柱撑蒙脱石制备与表征   总被引：47，自引：2，他引：47  

吴平霄  肖文丁 《矿物学报》1997,17(2):200-207

本文采用多种方法制备keggin离子，并探索出制备稳定keggin离子的适宜酸碱度，用此柱化剂制备出层间距为2．4～2．5nm的柱撑蒙脱石。应用X射线走向衍射技术、红外光谱、差热分析对往撑蒙脱石进行表征，用BET、吡啶吸附考察了其表面物理化学性质。结果表明，用Keggin离子制备出的柱撑蒙脱石其层间距在自然状态下为2．4～2．5nm，350C灼烧，层间距稳℃定在1．8nm，且具有耐热性能好、较大的比表面积和较强的Lewis酸位中心等特点．  相似文献   

矿物流体包裹体中的羧酸     

曾贻善  刘家齐 《矿物岩石地球化学通报》1997,(1)

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...  相似文献   

唐古拉山冬克玛底冰川雪层中淋溶作用的初步研究   总被引：7，自引：7，他引：7  

侯书贵  秦大河 《冰川冻土》1996,18(3):227-234

利用唐古拉山冬克玛底冰川雪坑和表层积雪样品的实测资料，初步探讨本区雪层中离子淋溶作用的特征，影响因素及其对冰芯记录的干扰。研究发现淋溶作用能够对数周至数月时间尺度的雪层记录产生“平滑”作用，但不会影响冰芯记录的长期变化趋势。  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

区域采样法测定水中硫酸根离子的研究     

李俊锋  张凯  鲍长利  许天博 《吉林大学学报(地球科学版)》1997,(1)

在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定，结果令人满意。应用此方法测定硫酸根离子的线性范围为２００．０～３０００ｍｇ／Ｌ；进样频率为１２０次／ｈ；相对标准偏差为１．７０％  相似文献   

探测冰盖和多年冻土层的融冰探头研发     

Norbert I. K 《冰川冻土》2004,26(Z1):310-318

The exploration of ice sheets by melting vertical holes into the ground has some tradition in terrestrial glaciology. Such probes have been used since the 1960's to investigate the vertical structure of the ice in Greenland and Antarctica and in alpine glaciers. In this paper we look into the possibility to develop similar devices for use on extraterrestrial icy bodies, like e.g. the polar areas on Mars or the icy satellites of the outer solar system. We report on some basic experiments performed in the cryo-vacuum laboratory of the Space Research Institute of the Austrian Academy of Sciences, Graz. In these experiments the penetration of a simple melting probe into compact and porous water ice (with a snow-like texture) was monitored, both under vacuum conditions and under air pressure. The observed penetration speeds for a given power supply are compared with a simple mathematical model. We conclude that a miniature melting probe with small overall dimensions and a reasonable power demand could well be part of the payload of a future planetary mission, for example to the poles of Mars. Such missions are currently under discussion in several space agencies. Moreover such probes could also e? ectively be used in terrestrial environments. A possible design is presented at the end of the paper.  相似文献   

大气季节内振荡对印度洋—西太平洋地区热带低压/气旋生成的影响   总被引：24，自引：4，他引：24  

祝从文  Tetsuo Nakazaw  李建平 《气象学报》2004,62(1):42-50

文中利用EOF分析大气季节内振荡 (MJO)的时空变化的方法 ,研究了 1996年 9月～ 1997年 6月间的MJO活动对生成在印度洋—西太平洋海域的热带低压 /气旋的影响。结果发现 ,除西北太平洋之外 ,发生在其他区域的热带低压 /气旋有半数以上生成在向东移动的MJO的湿位相中。伴随MJO的向东传播 ,热带低压 /气旋平均生成位置也随之向东移动 ,而生成在西北太平洋的热带低压 /气旋分别受到向东和向西传播的MJO影响  相似文献   

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy     

Yin Xiulan China Institute of Geo-environmental Monitoring  Beijing  China Hu Ping Faculty of Earth Sciences  China University of Geosciences  Wuhan  China  Northeastern Illinois University  Chicago  IL  USA Li Dien Division of Earth  Environmental Sciences  Los Alamos National Laboratory  Los Alamos  NM  USA 《中国地质大学学报(英文版)》2004,15(4):355-360

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Slow mass movement in the Kangchenjunga area, eastern Nepal Himalaya     

Dhananjay  Regmi  Teiji  Watanabe 《Island Arc》2005,14(4):400-409

Abstract   The rates of the accumulated and continuous displacement of solifluction lobes in the Kangchenjunga area, eastern Nepal Himalaya, were determined using glass fiber tubes and a strain probe. Ground temperature, precipitation and soil moisture were monitored at two sites, whose altitude differed by approximately 100 m, to understand the solifluction process. The average movement rate of the glass fiber tubes on a 31° slope at altitudes of 5412–5414 m a.s.l. was approximately 11 mm/year, being almost threefold greater than that observed on a 22° slope at 5322–5325 ma.s.l. There was no significant difference in the depth of displacement at these sites. The continuous displacement measurement near the ground surface at 5414 m showed permanent downslope movement from early July. Such movement may be attributed to additional moisture supply during the monsoon season. The amplitude of the displacement cycle was highest at the ground surface, and decreased to virtually zero at and below 20 cm in depth. Probable factors leading to the relatively slow rates of downslope displacement at the surface and depth at the studied altitudes are the lack of concurrence of the freeze–thaw cycles and the high moisture condition in the soil, and the low moisture retention capacity of the soil because of steep slopes and superficial desiccation. The rate of displacement may be more pronounced at altitudes above 5600 m because of the freeze–thaw cycles during the summer season.  相似文献   

Energetic Particles Observed in the CUSP Region During a Storm Recovery Phase     

S. Y. Fu  Q. G. Zong  Z. Y. Pu  C. J. Xiao  A. Korth  P. Daly  H. Reme 《Surveys in Geophysics》2005,26(1-3):241-254

In this paper we report energetic ion behavior and its composition variations observed by the Cluster/RAPID instrument when the spacecraft was travelling in the high latitude magnetospheric boundary region on the day of the 31 March, 2001, strongest magnetic storm in the past 50 years. The Dst index reached −360 nT at about 09:00 UT. During its early recovery phase, large amounts of oxygen and helium ions were observed; the ratio of oxygen to hydrogen in the RAPID energy range reached as high as 250%, which suggests that the observed energetic particles might be of magnetospheric origin. The observations further show that enhanced energetic electron fluxes are confined in a very narrow region, while protons have occupied a larger region, and heavy ions have been observed in an even larger region. The flux of energetic electrons show a slight enhancement in a region where the magnetic field magnitude is around zero. These observed energetic ions could be quasi-trapped by the current sheet in the stagnation region of the cusp.  相似文献