A novel high-resolution small ion spectrometer to study ion nucleation of aerosols in ambient indoor and outdoor air     

A.P. Fews  N.K. Holden  P.A. Keitch  D.L. Henshaw 《Atmospheric Research》2005,76(1-4):29

An electrically based ion spectrometer is described, capable of measuring particle sizes and mobilities from molecular ions (small ions) to aerosol particles across a size range of 0.4 to 30 nm in diameter. It consists of a single cylindrical capacitor divided into three electrically insulated sections. The current arriving at the central section is measured by an electrometer and represents the ion flux over a known range of mobilities determined by the applied voltage. The applied voltage is scanned in steps to measure the ion fluxes over a large number of overlapping mobility ranges. The recorded signal and the response function of the instrument are unfolded using a maximum entropy procedure to give a high-resolution measured mobility spectrum. The maximum entropy approach offers a considerable improvement over traditional aspiration collectors and can approach the resolution of a drift tube system. In this way, the spectrometer successfully overcomes the diffusion limit to small ion resolution. Illustrative spectra are shown, demonstrating for the first time the presence of some resolved structure within the small ion spectrum at the highest mobilities. It is demonstrated that the actual mobility spectrum of small ions falls in the range 0.8–2.0 × 10⁻⁴ m² V⁻¹ s⁻¹. This represents a narrower range than that previously measured which is attributed to improved spectral resolution in the present work.  相似文献   

Preparation and Characterization of Hydroxyiron-Montmorillonite Complexes   总被引：1，自引：0，他引：1  

Liao Libing Jia Fuli Faculty of Materials Science  Engineering  China University of Geossciences  Beijing  China 《中国地质大学学报(英文版)》2000,11(3)

Iron elementin soil exists mainly in form s of Fe(OH) 2 ,Fe(OH ) 2 and Fe2 (OH ) 2 2 in tropical and subtropical areaswhere p H values are less than7.These hydroxy- Fe ions reactslowly with montmorillonite by intercalation into their inter-layer space and adsorption on their surfaces,and in this wayvarious hydroxyiron- montmorillonite complexes are formed(Cool and Vansant,1998;Wu et al.,1997;Molinared andClearfield,1994) . Hydroxyiron- montm orillonite complexesare assum ed to have…  相似文献   

青藏高原中部各拉丹冬峰雪冰记录特征   总被引：1，自引：0，他引：1  

张玉兰  康世昌  张强弓  丛志远  张拥军 《冰川冻土》2007,29(5):685-693

2005年10~11月在青藏高原唐古拉山脉各拉丹冬峰冰川区不同海拔采集了3个雪坑样品,分析结果表明,雪坑中δ¹⁸O和主要离子浓度具有明显的季节变化特征.夏季风期间降水中δ¹⁸O低于其它季节,表明该地区夏季δ¹⁸O的"降水量效应"仍然存在.雪坑中主要离子在非季风期的浓度高于夏季风期.主要离子的相关分析表明,除NH₄⁺、NO₃^-外,雪坑中其它离子浓度之间均存在较好的正相关性.各拉丹冬峰冰川区仍受到南亚季风的影响,但因其位于夏季风影响的边缘区域,其影响程度相对于高原南部较弱;同时也受到大陆性气候的影响,在冬春季节具有较高的粉尘气溶胶沉降.  相似文献   

Mobility of major ions and nutrients in the unsaturated zone during paddy cultivation: a field study and solute transport modelling approach     

N. Rajmohan  L. Elango 《水文研究》2007,21(20):2698-2712

Study of the movement of water and solute within soil profiles is important for a number of reasons. Accumulation of prominent contaminants from agricultural chemicals in the unsaturated zone over the years is a major concern in many parts of the world. As a result, the unsaturated zone has been a subject of great research interest during the past decade. Hence, an intensive field study was conducted in a part of Palar and Cheyyar river basins to understand the variation of major ions and nutrients in the soil zone during paddy cultivation. The chloride and nitrate data were used to model the movement of these chemicals in the unsaturated zone using the HYDRUS‐2D model. The field study shows that fertilizer application and irrigation return flow increases the major ions and nutrients concentration in the unsaturated zone. Further, the nutrient concentrations are regulated by plant uptake, fertilizer application and infiltration rate. Additionally, denitrification and soil mineralization processes also regulate the nitrogen concentration in the unsaturated zone. The solute transport modelling study concluded that the simulated results match reasonably with the observed trends. Simulated concentrations of chloride and nitrate for a 5‐year period indicate that the concentrations of these ions fluctuate in a cyclic manner (from 60 to 68 mg l^?1 and from 3·4 to 3·5 mg l^?1 respectively in groundwater) with no upward and downward trend. The influence of excessive fertilizer application on groundwater was also modelled. The model predicts an increase of about 17 mg l^?1 of chloride and 2·3 mg l^?1 of nitrogen in the groundwater of this area when the application of fertilizers is doubled. The model indicates that the present level of use of agrochemicals is no threat to the groundwater quality. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Ion composition and solar wind interaction: Observations of comet C/1995 O1 (Hale-Bopp)     

