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801.
田立明  郑有业  郑海涛 《地质学报》2017,91(5):992-1006
列麦白云母花岗岩位于特提斯喜马拉雅东段,侵位于雅拉香波穹窿边部早古生代浅变质岩中。为揭示其形成时代及成因,本文对其开展LA-ICP-MS锆石U-Pb年代学、Hf同位素及岩石地球化学研究。结果表明列麦白云母花岗岩具有高SiO_2(71.08%~71.49%)、Al_2O_3(15.55%~15.72%)和K_2O(4.32%~4.57%),高的A/CNK比值(1.17~1.21),低的CaO/Na_2O比值(0.22~0.28),属于高钾钙碱性过铝质花岗岩;富集Rb、Th和Hf,亏损Ba、Nb、Sr和Ti,稀土元素呈轻稀土(LREE)富集,重稀土(HREE)相对亏损的向右倾斜的配分模式(LREE/HREE=16.57~17.91),具有弱负Eu异常(δEu=0.78~0.79)。与二云母花岗岩比较,列麦白云母花岗岩具有较高的Rb含量(204.1×10~(-6)~293.8×10~(-6))、较低的Sr(134.6×10~(-6))及显著的重稀土分馏效应。锆石新生边年龄为48.5±1.1 Ma(MSWD=2.1),代表其结晶年龄,该年龄为目前报道的最早年龄,其初始Hf同位素组成ε_(Hf)(t)=-6.4~-2.3,显示物源为壳源性质,二阶段模式年龄介于731~839 Ma之间,表明成岩物质形成于新元古代;核部继承锆石年龄变化在135.7~3339.2 Ma之间,表明其源岩为早白垩世沉积岩,是在印度与欧亚大陆主碰撞阶段,陆-陆碰撞导致地壳缩短加压升温,引起早白垩世沉积岩部分熔融而形成的。  相似文献   
802.
湖南祁东清水塘铅锌矿床成矿物质来源同位素示踪   总被引:3,自引:0,他引:3  
清水塘铅锌矿床位于湖南省祁东县北东部,是一个中型矿床。在详细的野外地质调查基础上,本文通过矿石硫、铅同位素,含矿石英氢、氧同位素和含矿方解石碳、氧同位素等综合研究,探讨清水塘铅锌矿床成矿物质来源和成因。硫同位素研究结果表明,清水塘铅锌矿床中黄铁矿、方铅矿和闪锌矿的硫同位素δ~(34)S介于-7.41‰~2.91‰之间,重晶石的硫同位素δ~(34)S介于11.49‰~12.34‰之间,表明矿石中的硫主要来源于深源岩浆,并受到上部地壳物质的混染。黄铁矿、方铅矿和闪锌矿的Pb同位素~(206)Pb/~(204)Pb介于17.810~18.710之间,~(207)Pb/~(204)Pb介于15.497~15.726之间,~(208)Pb/~(204)Pb介于37.858~38.834之间;其中闪锌矿变化范围略偏大,表明矿石中的铅主要来源于地壳,可能混有少量地幔物质。含矿石英的氢、氧同位素δD_(SMOW)介于-87.4‰~-79.3‰之间,δ~(18)O_(H_2O)介于-8.10‰~0.63‰之间,表明成矿流体以岩浆水为主,晚期有大气降水的混入。含矿方解石的碳、氧同位素δ~(13)C_(VPDB)介于-5.3‰~-4.6‰之间,δ~(18)O_(SMOW)介于12.30‰~13.48‰之间;与地层灰岩的δ~(13)C_(VPDB)(0.9‰~2.6‰),δ~(18)O_(SMOW)(21.86‰~23.39‰)不一致;说明成矿流体中的碳主要来自深源岩浆。以上研究表明,清水塘铅锌矿床的成矿物质主要来自地壳熔融形成的岩浆,混合作用是成矿的主要机制。  相似文献   
803.
