黄原胶改性微米铁修复地下水中Cr(Ⅵ)污染的试验     

赵勇胜  李彧 《吉林大学学报(地球科学版)》2021,51(4):1224-1230

为了解决微米铁的重力沉降问题,提高微米铁修复地下水Cr（Ⅵ）污染的原位修复效果,本文利用黄原胶对微米铁进行改性,并通过沉降实验探究改性微米铁浆液的稳定性,同时选择Cr（Ⅵ）作为目标污染物,探究黄原胶改性微米铁去除地下水Cr（Ⅵ）污染的降解能力。实验结果显示：当黄原胶的投加质量浓度分别为0.0、1.0、1.5、2.0、2.5、3.0、6.0 g/L时,改性微米铁浆液的悬浮稳定性逐渐得到加强,在5 h沉降实验结束时,对应的相对分光光度值分别为0.05、0.25、0.46、0.57、0.65、0.73和0.87;黄原胶具有抑制微米铁吸附Cr（Ⅵ）的能力,其可促进Cr（Ⅵ）的还原,提高Cr（Ⅵ）的去除率;随着黄原胶投加质量浓度的增加,对应的Cr（Ⅵ）去除率分别为33.4%、41.2%、47.4%、51.1%、53.0%、63.9%和64.1%;6.0 g/L黄原胶改性的微米铁浆液具有最佳的悬浮稳定性,黄原胶的投加提高了微米铁的反应活性,但当黄原胶投加质量浓度超过3.0 g/L时,其对Cr（Ⅵ）的去除率没有显著提高;黄原胶投加质量浓度越大,黄原胶的缓冲作用就越明显。  相似文献   

机器学习与成矿预测:以闽西南铁多金属矿预测为例     

张振杰  成秋明  杨玠  武国朋  葛云钊 《地学前缘》2021,28(3):221-235

作为近年来爆炸式发展的方法模型,机器学习为地质找矿提供了新的思维和研究方法。本文探讨矿产预测研究的理论方法体系,总结机器学习在矿产预测领域的特征信息提取和信息综合集成两个方面的应用现状,并讨论机器学习在矿产资源定量预测领域面临的训练样本稀少且不均衡、模型训练中缺乏不确定性评估、缺少反哺研究、方法选择等困难和挑战。进一步以闽西南马坑式铁矿为实例论述基于机器学习方法的矿产预测基本流程:(1)通过成矿系统研究建立成矿模型,确定矿床控矿要素;(2)通过勘查系统研究建立找矿模型,并为评价预测提供相关的勘查数据;(3)通过预测评价系统研究,建立预测模型,并提取预测要素;(4)利用机器学习模型对预测要素进行信息综合集成,获取成矿有利度图;(5)对预测性能和结果进行不确定性评估;(6)找矿靶区/成矿远景区圈定及资源量估算。最后,总结建立以地学大数据和地球系统理论为指导,以“地球系统-成矿系统-勘查系统-预测评价系统”为研究路线的基于地学大数据的矿产资源定量预测理论和方法体系的研究愿景。  相似文献   

The importance of iron speciation (Fe+2/Fe+3) in determining mineral assemblages: an example from the high‐grade aluminous metapelites of southeastern Madagascar     

S. D. BOGER  R. W. WHITE  B. SCHULTE 《Journal of Metamorphic Geology》2012,30(9):997-1018

Metapelitic granulites from the Anosyen domain of southeastern Madagascar are exposed in three intercalated formations: the Amparihy, Bakika and Ihosy formations. Although mineralogically distinct from each other, the rocks from these formations show very similar bulk‐rock compositions when measured on a Fe_T basis. The preserved mineral assemblages thus do not reflect differences in the ratios of the main rock‐forming oxides (i.e. Al₂O₃:Fe_T:MgO), but instead reflect variations in the pre‐metamorphic oxidation state of the protolith rocks. These differences in oxidation state are manifested via differences in iron speciation – either Fe⁺² or Fe⁺³. The relatively reduced rocks of the Amparihy Formation preserve the assemblage bi–sp–sill–g–cd, which contrasts markedly with the mostly garnet and spinel‐absent bi–cd–sill–mt assemblages preserved in the strongly oxidized rocks of the Ihosy Formation. Compositionally intermediate rocks of the Bakika Formation are garnet bearing, but sillimanite‐absent, and contain the assemblage sp–g–cd–mag. Modelling of these rocks in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O system suggests that they evolved along a heating and cooling P–T path with only limited decompression accompanying cooling on the retrograde path. Peak temperatures and pressures of ～880–920 °C and 6–6.5 kbar are inferred for the majority of the Anosyen domain, with slightly lower peak temperatures (～840 °C) estimated in the extreme northwest of the area. The high‐temperature and relatively low‐pressure nature of metamorphism suggests high geothermal gradients existed during orogenesis, which in southern Madagascar is related to the amalgamation of Gondwana (580–520 Ma). Although metamorphic temperatures may have been augmented via thermal advection from the emplacement of the syn‐ to post‐tectonic Ambalavao suite, the high geothermal gradients nevertheless suggest thin and consequently hot lithosphere existed prior to orogenesis.  相似文献   

