金氢化物的H2-CH4超临界流体沿构造带侵入到地壳浅部,并与构造带内水混合,水与铬合金氢化物发生化学反应,产生的铬尖晶石沉淀在构造带内,形成透镜状铬铁矿体。  相似文献   

Shaking table tests of steel frame with superelastic Cu–Al–Mn SMA tension braces          下载免费PDF全文

Yoshikazu Araki  Kshitij C. Shrestha  Nao Maekawa  Yuji Koetaka  Toshihiro Omori  Ryosuke Kainuma 《地震工程与结构动力学》2016,45(2):297-314

Shaking table tests are performed on a one‐bay one‐story steel frame with superelastic Cu–Al–Mn shape memory alloy (SMA) tension braces. The frame is subjected to a series of scaled ground motions recorded during the 1995 Kobe earthquake, Japan. The test results demonstrate that the SMA braces are effective to prevent residual deformations and pinching. It is also shown that the time history responses observed from the shaking table tests agree well with the numerical predictions using a rate‐independent piecewise‐linear constitutive model calibrated to the quasi‐static component tests of the SMA braces. This suggests that the loading rate dependence of Cu–Al–Mn SMAs as well as the modeling error due to the piecewise linear approximation can be neglected in capturing the global response of the steel frame. Numerical simulations under a suite of near‐fault ground motion records are further performed using the calibrated analytical models to demonstrate the effectiveness of the SMA braces when the variability of near‐fault ground motions is taken into account. A stopper, or a deformation restraining device, is also proposed to prevent premature fracture of SMA bars in unexpectedly large ground motions while keeping the self‐centering capability in moderate to large ground motions. The effectiveness of the stopper is also demonstrated in the quasi‐static component and shaking table tests. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

形状记忆合金橡胶对高架桥梁碰撞减震效果的试验研究   总被引：2，自引：0，他引：2  

李素超  郭安薪  崔丽丽  李惠 《地震学刊》2014,(5):559-565

地震作用下,高架桥梁相邻主梁间的碰撞会引起结构位移和加速度响应增大、应力提高,导致混凝土开裂、脱落和伸缩缝被挤压破坏,甚至引发桥梁落梁和倒塌等,因此采取减轻或者避免桥梁结构在地震作用下碰撞的措施显得尤为必要。设计制备了具有变形自恢复能力的形状记忆合金橡胶碰撞缓冲器,通过桥梁地震碰撞的振动台试验,研究了形状记忆合金橡胶缓冲器对桥梁碰撞的控制效果,提出了碰撞缓冲器吸能效率和结构自身耗能控制率指标。研究表明,形状记忆合金橡胶碰撞缓冲器具有稳定的吸能效率,能够大幅度降低桥梁结构碰撞加速度和碰撞力,这对于提高城市交通网络的地震安全性能具有重要意义。  相似文献   

Penetration of molten iron alloy into the lower mantle phase     

Takashi Yoshino 《Comptes Rendus Geoscience》2019,351(2-3):171-181

The core–mantle boundary is the only interface where the metallic core and the silicate mantle interact physically and chemically. Many geophysical anomalies such as low shear velocity and high electrical conductivity have been observed at the bottom of the mantle. Perturbations in the Earth's rotation rate at decadal time periods require the existence of a thin conductive layer with a conductance of 10⁸ S. Substantial additions of molten iron from the outer core into the mantle may produce these geophysical anomalies. Although iron enrichment by penetration has only been observed in (Mg,Fe)O, the second dominant mineral in the lower mantle, the penetration process leading to iron enrichment in the silicate mantle has not been experimentally confirmed. In this study, high-pressure and high-temperature experiments were conducted to investigate the penetration of molten iron alloy into lower mantle phases; postspinel, polycrystalline bridgmanite and polycrystalline (Mg,Fe)O. At the interface between (Mg,Fe)O aggregate and molten iron alloy, liquid metal penetrated the (Mg,Fe)O aggregate along grain boundaries and formed a thin layer containing metal-rich blobs. In contrast, no penetration of molten iron alloy was observed at the interface between molten iron alloy and silicate phases. Penetration of liquid iron alloy into the (Mg,Fe)O aggregate is caused by the capillarity phenomenon or Mullins–Sekerka instability. Neither mechanism occurs at the boundary of pure polycrystalline MgO, indicating that the FeO in (Mg,Fe)O plays an essential role in this phenomenon. Infiltration of molten iron alloy along grain boundaries (capillarity phenomenon) is the dominant process and precedes penetration due to the Mullins–Sekerka instability. The capillarity phenomenon is governed by the balance of forces between surface tension and gravity. In the case where the ultralow velocity zone (ULVZ) with a low shear velocity is composed of Fe-rich (Mg,Fe)O, the maximum penetration distance of molten iron alloy by capillary rise is limited to 20 m. The addition of iron-rich melt to the base of the mantle is therefore unlikely to be the main cause of the high conductance of the CMB region predicted from decadal variation of the length of day. Furthermore, the absence of molten iron alloy penetration into silicate phases does not allow an extensive modification of the chemical composition of the mantle by core–mantle interaction.  相似文献   

高层钢结构地震反应形状记忆合金拉索控制研究   总被引：3，自引：0，他引：3  

丁阳  张笈玮 《地震工程与工程振动》2005,25(3):152-157

本文通过形状记忆合金(SMA)材料的超弹性性能试验确定了SMA材料的各项参数和常温状态下的本构模型。对采用SMA拉索实施振动控制的20层钢结构的Benchmark模型的地震响应进行了时程分析。计算结果表明,实施SMA拉索控制后,层间相对位移可降低70％左右,且SMA材料很好的耗能作用有效地减少了地震能量向上部楼层的传递,对上部结构具有一定的隔振作用;顶层相对位移的控制效果达到51％;顶层加速度可降低43％;地震波强度和拉索初应变对拉索的被动控制效果影响较大。最后给出了拉索的安装位置与拉索的应变之间的关系曲线,建议了合理的布置方案。  相似文献