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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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1 IntroductionAccordingtogeologicalstructure ,theGansu Ningxia Qinghaiareabelongstothenortheastmar ginofQinghai Tibetblock .Thisareahasbeenpaidmuchattentionby geo specialistsinChinaandabroadbecauseofitssignificanttectonicmovement,itsintensiveseismicity ,anditsimportanceinearth quakehazardmitigation .IntheDevelopmentPro gramonNationalKeyBasicResearchesundertheProject“MechanismandPredictionofContinentalStrongEarthquakes”,themechanismsofcontinen talstrongearthquakesarestudied ,usinghypo…  相似文献   
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ECOLOGICAL SERIES OF SOIL ANIMALS IN DARLIDAI MOUNTAIN   总被引:1,自引:0,他引:1  
The ecological series of soil animals under the broad-leaved and pine mixed forest in Darlidai Mountainwas studied. Seven sample plots were selected according to different altitude gradients, which belong to different vegeta-tion types. By investigating and analyzing soil animals in every sample plot it is found that there are 45 groups and 1956individuals, which axe involved in 3 phylums, 7 classes, 16 orders, respectively. The altitude is a key factor which af-fects ecological series of soil animals. Both the groups and individuals of soil animals increase with altitude increasingunder certain conditions, which contrastes with ordinary cases, resulting from special micro-climate in studied area. Thegroups and individuls of soil animals are the most under the broad-leaved and pine forest on the top of the mountain, andthe least under Picea-Abies forest in the foot of the mountain.  相似文献   
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本文简要介绍了陆地系列地球资源卫星的轨道特征,并以陆地—5号资源卫星为例,根据南山站的座标计算出该站对陆地—5号资源卫星的可观测范围及以该站为中心的卫星的覆盖区域。  相似文献   
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粤东海岸东起闽粤交界的大埕湾,西迄深圳市的大鹏湾,岸线曲折,港湾较多,河溪人海泥沙在潮间带及紧邻5m 等深线以内形成大片海涂,土壤类型多样,以泥质和沙泥质土壤为主;除河口湾的土壤含盐量低外,其余较高;土壤有机质含量中等,钾素较丰富,磷素较低。因地处亚热带南缘,光、热和水资源条件较好,且多数海湾有深入内地的小海湾和潮沟,甚适合发展海水养殖与晒盐,韩江口的义丰河和海门龟头海大闸外等滩地尚有围垦价值。多处海湾潮滩沙土适合作海滨浴场,也有小片滩地红树林适合旅游观赏。  相似文献   
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1IN T R O D U C T IO N The western China isfacinggrowing problems of eco- logicaland economic development. The disparitiebse- tween the socio-economy of the western and eastern China were enlarging, and the major ecologicalprob- lems stilelvolve as past(H…  相似文献   
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