Sunrise Hill unconformity: A newly discovered regional hiatus between Archaean granites and greenstones in the northeastern Pilbara Craton     

P. R. Dawes  R. H. Smithies  J. Centofanti  D. C. Podmore 《Australian Journal of Earth Sciences》2013,60(6):635-639

Contacts between Archaean granites and greenstones in the northeastern part of the Pilbara Craton have been described as intrusive and tectonic. New field observations in the Shay Gap region demonstrate that greenstones of the Gorge Creek Group unconformably overlie the Muccan and Warrawagine batholiths. Regionally, the unconformity is marked by a persistent but relatively thin basal clastic sequence, locally with a granite boulder conglomerate, overlain by ore‐bearing banded iron‐formation, fine‐grained clastic rocks and chert. The granite basement is dated at 3443 ± 6 Ma. The precise age of the hiatus is unknown but its maximum effect might have been the removal of a substantial thickness of Early to Middle Archaean strata.  相似文献   

Leachable particulate iron in the Columbia River,estuary, and near-field plume     

Sherry M. Lippiatt  Matthew T. Brown  Maeve C. Lohan  Carolyn J.M. Berger  Kenneth W. Bruland 《Estuarine, Coastal and Shelf Science》2010

This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.  相似文献   

Role of buffer layer in electronic structures of iron phthalocyanine molecules on Au(111)     

孙家涛  潘理达  胡昊  杜世萱  高鸿钧 《海洋学报(英文版)》2010,29(9)

We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ～15° relative to the substrate plane along the nearest neighbour [101^-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111).  相似文献   

Iron porphyrins in the Permian Kupferschiefer of the lower Rhine Basin, N.W. Germany     

C. B. Eckardt  M. Wolf  J. R. Maxwell 《Organic Geochemistry》1989,14(6)

Immature samples of the Permian Kupferschiefer from the Lower Rhine Basin in N.W. Germany were analysed for tetrapyrrole pigment type and abundance. The sediment, thought to have been deposited in a marine regime with enhanced salinity, was found to contain high concentrations of metalloporphyrins. The porphyrins are complexed to nickel (Ni) and oxovanadium (V=0), but high abundances of iron (Fe) porphyrins were also detected using UV/visible spectroscopy and mass spectrometry. The presence in the latter of series of aetioporphyrins, cycloalkanoporphyrins, di-cycloalkanoporphyrins and benz-cycloalkanoporphyrins was confirmed by accurate mass measurements; HPLC co-injection of deoxophylloerythroetioporphyrin (C₃₂ DPEP) with the demetallated iron porphyrins indicated its presence in the sediment as an iron complex. The study provides the first evidence for the occurrence of Fe porphyrins in geological samples other than coals and lignites, and reports the highest concentrations in sedimentary organic matter to date.  相似文献   

游离氧化铁形态转化对红粘土工程性质的影响   总被引：6，自引：5，他引：6  

孔令伟  罗鸿禧 《岩土力学》1993,14(4):25-39

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。  相似文献   

由电子探针分析数据估算角闪石、黑云母中的Fe~（3＋）、Fe~（2＋）     

林文蔚  彭丽君 《吉林大学学报(地球科学版)》1994,(2)

待定矿物化学式中阳离子数法是由电子探针分析值求矿物中Ｆｅ￣（３＋）、Ｆｅ￣（２＋）的新方法。在该方法中，矿物化学式中的阴离子数是唯一已知条件，阳离子数未知，通过本文给出的一系列步骤可以得出实际阳离子数的可能估计。进而求出Ｆｅ＿２Ｏ＿２、ＦｅＯ。该法对Ｆｅ＿２Ｏ＿３、ＦｅＯ的计算结果避免了出现负值，在总体上，该方法的计算结果较其它方法更接近其化学分析值。  相似文献   

微波等离子体炬原子发射光谱法测定铁和铝的研究   总被引：2，自引：0，他引：2  

董德凡  叶冬梅 《岩矿测试》1994,13(1):41-44

研究了低功率微波等离子体炬原子发射光谱法（ＭＰＴ－ＡＥＳ）对Ｆｅ，Ａｌ的测定。样品经气动雾化后，分别以流动注射与连续式两种方式引入ＭＰＴ。考察了用这两种进样方式时ＭＰＴ－ＡＥＳ的分析性能，证明低功率ＭＰＴ－ＡＥＳ具有良好的分析特性。  相似文献