李睿华  孙丰月  李良  白宜娜  王飞  姜和芳  禹禄 《地质学报》2017,91(10):2273-2284
本文对牛鼻子梁镁铁质-超镁铁质杂岩体中产出的闪长岩进行了详细的U-Pb年代学、岩石地球化学和Hf同位素分析,以便对岩石的成因及南祁连造山带对柴达木盆地的俯冲效应予以研究。闪长岩中锆石LAICP-MS U-Pb定年结果表明,闪长岩的形成时代为361±3 Ma(MSWD=0.049),即晚泥盆世。岩石地球化学方面,SiO_2含量为53.44%~58.27%,Na_2O+K_2O为4.80%~6.39%,K_2O/Na_2O比值为0.33~0.97,显示出富钠的特征,岩石由钙碱性序列向高钾钙碱性序列过渡。微量元素原地地幔标准化蛛网图上显示相对富集大离子亲石元素(Rb、K)及轻稀土,相对亏损高场强元素(Ta、Nb、Zr),同时Th含量介于2.03×10~(-6)~6.57×10~(-6)之间,Th/Ta比值为2.73~12.82之间,显示为壳幔混染作用的产物,另外据闪长岩中发现的辉长岩包体也表明了壳幔岩浆的混合。闪长岩Hf同位素显示,岩石的ε_(Hf)(t)值和二阶段模式年龄(TDM2)分别介于±6.41~±9.36和714~878Ma之间。上述结果表明,岩体的原始岩浆是一种幔源物质为主,混合新生陆壳部分熔融的产物。综合区域岩石构造背景的研究,认为牛鼻子梁闪长岩岩体形成于南祁连向柴达木板块俯冲碰撞后伸展的环境。  相似文献   
804.
太行山南段井陉-内丘一带是河北省重要的铜矿远景区,区内成矿条件优越。已有研究资料多将该区铜矿类型、成矿条件等与山西中条山铜矿富集区进行类比。由于缺少对铜的成矿时代的精确限定,致使无法对区内铜矿床的形成过程及成因进行较为准确的分析,制约着区域铜矿成因类型对比及找矿勘查工作部署。本文以区内桃园铜矿床及酸枣坪、虎寨口、鹿峪和方垴等四个铜矿化点为研究对象,采用Rb-Sr法测试分析了上述铜矿床及矿化点的矿石硫化物。测试结果显示,桃园铜矿不同硫化物对Rb-Sr等时线年龄在1829.6~1840Ma之间,酸枣坪铜矿点的形成时代为1830.7±5.2Ma,虎寨口铜矿点的形成时代为1844.3±5.9Ma。上述三个铜矿床(点)矿石硫化物Rb-Sr等时线年龄测试结果表明,在古元古代晚期区内有一次较为强烈的铜矿成矿作用,成矿时限在1830~1844Ma之间。而方垴和鹿峪两个铜矿化点矿石硫化物测年结果与上述三个铜矿床(点)形成时间有较大差异,Rb-Sr等时线测年结果分别为1402±23Ma和1376±37Ma,说明在中元古代长城纪末期区内仍有一次铜矿化作用发生。结合华北地台构造演化过程,太行山南段古元古代晚期第一次铜矿化与山西中条山胡-篦型铜矿形成时代接近,铜矿床的形成与吕梁运动关系密切。由于太行山南段铜矿(点)分布区地处陆内构造环境的晋豫裂陷带,而山西中条山铜矿富集区处于秦岭-大别活动带的北缘的"秦岭古洋"壳向华北地台俯冲环境,构造环境差异可能导致两区在铜矿形成潜力及规模上存在一定差异。与区内第一次铜矿化作用相比,发生在中元古代长城纪末期的第二期铜矿化在成矿规模及强度上均较弱,其成矿动力学机制有待进一步分析确定。  相似文献   
805.
