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51.
52.
碳酸盐岩与泥质烃源岩生气规律对比研究 总被引:10,自引:1,他引:10
配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验,研究了碳酸盐岩生气量随成熟度和温度变化的趋势,探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数,与岩性无关;碳酸盐岩的产气规律与泥质岩相似,而且两者产烃的量级也相当,并不存在碳酸盐岩生排烃效率高的现象;碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化;不同岩性的有机质的产烃效率主要受温度和有机质类型决定。 相似文献
53.
Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea 总被引:1,自引:0,他引:1
Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ13CPDB = 2.4 to 4.0‰ and δ18OSMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts. 相似文献
54.
ABSTRACT In situ measurements of lakebed sediment erodibility were made on three sites in Hamilton Harbour, Lake Ontario, using the benthic flume Sea Carousel. Three methods of estimating the surface erosion threshold (τc(0)) from a Carousel time series were evaluated: the first method fits measures of bed strength to eroded depth (the failure envelope) and evaluates threshold as the surface intercept; the second method regresses mean erosion rate (Em) with bed shear stress and solves for the floc erosion rate (Ef) to derive the threshold for Em = Ef = 1 × 10?5 kg m?2 s?1; the third method extrapolates a regression of suspended sediment concentration (S) and fluid transmitted bed shear stress (τ0) to ambient concentrations. The first field site was undisturbed (C) and acted as a control; the second (W) was disturbed through ploughing and water injection as part of lakebed treatment, whereas the third site (OIP) was disturbed and injected with an oxidant used for remediation of contaminated sediment. The main objectives of this study were: (1) to evaluate the three different methods of deriving erosion threshold; (2) to compare the physical behaviour of lacustrine sediments with their marine estuarine counterparts; and (3) to examine the effects of ploughing and chemical treatment of contaminated sediment on bed stability. Five deployments of Sea Carousel were carried out at the control site. Mean erosion thresholds for the three methods were: τc(0) = 0·5 (±0·06), 0·27 (±0·01) and 0·34 (±0·03) Pa respectively. Method 1 overpredicted bed strength as it was insensitive to effects in the surface 1–2 mm, and the fit of the failure envelope was also highly subjective. Method 2 exhibited a wide scatter in the data (low correlation coefficients), and definition of the baseline erosion rate (Ef) is largely arbitrary in the literature. Method 3 yielded stable (high correlation coefficients), reproducible and objective results and is thus recommended for evaluation of the erosion threshold. The results of this method correlated well with sediment bulk density and followed the same trend as marine counterparts from widely varying sites. Mass settling rates, expressed as a decay constant, k, of S(t), were strongly related to the maximum turbidity at the onset of settling (Smax) and were also in continuity with marine counterparts. Thus, it appears that differences in salinity had little effect on mass settling rates in the examples presented, and that biological activity dominated any effects normally attributable to changes in salinity. Bedload transport of eroded aggregates (2–4 mm in diameter) took place by rolling below a mean tangential flow velocity (Uy) of 0·32 ms?1 and by saltation at higher velocities. Mass transport as bedload was a maximum at Uy = 0·4 ms?1, although bedload never exceeded 1% of the suspended load. The proportion of material moving as bedload was greatest at the onset of erosion but decreased as flow competence increased. Given the low bulk density and strength of the lakebed sediment, the presence of a bedload component is notable. Bedload transport over eroding cohesive substrates should be greater in estuaries, where both sediment density and strength are usually higher. Significant differences between the ploughed and control sites were apparent in both the erosion rate and the friction coefficient (φ), and suggest that bed recovery after disruption is rapid (< 24 h). τc(0) increased linearly with time after ploughing and recovered to the control mean value within 3 days. The friction coefficient was reduced to zero by ploughing (diagnostic of fluidization), but increased linearly with time, regaining control values within 6 days. No long‐term reduction in bed strength due to remediation was apparent. 相似文献
55.
