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21.
Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain 总被引:1,自引:0,他引:1
The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ11B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ11B are related to pollution of human origin. 相似文献
22.
Taeko Shinonaga Helmuth Aigner Dilani Klose Peter Spinder Heinz Fröschl David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101
The recommended concentrations of 239Pu, 240Pu and 239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of 239Pu and 240Pu (239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of 242Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg?1, (28 ± 3) Bq kg?1 and (66 ± 4) Bq kg?1 are proposed as recommended values for 239Pu, 240Pu and 239+240Pu, respectively, and (9.5 ± 0.4) Bq kg?1 for 238Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg?1, (3.3 ± 0.4) ng kg?1 and (0.015 ± 0.003) ng kg?1 for 239Pu, 240Pu and 238Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study. 相似文献
23.
We discuss wind variability in intermediate luminosity B supergiants. Because these are not the hottest, most luminous or just about other kind of -est stars, they have not attracted much attention. However, since their wind lines are well-developed, but unsaturated, they make ideal diagnostics for time dependent wind studies. We show that their wind profiles undergo large scale variability and that this phenomenon is quite common. We also discuss a time series for the B0.5 Ib HD 64760 which suggests the long sought after connection between wind and photospheric activity. Newly developed analysis techniques needed to extract physical information from the wind lines are discussed, and results are applied to the time series. 相似文献
24.
阿克库勒地区卡拉沙依组碎屑岩储层的成分成熟度和结构成熟度均较低.储层的次生溶蚀孔隙所占比例远高了:原生孔隙,次生孔隙是储层的主要储集空间.样品数据统计显示,卡拉沙依组储层属于低孔、低渗储层类型.根据岩石薄片、铸体薄片观察及储层样品的扫描电镜和阴极发光分析结果,本区石炭系储层主要经历的成岩作用有压实(压溶)作用、胶结作用、溶蚀作用和交代作用,其中碳酸盐矿物的沉淀和溶蚀作用是本区卡拉沙依组储层所经历的最重要的成岩作用.成岩作用已达到晚成岩B期,早期方解石交代石英颗粒并发生大量溶蚀,生成大量次生孔隙,晚期方解石没有发生溶蚀. 相似文献
25.
26.
Yao Chun-xial Li Bao-sheng Jin He-ling David Dian Zhang Yan Man-cun Zhu Yi-zhi Li Hou-xin Zhang Yu-hong Luo Kai-li 《地理学报(英文版)》2002,12(1):65-71
The paper makes some analyses on 11 trace elements in the Milanggouwan stratigraphical section in the Salawusu River valley,
which is regarded as a prototype geology-palaeoclimate record since 150 ka BP. The results show that the content and variation
of trace elements has experienced remarkably regular changes in the pace with coarse and fine sedimentary cycles of palaeo-aeolian
sands to its overlying fluvio-lacustrine facies or/and palaeosols. The trace elements with chemical properties of relatively
active (V, Sr, Cu, Ni, As) and relatively stable (P, Pb, Rb, Mn, Nb, Zr) are a manifestation of the corresponding 27 changeable
cycles between peak and valley values, appearing a multi-fiuctuational process line of relative gathering and migration since
then. The low numerical value distribution of these two types of trace elements in the aeolian sand facies represents erosion
and accumulation under wind force during the cold-dry climate. Whereas their enrichments in both fluvio-lacustrine facies
and palaeosols are related to the valley’s special low-lying physiognomic position between the Ordos Plateau and the Loess
Plateau under the warm and humid climate conditions. The above relatively migrated and gathered change of the trace elements
is the result of 27 climatic cycles of cold-dry and warm-humid, which is probably caused by repeated alternations of winter
monsoon and summer monsoon in the Mu Us Sandy Land influenced by the climate vicissitudes in northern hemisphere during glacial
and interglacial periods since 150 ka BP. 相似文献
27.
PowerBuilder 8.0中C/S模式应用过渡到B/S模式应用的实现技术 总被引:1,自引:0,他引:1
简要分析了PowerBuilder 8.0中各种B/S解决方案的优劣,探讨了适用于已有C/S模式应用过渡到B/S模式应用的实现方法,以及利用ASP技术实现对不同类型的客户测览器隐藏底层实现方法的技术,并给出了C/S模式应用过渡到B/S模式应用的一个实例。 相似文献
28.
Manuel Moreira Jerzy Blusztajn Joshua Curtice Stan Hart Henry Dick Mark D. Kurz 《Earth and Planetary Science Letters》2003,216(4):635-643
In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10−10 to 2.5×10−7 ccSTP/g by crushing and from 5.4×10−8 to 2.4×10−7 ccSTP/g by melting. 3He/4He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated 20Ne/22Ne and 21Ne/22Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric 20Ne/22Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/3He ratio of these crustal gabbros will generate very radiogenic 4He/3He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing. 相似文献
29.
本文用1959~1994年6、7、8月全国范围47个5°×5°经纬度网格降水资料分析了夏季降水异常空间模的月际差异,并在此基础上用西太平洋副高指数及青藏高原指数#FKB#FS分析降水异常空间模与环流的关系,为检验环流指数与降水相关场的整体信度,还对8月份降水资料进行了Monte-Carlo检验。结果表明,夏季总降水异常的空间模在每一月份中并非表现得同样清楚,江淮流域与河套及华南的反相关在8月份表现得最清楚。而青藏高原中东部南北两侧的负相关在6月及8月很清楚,7月份次之。8月份西太平洋副高北界异常对江淮流域与河套及华南地区降水异常反相关的产生有很大作用。副高稳定偏北时,河套、华南易涝,江淮易旱。反之亦然。青藏高原指数#FKB#FS与逐月降水的相关分析表明,青藏高原上高压及低涡活动对高原中东部南北两侧负相关的产生有一定作用。当高压活动偏多时,北侧易旱、南侧易涝。并且6月及8月的作用较大,7月较小。另外,8月份副高活动对这一降水异常空间模的产生也有一定影响。 相似文献
30.
40Ar/39Ar同位素年龄测定,获得南天山蛇绿混杂岩基质黑云母石英片岩单矿物黑云母的两个坪年龄分别为(370.0±4.8)Ma和(259.0±3.3)Ma;中天山南缘长英质糜棱岩单矿物黑云母的坪年龄为(250.5±7.9)Ma,二云母花岗岩单矿物白云母的坪年龄为(348.9±0.3)Ma。结合南天山古生代沉积特征和塔里木及伊犁-哈萨克斯坦板块古地磁数据的综合分析,提出南天山晚泥盆世至石炭纪早期完成向伊犁-哈萨克斯坦板块的B型俯冲,中-晚二叠世进行陆内A型俯冲造山的板块碰撞演化模式。 相似文献