The recently discovered Zhuxi W–Cu ore deposit is located within the Taqian–Fuchun Ore Belt in the southeastern edge of the Yangtze Block, South China. Its inferred tungsten resources, based on new exploration data, are more than 280 Mt by 2016. At least three paragenetic stages of skarn formation and ore deposition have been recognized: prograde skarn stage; retrograde stage; and hydrothermal sulfide stage. Secondly, greisenization, marmorization and hornfels formation are also observed. Scheelite and chalcopyrite are the dominant metal minerals in the Zhuxi deposit and their formation was associated with the emplacement of granite stocks and porphyry dykes intruded into the surrounding Carboniferous carbonate sediments (Huanglong and Chuanshan formations) and the Neoproterozoic slate and phyllites. The scheelite was mostly precipitated during the retrograde stage, whereas the chalcopyrite was widely precipitated during the hydrothermal sulfide stage. A muscovite 40Ar/39Ar plateau age of about 150 Ma is interpreted as the time of tungsten mineralization and molybdenite Re–Os model ages ranging from 145.9 ± 2.0 Ma to 148.7 ± 2.2 Ma (for the subsequent hydrothermal sulfide stage of activity) as the time of the copper mineralization. Our new molybdenite Re–Os and muscovite 40Ar/39Ar dating results, along with previous zircon U–Pb age data, indicate that the hydrothermal activity from the retrograde stage to the last hydrothermal sulfide stage lasted up to 5 Myr, from 150.6 ± 1.5 to 145.9 ± 1 Ma, and is approximately coeval or slightly later than the emplacement of the associated granite porphyry and biotite granite. The new ages reported here confirm that the Zhuxi tungsten deposit represents one of the Mesozoic magmatic–hydrothermal mineralization events that took place in South China in a setting of lithospheric extension during the Late Jurassic (160–150 Ma). It is suggested that mantle material played a role in producing the Zhuxi W–Cu mineralization and associated magmatism.  相似文献   
806.
The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average 206Pb/238U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average 206Pb/238U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.  相似文献   
807.
The newly discovered Jiaojiguan deposit, a medium-scale skarn iron-tin polymetallic deposit on the Sino-Burma boundary of Yunnan Province (SW China), is spatially associated with the biotite monzonitic granite. Here, we report new in situ zircon LA-MC-ICP-MS U–Pb ages, trace element and Hf isotope data from the granite, and U–Pb dating ages of cassiterite from the ore bodies. In this study, we obtain a weighted mean 206Pb/238U age of 124.1 ± 1.4 Ma for the zircon and a 207Pb/206Pb-238U/206Pb intercept age of 123.8 ± 2.2 Ma for the cassiterite. The granite crystallized during the Early Cretaceous, with zircons exhibiting εHf(t) values from ?5.8 to ?0.6 and two-stage Hf model ages (TDM2) of 1.21–1.54 Ga. The close temporal and spatial links between pluton emplacement and ore-forming events suggest that magmatic-hydrothermal events were the key factors that triggered the genesis of the iron-tin polymetallic deposits in the area. Regional geochronological data show that tin mineralization took place three times during the Cretaceous–Palaeogene in the Tengchong block due to re-melting of the underlying supposed Proterozoic (1.5 ± 0.5 Ga) Sn-rich strata/materials. Compared with those in the Bangong–Nujiang metallogenic belt (BNMB), we propose that the Cretaceous iron-tin polymetallic mineralization events in Tengchong–Baoshan closely resemble those of the Bangong–Nujiang belt in northern Tibet, both of which have experienced similar tectono-magmatic-metallogenic histories since the Mesozoic.  相似文献   
808.