Rauer  H. 《Earth, Moon, and Planets》1997,79(1-3):161-178

The extraordinary brightness of comet Hale-Bopp (C/1995 O1) offered the rare opportunity to investigate its ion tail by observations over a wide range of wavelengths. For the first time, ion emission lines could be detected in the radio domain, originating from H₃O⁺, HCO⁺ and CO⁺ ions. Observations in the extreme ultraviolet range showed O⁺ emissions. Optical imaging observations show a spectacular detail of structures in the ion tail. The combined measurements of the ion spatial distribution and dynamic provide a wealth of information which needs to be understood in terms of models of the comet-solar wind interaction and ion-neutral molecule reactions in the coma. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

成水滴灌下塔里木沙漠公路防护林土壤盐分分布特征分析     

窦凯歌  王永东  雷加强  赵英  贾萌萌  沈芳宇 《干旱区地理》2015,38(3)

对塔里木沙漠公路防护林地进行实地取样分析,研究咸水滴灌条件下土壤盐分变化规律及其离子分布特征.试验采用5个矿化度水平的咸水灌溉处理:29.70(1号井),25.90(2号井),20.99(8号井),16.95(14号井)和5.75 g·L-1(18号井).试验结果表明:咸水滴灌对土壤盐分含量和离子组成有显著影响,土壤积盐程度随灌溉水矿化度的增大而加剧,土壤盐分组成以C1-、Na+和SO42-为主;不同盐分离子在土壤剖面上的分布特征不同,C1-、Na+、Mg2+和SO42-四种离子的分布较一致,在垂直滴头向下方向浓度最低,远离滴头径向浓度逐渐增大,Ca外和HCO3-在剖面上的分布存在明显的不一致性,在水平方向上远离滴头HCO3-离子浓度向上层聚集,Ca2+则表现为向下层淋溶.研究结果对极端干旱区高矿化度咸水的合理开发利用及防护林的可持续发展具有理论意义和应用价值.  相似文献   

应用SHRIMP铀-铅定年法研究腾冲地区中更新世英安岩的形成时代   总被引：1，自引：0，他引：1  

李琳琳  王书兵  石玉若 《岩矿测试》2015,34(1):19-27

腾冲火山岩群是我国著名的年轻火山岩群,前人主要采用K-Ar法、不平衡铀系等同位素定年方法研究该区火山岩的年龄并划分其喷发期次,采用K-Ar法获得腾冲火山岩0.013~17.84 Ma的年龄以及0.13~2.9 Ma的等时线年龄,不平衡铀系法主要用于该地区0.23 Ma以来的样品年龄研究。传统的同位素定年体系的精确度和定年范围对于研究该区火山岩的年龄存有很大局限性。近年来,微区原位离子探针U-Pb定年在年轻地质体年代学研究中表现出巨大潜力,在国际上已经应用于中更新世晚期地质体的年龄测定。本文报道了应用锆石SHRIMP U-Pb定年方法对腾冲曲石地区中更新世英安岩的3次测定结果,3次实验的年龄值在误差范围内一致。在对一次离子流选择及其强度、二次离子积分时间等实验条件探讨的基础上,综合分析3次实验中的二次离子计数表明第3次实验结果具有更高的精确度,年龄值为0.41±0.01 Ma,属中更新世,代表该英安岩的形成时代,该年龄结果是目前我国获得的最年轻的高精度锆石SHRIMP U-Pb年龄。本研究获得的中更新世锆石U-Pb年龄为年轻地质体的年代学研究提供了新的思路。  相似文献   

Major ion chemistry and weathering processes of the Danjiangkou Reservoir,China     

Siyue Li 《水文科学杂志》2013,58(8):1385-1395

  相似文献   

Determination of Fluoride Ions in Iron Ores by UV–VIS Spectrophotometry after Matrix Removal Using Diphonix® Resin     

Agata Jakóbik‐Kolon  Monika Skwira 《Geostandards and Geoanalytical Research》2012,36(1):21-25

A modification of the spectrophotometric method for the determination of fluoride ions in iron‐rich materials is proposed. In this method the iron matrix was successfully removed using Diphonix^® resin. The studied sample was a ferruginous mineral which contained about 38% of iron. The Euronorm certified reference material (ECRM) 676‐1 (Iron Ore Sinter), as a commercially available material having a similar matrix (39.76% w/w Fe) and fluoride level (0.1% w/w), was used to validate the method. After partial digestion in concentrated hydrochloric acid the samples were diluted and passed through Diphonix^® resin. The concentration of fluoride ions was determined by a spectrophotometric method using a Zr:ER complex (λ = 540 nm). The result obtained for the ECRM was in good agreement with the certificate specification and thus proved the method to be applicable for the determination of fluoride ions in iron‐rich materials. Due to the easy digestion step and simple requirements for equipment, this method can be used in most laboratories.  相似文献   

金川矿区尾矿库排水对地下水水质影响：现状及预测分析   总被引：1，自引：0，他引：1  

刘卫东  李峰  孙伟 《冰川冻土》2012,34(1):114-119

处于甘肃河西干旱区的金川公司在生产过程中产生了大量含有重金属离子的工业废水、废渣,废水排放会对地下水水质产生影响,其重金属离子会对人体有危害.重点对尾矿库排水对当地地下水水质影响进行了研究分析,对库区地下水污染现状进行了调查.绘制了尾矿库排水影响区的地下水中Ni、Cu、Zn和Cr四种主要元素平面分布等值线图,分析了重金属离子污染来源;通过建立物理、数学模型,对尾矿排出废水中主要污染物(Ni、As、Cu、Cr、Cd、SO24-等组分)分布进行了模拟预测,对各类污染物可能造成的危害进行了分析,建议加强地下水质监测和处理排放.  相似文献