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51.
Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS 总被引:6,自引:1,他引:6
Alistair B. Jeffcoate Tim Elliott Alex Thomas Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172
The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li. 相似文献
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Geochemical Information Indicating the Water Recharge to Lakes and Immovable Megadunes in the Badain Jaran Desert 总被引:1,自引:0,他引:1
CHEN Jiansheng ZHAO Xi SHENG Xuefeng Wang Jiyang GU Weizu and CHEN Liang State Key Laboratory of Hydrology-Water Resources Hydraulic Engineering Hohai University Nanjing Jiangsu E-mail: jschen@hhu.edu.cn Institute of Isotope Hydrology Research Hohai University Nanjing Jiangsu Institute of Geology Geophysics Chinese Academy of Sciences Beijing 《《地质学报》英文版》2005,79(4):540-546
1 Introduction The Badain Jaran Desert, located in western Inner Mongolia, China, has a unique landscape containing 144 lakes (72 of which are still watery) with a total water area of about 23 km2, and the world’s highest stationary sand dunes with a height between 200 m and 500 m. Much attention has been paid to the water recharge of the desert in the past decade. Investigations on the resources of water system there have been performed continuously since the early 1990s, which lead to th… 相似文献
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阿拉善地区前寒武纪斜长角闪岩的岩石学、地球化学、形成环境和年代学 总被引:8,自引:0,他引:8
阿拉善地区前寒武纪不同岩群、岩组和杂岩中的斜长角闪岩均呈层状产出 ,其原岩多为高铁拉斑玄武岩 ,普遍具有高钾高钛、稀土元素含量高、轻稀土元素富集的地球化学特征 ,与典型的大洋拉斑玄武岩、太古宙的TH1型和TH2 型拉斑玄武岩有较明显的区别。岩石组合特征和多种地球化学判别图解均表明 ,该区的斜长角闪岩主要形成于板内环境 ,属于板内裂陷或大陆边缘裂陷的大地构造环境。初步的同位素年代学研究表明 ,叠布斯格岩群中斜长角闪岩的原岩形成于新太古代 ,含黑云斜长角闪岩中的角闪石3 9Ar_40 Ar坪年龄和等时线年龄分别为 1918Ma和1919Ma ,说明其曾经历了古元古代角闪岩相变质作用的叠加。巴彦乌拉山岩组中斜长角闪岩形成于 2 2 71Ma~2 2 6 4Ma。波罗斯坦庙片麻杂岩中的斜长角闪岩已被 1818Ma和 1839Ma花岗片麻岩侵入 ,根据该杂岩体中斜长角闪岩与巴彦乌拉山岩组中同类岩石的地球化学特征 ,推断其形成于古元古代早期。阿拉善群德尔和通特组中的斜长角闪岩目前尚无确切的同位素年代学数据 ,但相同层位的石榴石二云母石英片岩中锆石离子探针定年已获得平均同位素年龄值为 136 3Ma ,推测它有可能形成于中元古代 相似文献
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MO Xuanxue DONG Guochen ZHAO Zhidan GUO Tieying WANG Liangliang CHEN Tao 《《地质学报》英文版》2005,79(1):66-76
Abstract Abundant mafic microgranular enclaves (MMEs) extensively distribute in granitoids in the Gangdisê giant magmatic belt, within which the Qüxü batholith is the most typical MME‐bearing pluton. Systematic sampling for granodioritic host rock, mafic microgranular enclaves and gabbro nearby at two locations in the Qüxü batholith, and subsequent zircon SHRIMP II U‐Pb dating have been conducted. Two sets of isotopic ages for granodioritic host rock, mafic microgranular enclaves and gabbro are 50.4±1.3 Ma, 51.2±1.1 Ma, 47.0±1 Ma and 49.3±1.7 Ma, 48.9±1.1 Ma, 49.9±1.7 Ma, respectively. It thus rules out the possibilities of mafic microgranular enclaves being refractory residues after partial melting of magma source region, or being xenoliths of country rocks or later intrusions. Therefore, it is believed that the three types of rocks mentioned above likely formed in the same magmatic event, i.e., they formed by magma mixing in the Eocene (c. 50 Ma). Compositionally, granitoid host rocks incline towards acidic end member involved in magma mixing, gabbros are akin to basic end member and mafic microgranular enclaves are the incompletely mixed basic magma clots trapped in acidic magma. The isotopic dating also suggested that huge‐scale magma mixing in the Gangdisê belt took place 15–20 million years after the initiation of the India‐Asia continental collision, genetically related to the underplating of subduction‐collision‐induced basic magma at the base of the continental crust. Underplating and magma mixing were likely the main process of mass‐energy exchange between the mantle and the crust during the continental collision, and greatly contributed to the accretion of the continental crust, the evolution of the lithosphere and related mineralization beneath the portion of the Tibetan Plateau to the north of the collision zone. 相似文献