The Duguer area represents one of the few occurrences of high-grade metamorphic rocks in the ‘Central Uplift’ zone of the Qiangtang terrane, central Tibet. The metamorphic rocks consist mainly of orthogneiss, paragneiss, and schist. To better understand the formation of these rocks, seven samples of gneiss and schist from the Duguer area were selected for in situ zircon U–Pb analysis and Ar–Ar dating of metamorphic minerals. The results suggest two distinct metamorphic stages, during the Late Triassic (229–227 Ma) and Late Jurassic (150–149 Ma). These stages correspond to the closure of the Palaeo-Tethys Ocean and northward subduction of the Bangong–Nujiang Neo-Tethys oceanic crust, respectively. We suggest that the Late Triassic metamorphic rocks of the Duguer area in the central South Qiangtang subterrane provide evidence of continental collision between the North and South Qiangtang subterranes, following the subduction of oceanic crust. It is likely that deep subduction of oceanic crust occurred along the Longmu Co–Shuanghu–Lancangjiang suture zone (LSLSZ), which would have hindered exhumation owing to the high density of oceanic crust. Subsequent break-off and delamination of the subducted oceanic slab at ~220 Ma may have resulted in exhumation of high-pressure and high-grade metamorphic rocks in the South Qiangtang subterrane. The Late Jurassic ages of metamorphism and deformation obtained in this study indicate the occurrence of an Andean-type orogenic event within the South Qiangtang subterrane. This hypothesis is further supported by an apparent age gap in magmatic activity (150–130 Ma) along the magmatic arc, and the absence of Late Jurassic sediments.  相似文献   
809.
Various tectonic models have been proposed to account for the widely distributed igneous activities in the southeastern part of the South China Block (SCB) during the Triassic–Jurassic period. One of the major contending debates is on the timing of initiation of the palaeo-Pacific plate subduction under the SCB, due to lack of unequivocal evidence for arc magmatism during the period in this region.

The 191 ± 10 Ma (N = 5, MSWD = 12) calc-alkalic high-K I-type Talun metagranite occurs in the southern Tailuko belt of the Tananao metamorphic complex, Taiwan. In terms of age, this metagranite belongs to the Early Yanshanian igneous activity in the southeastern part of the SCB. However, its geographic position does not accord with the well-known general oceanward younging trend of the Yansnanian igneous rocks. In view of the large age uncertainty reported, this metagranite is redated in this study. Some zircons of this metagranite are high in U content and are metamict. Zircons with low U contents are analysed by SHRIMP yielding a more precise age of 200 ± 2 Ma (N = 10, MSWD = 4). In particular, the εHf(t) of these dated zircons ranges from +4.5 to +12.9. The metagranite mainly consists of quartz, K-feldspar, plagioclase, with minor amounts of garnet, biotite, zircon, apatite, and pyrrhotite. Chlorite and calcite are secondary phases overprinted by the later tectonic event(s). Its initial Sr isotope compositional range is 0.70473–0.70588, and εNd(t), +2.4 to +3.6. The results demonstrate that the genesis of this metagranite could be attributed to the assimilation-fractionation of a depleted mantle-derived basaltic magma, which was most likely related to arc magmatism. The present study therefore offers key evidence that during the Mesozoic, the palaeo-Pacific plate subduction underneath the SCB would have taken place no later than the very early Jurassic.  相似文献   

810.
胡军  徐德明  张鲲  王磊  陈沐龙  云平 《矿床地质》2017,36(2):303-316
新村钼矿床是海南省近年来发现的具中型规模的钼矿床。文章对赋矿二长花岗岩进行LA-ICP-MS锆石U-Pb同位素测年,获得~(206)Pb/~(238)U年龄加权平均值为(102.0±1.5)Ma(MSWD=2.3);对辉钼矿进行Re-Os同位素定年,获得5件样品的模式年龄范围为(97.29±1.43)Ma~(98.52±1.55)Ma,加权平均年龄为(97.84±0.64)Ma,等时线年龄为(98.90±3.40)Ma,成岩年龄与成矿年龄在误差范围内一致。辉钼矿的Re含量和锆石Hf同位素特征指示新村钼矿的成岩成矿物质来自于壳幔混源。新村钼矿床的成岩成矿年龄与海南岛最重要的钼成矿期(95~105 Ma)一致,属中国东部早白垩世晚期—晚白垩世早期钼成矿事件的一部分,与该时期岩石圈大规模拉伸减薄、软流圈上涌及强烈壳-幔作用密切相关。  相似文献   
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