碳酸盐与陆源碎屑的混合沉积研究至今尚未引起足够重视。文献屈指可数。扬子西经缘龙门山地区盆纪发育了了这类良好的混合沉积。作者根据实际材料,首次从这一思路出发,识别该区泥盆纪Emsian期到Givetian早期的混积相四种,混积亚相约14种,阐明了其优势混积作用;根据混积作用特征、沉积背景关系,划分出两大混积类型,即泥质背景下的混积1型和砂灰质背景下的混积Ⅱ型;对混积作用机理进行了探讨;并指出不同级次 相似文献
56.
新疆玛纳斯湖沉积柱样的古气候古环境研究 总被引:34,自引:3,他引:34
本文提供玛纳斯湖两个长约5m柱样的研究结果,并据此讨论新疆西部晚第四纪古气候演化。研究内容包括沉积物的矿物组成、自生碳酸盐的稳定同位素组成、孢粉组合等;用加速器质谱(AMS)测定碳酸盐或有机质的^14C年龄。讨论了δ^18O剖面与亚洲夏季季风的关系。柱样的研究结果表明:玛纳斯湖地区晚更新世的37000-32000aB.P.气候潮湿,而后又回到末次冰期的极端干旱气候。12000-10000aB.P. 相似文献
57.
黔南Triticites带旋回层序碳同位素特征及冰川型海平面变化 总被引:4,自引:0,他引:4
应用层序地层学理论对黔南独山地区晚石炭世麦粒链带地层进行了详细的沉积层序分析和系统的碳同位素测定,识别出2个三级沉积层序和17个准层序,其可与北美中大陆同期地层中发现的2个三级沉积层序和17个亚层序对比,是晚石炭世Gzhelian期存在全球沉积记录同时性的佐证。同时探讨了碳同位素演化与全球海平面变化之间的内在联系,总结出沉积层序内碳同位素演化规律。 相似文献
58.
This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg–1 pH of 7.6 and p(CO2) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg–1, pH of 7.70 and p(CO2) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO2) up to 5.6 times the atmospheric P(CO2). 相似文献
59.
Wolfgang H. Berger Memorie K. Yasuda Torsten Bickert Gerold Wefer 《International Journal of Earth Sciences》1996,85(3):466-495
We provide a reconstruction of atmospheric CO2 from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template
of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western
equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple
regression between deep-sea data, on one hand, and ice-core CO2 data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO2 can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change
are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric
CO2 (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on
short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO2. 相似文献
60.
Chr Samtleben A. Munnecke T. Bickert J. Pätzold 《International Journal of Earth Sciences》1996,85(2):278-292
The Silurian of Gotland, Sweden, consists of 440 m of carbonate deposits. Repeatedly, uniform sequences of micritic limestones
and marls are interrupted by complex-structured reefs and by adjacent platform sediments. Generally, the alteration of facies
is interpreted as the result of sea-level fluctuations caused by a gradual regression with superimposed minor transgressive
pulses. The purpose of this study is a facies interpretation based on both field observations and stable isotope measurements
of brachiopod shells. Approximately 700 samples from stratigraphically arranged localities in different facies areas have
been investigated. The carbon and oxygen isotopes show principally parallel curves and a close relationship to the stratigraphic
sequence. Lower values occur in periods dominated by deposition of marly sequences. Higher values are observed in periods
dominated by reefs and extended carbonate platforms. The oxygen isotope ratios are interpreted to reflect paleosalinity changes
due to varying freshwater input, rather than to paleotemperature. Carbon isotope ratios are believed to have been connected
to global changes in the burial of organic carbon in black shales during periods of euxinic deep water conditions. Consequently,
the facies succession on Gotland results from global paleoclimatic conditions. Changes in terrigenous input due to different
rates of weathering and freshwater runoff, rather than sea-level fluctuations, control the carbonate formation of the Silurian
on Gotland. 相似文献