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131.
Shenggao CHENG Qi AN Jing HU 《中国地球化学学报》2006,25(B08):29-29
Vanadium, improving mechanism and jointing capacity of steel products, is a kind of excellent additive during steel-making and its industry gets support from national industry policy. On account of shallow buried depth and low technique request of exploitation, there is much exploitation by local people lacking system management and technique guidance in area rich in vanadium since years ago, which damages regional environment dramatically. Accordingly, taking stone coal-vanadium as an example, the paper focuses on environment impact on water environment and eco-environment caused by exploitation in open air. Impact of exploitation on surface water mainly includes mining drainage and eluviated water of stock yard. According to civilian exploitation in the area, the rock suffers man-made disturbance, therefore, water quality indicators of mining drainage like heavy metal, permanganate, CI, SO4^2-, F are able to be analogies of ground water quantity in the region since the primary component of drainage is surrounding rock ground water. Water monitoring result of local well shows as follows: pH 6.68, SO4^2- 5.76 mg/L, F- 0.005 mg/L, Fe 0.025 mg/L, Mo 8.08 μg/L, Ni 5.91 μg/L, Co 0.61 μg/L, and all of them reach corresponding standard of water quality. Ground water turns into acid mine water by oxygenation after it discharges and with the help of sulfur the acid water contains nocuous elements which permeate in groundwater and surface water arousing pollution. The value of pH in the range of standard indicates that the acidification of mine water is relatively weak in the diggings. Eco-environment damage is another aspect that cannot be ignored, it acts as: (1) peeling work and establishment construction destroy landform; (2) stack of waste soil and rock occupies amounts of land; (3) various exploitation activities like vegetation peeling, landform change will enlarge the scope or enhance the intensity of soil erosion, which destroys eco-environment by leading water and soil loss; 相似文献
132.
Seng Chee Poh Norhaxati Mohd Tahir Hafiza Mohamed Zuki Mohd Izwadi Musa Khai Hock Ng Noor Azhar Mohamed Shazili 《中国地球化学学报》2006,25(B08):56-56
A total of 63 soil samples from 3 different soil profiles (urban, suburban and industrial areas) in major towns in the east coast of Peninsular Malaysia were analyzed for the total concentrations of Cu, Zn, Pb, Ni and Cr. The soil samples were subjected to acid digestion and the concentrations of total metals extracted were measured or flame atomic absorption spectrometry and inductively coupled plasma - atomic emission spectrometry. According to the result of this study, Pb and Zn concentrations in urban soils are much higher than those of industrial and suburban soils. Total concentrations of Cu and Cr in industrial soil samples are high compared to other two soil profiles and Ni concentrations in the suburban area are slightly higher those of urban and industrial soils. Since Malaysia has not yet to come up with her own soil maximum allowable limit, the heavy metal concentrations were compared with the Dutch maximum allowable limit. The results indicated that the median of heavy metals values in the three different soil profiles is still below the Dutch system limit. From the maximum allowable value obtained from the Dutch system, a contamination/pollution (C/p) index for each site was calculated for the set of these five heavy metals. An advantage of using this method is to make a differentiation between pollution (C/p〉1) and contamination (C/p〈1) status in soils as well as being able to characterize each status into 5 different categories (slight, moderate, severe, very severe and excessive). 相似文献
133.
Brian Gulson Karen Mizon Michael Korsch Honway Louie Michael Wu Jenny Stauber J. Michael Davis Alan Taylor 《中国地球化学学报》2006,25(B08):62-62
This is a 4-year longitudinal study to evaluate changes to the environment and exposure of young children associated with the introduction of methylcyclopentadienyl manganese tricarbonyl (MMT) into Australia in 2000. The cohort includes 57 females and 56 males; age range of 0.29 to 3.9 years. Samples are collected every 6 months from children in residences located at varying distances from major traffic thoroughfares in Sydney. Environmental samples: air, house and day care dustfall, soil, dust sweepings and gasoline. Samples from children: blood, urine, handwipes prior to and after playing outdoors, and a 6-day duplicate diet. All samples are analyzed for a suite of 20 elements using ICP-MS. Results are presented for the first three 6-month sampling periods for Pb and Mn. For dustfall accumulation, there was no significant change over the 3 sampling periods (time) for Pb or Mn, and a positive relationship between ‘traffic exposure' (traffic volume and proximity to the road) and Pb but not Mn. For handwipes, Pb and Mn in wipes taken from children after playing outdoors were usually significantly greater than for wipes taken prior to playing. There was no significant association between Pb or Mn in handwipes with traffic exposure. Dustfall accumulation was a significant predictor for Pb in the handwipes, and dust sweepings were a significant predictor of Mn in handwipes. 相似文献
134.
135.