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At first sight, experimental results and observations on rocks suggest that the Zr content in rutile, where equilibrated with quartz and zircon, should be a useful thermometer for metamorphic rocks. However, diffusion data for Zr in rutile imply that thermometry should not, for plausible rates of cooling, give the high temperatures commonly observed in high‐grade metamorphic rocks. It is suggested here that such observations can be accounted for by high‐T diffusive closure of Si in rutile, causing the interior of rutile grains to become insensitive to the thermometer equilibrium well above the temperature of Zr diffusive closure. Paired with comparatively slow grain boundary diffusion and problematic zircon nucleation, this allows for cases of Zr retention in rutile through temperatures where Zr is still diffusively mobile within rutile grains. Other observations that may be accounted for in this context are large inter‐grain ranges of rutile Zr contents uncorrelated with rutile grain size, and flat Zr profiles across individual rutile grains, counter to what would be expected from diffusive closure. A consequence is that it is unlikely that Zr‐in‐rutile thermometry will be useful for estimating rock cooling rates. 相似文献
60.
Timing of folding is usually dated indirectly, with limited isotopic dating studies reported in the literature. The present study investigated the timing of intracontinental, multi-stage folding in Upper Proterozoic sandstone, limestone, and marble near Beijing, North China, and adjacent regions. Detailed field investigations with microstructural, backscattered electron (BSE) images and electron microprobe analyses indicate that authigenic muscovite and sericite crystallized parallel to stretching lineations/striations or along thin flexural-slip surfaces, both developed during the complex deformation history of the study area, involving repeated compressional, extensional and strike-slip episodes. Muscovite/sericite separates from interlayer-slip surfaces along the limbs and from dilatant sites in the hinges of folded sandstones yield muscovite 40Ar/39Ar plateau ages of ∼158–159 Ma, whereas those from folded marble and limestone samples yield ages of 156 ± 1 Ma. Muscovite from thin flexural-slip planes on fold limbs and hinges yields ages within analytical error of ∼155–165 Ma. Further muscovite samples collected from extensionally folded limestone and strike-slip drag folds yield younger ages of 128–125 Ma with well-defined plateaus. To assess the potential influence of the detrital mica component of the host rock on the age data, two additional muscovite samples were investigated, one from a folded upper Proterozoic–Cambrian sandstone outside the Western Hills of Beijing and one from a folded sandstone sampled 20 cm from folding-related slip planes. Muscovite separates from these samples yield significantly older ages of 575 ± 2 Ma and 587 ± 2 Ma, suggesting that the timing of folding can be directly determined using the 40Ar/39Ar method. This approach enables the identification and dating of distinct deformation events that occur during multi-stage regional folding. 40Ar/39Ar dating can be used to constrain the timing of muscovite and sericite growth at moderate to low temperatures (<400 °C) during folding, yielding well-defined plateau ages and thereby the age of deformation in the upper crust. 相似文献