Major and trace element chemical analyses of the Plio‐Pleistocene Bardin Bluffs Formation, on the margin of a major ice‐stream of the East Antarctic Ice Sheet, yield an anomalous chemically altered sediment composition. The Bardin Bluffs Formation of the Pagodroma Group is one of the key deposits on the Antarctic continent recording glaciomarine sedimentation under open marine fjord conditions as recently as the Plio‐Pleistocene. In modern fjords occupied by outlet glaciers of ice sheets, the composition of fine‐grained terrigenous sediments approaches that of unweathered rock types exposed upstream. In the Bardin Bluffs Formation, average abundances of stable elements (Ti, Al, Zr) approach average upper crustal compositions and the element ratios are consistent with sediments with a cratonic source, implying glacial dispersal from a large shield area through the Lambert Glacier drainage system. Interestingly, the chemical index of alteration (CIA) of these sediments has values similar to those of average shales formed under conditions of chemical weathering. The sediments are particularly depleted in silicate Ca, which has been observed elsewhere in glacial muds sourced from pre‐glacial saprolites. The anomalous chemistry of the Bardin Bluffs Formation can be explained by a sequence of events, involving chemical weathering prior to glacial expansion and erosion. The presence of a remnant 1·5 m deep late Neogene weathering profile at the base of the Bardin Bluffs sequence corroborates this conclusion. Supply of large quantities of chemically weathered materials to Antarctic marginal basins requires at least partial deglaciation of the continent and was previously regarded as uncharacteristic for late Neogene Antarctica. 相似文献
136.
137.
新疆和田河水资源利用与绿色走廊生态建设研究 总被引:2,自引:0,他引:2
水是和田河绿色走廊形成与演变最重要的因素。虽然和田河径流量年际变化比较平稳.但年内径流量洪枯季节差异十分悬殊,人工调配水资源的难度较大。随着人类开发利用水资源规模扩大.水资源时空分布格局发生变化,中上游人工绿洲面积扩大,下游绿色走廊植被衰竭,土地荒漠化日趋严重,走廊生态环境持续恶化。文章分析了和田河水资源变化对下游绿色走廊兴衰的影响过程,提出了合理利用水资源、保护绿色走廊生态环境的对策建议。 相似文献
138.
1990~2003年洪湖水体环境质量演变分析 总被引:16,自引:0,他引:16
以详细的水质监测资料为基础,采用标准指数法并结合实地调查,分析了1990~2003年洪湖水质的变化状况。结果表明,14 a间,洪湖水质类别以Ⅲ类和Ⅳ类为主。水质恶化的驱动因子是氮、磷及其它有机污染物。1991年到1994年期间,水体中氨氮(NH4 -N)占溶解无机氮(D IN)的比例逐年增高;1995~2003年,以氨氮和硝酸盐(NO3--N)同时作为水体中溶解无机氮的主要存在形式,与1990~1994年的水质状况相比,亚硝酸盐(NO2--N)所占的比例呈增加之势。氨氮、硝酸盐和亚硝酸盐的年际变化表明,洪湖水体自净能力在逐渐降低。以总磷(TP)、总氮(TN)和溶解无机氮(D IN)作为评价指标,洪湖水体已属中富营养型湖泊。洪湖水质演变与该区域人类活动(围湖造田、围网养殖等)以及江湖连通的变化对水环境的作用相耦合。 相似文献
139.
140.
Yaping WANG Chunxue XU Ziyi AN Suming WANG 《中国地球化学学报》2006,25(B08):205-205
Different species of one element have different activities, so it has different effects on environment and human health. To analyze qualitatively and quantitatively the speciation of a special element in sample, which is the important basis for appraising the toxicity and studying the rule of transfer and translation of elements. Since the 1970's, the scheme of sequential extraction has already been used at many laboratories both at home and abroard, to get the information about heavy metals' activity in polluted soils. Because this method has the experimental nature, many schemes of problem has taken place, the absence of consistency of these sequential extraction have been formed. Thus the complexity of the schemes, the lack of selectivity of reagent, the lack of quality control, the result mainly related to the extraction scheme used, and so on. In the face of these problems, the study of experimental methods of sequential extraction on three different soils, sediment in Dongting Lake, soil in Jiangsu Province and loess in Shanxi Province was made. Reference materials of heavy metal speciation following sequential extraction in soil and sediment had been developed. Nowadays two kinds of sequential extraction methods which are widely used are BCR (three steps) and improved Tessier methods (seven steps). Based on three steps of BCR, water-soluble speciation and the residual speciation were increased in our research. BCR701 was determined eight times at different laboratories using BCR three steps. The results showed that determined data obtained eight times were identical to the standard value, and it is indicated that this method has good reproducibility. The stability and homogeneity experiments indicated that the preparation of three types of candidates accorded with our requirements. Eight laboratories had afforded the determined values of 12 heavy metal elements (Cu, Pb, Zn, Mn, Co, Ni, Cd, Cr, Mo, As, Sb, Hg, Se et al.) using BCR three steps. Also, these three candidates afforded the determined values by seven steps, and 12 laboratories had participated. 相似文献