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11.
梅世蓉 《地震学报(英文版)》1995,(3)
Onthephysicalmodelofearthquakeprecursorfieldsandthemechanismofprecursors'timespacedistribution──originandevidencesof thestron... 相似文献
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Treatment of high fluoride concentration wastewater by layered double hydroxides: Mechanism studies 总被引:1,自引:0,他引:1
Liang LU Jing HE 《中国地球化学学报》2006,25(B08):160-161
An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides (LDHs) are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China. 相似文献
14.
CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174
Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition. 相似文献
15.
A numerical procedure is described for the analysis of the vertical deformation and the stress distribution of the strip footings
on layered soil media. Three layers of soil with different stiffness are considered with the middle soil layer the thinnest
and most stiff layer. The soil media is discretized and using the theory of elasticity, the governing differential equations
are obtained in terms of vertical and horizontal displacements. These equations along with appropriate boundary and continuity
conditions are solved by using the finite difference method. The vertical and horizontal displacements, strains and stresses
are found at various nodes in the soil media. Parametric studies are carried out to study the effect of the placement depth
of the middle soil layer, the relative ratios of the moduli of deformation of the soil layers on the vertical displacement
of the footing and the vertical stress distribution. These studies reveal that the middle thin but very stiff layer acts like
a plate and redistributes the stresses on the lower soft soil layer uniformly. The displacement on the top and bottom of the
middle soil layer is almost the same showing that the compression of the middle layer is negligible as it is very stiff. 相似文献
16.
Cyclicity in the Main and Upper Zones of the Bushveld Complex, South Africa: Crystallization from a Zoned Magma Sheet 总被引:9,自引:0,他引:9
The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock 87Sr/86Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial 87Sr/86Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetiteilmeniteapatite)layers and changes up-section from gabbronorite (An72 plagioclase;Mg# 74 clinopyroxene) to magnetiteilmeniteapatitefayaliteferrodiorite (An43; Mg# 5 clinopyroxene; Fo1 olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V2O5 of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO2 and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO2 and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation 相似文献
17.
冲积平原区土壤元素组成特征及其示踪作用 总被引:5,自引:3,他引:5
应用土壤元素组成特征研究基础地质问题是覆盖区多目标地球化学调查工作后项重要任务。通过对珠江三角洲,江汉平原,成都盆地3个冲积平原区土壤元素组成特征的研究,探讨了其对土壤成壤母质特性的示踪作用,为今后开展类似的研究工作提供了一种思路。 相似文献
18.
层柱粘土材料制备与应用研究 总被引:9,自引:1,他引:9
简述了层柱粘土矿物材料研究与应用的现状和进展。利用粘土矿物蒙脱石作母体,通过大体积的铝、锆、硅等交联剂插层可制成层柱多孔材料,在酸催化、氧化还原催化中均有十分广阔的应用前景。研究表明,改进制备工艺后可提高层柱蒙脱石的热稳定性、比表面积和催化活性;通过酸或表面活性剂等预处理,再进行粘土的支撑,可以调节和控制层柱粘土的结构与性能;采用有机改性和模板导向等技术,可获得孔径介于大微孔和中孔之间的新型层柱粘土矿物材料,并应用于大分子催化反应与吸附,为粘土矿物材料合成和应用开辟了新方向。 相似文献
19.
软土地基沉降计算的误差分析 总被引:2,自引:0,他引:2
对引起路堤荷载下软土地基沉降从竖应力、固结沉降、瞬时沉降和后期沉降的计算四个方面,常见计算方法误差的诸多因素,从受力、沉降原理上进行了详细分析并提出一些建议,以使沉降更为接近实际. 相似文献
20.
圆弧状沉积盆地与软土单覆盖层出平面地表运动对比 总被引:2,自引:0,他引:2
采用解析方法,通过圆弧状沉积盆地与同样参数的软土均匀单覆盖层的对比,研究沉积盆地对平面SH波二维散射效应和其出平面地表运动。数值对比结果表明:(1)波垂直入射时盆地中央地表位移幅值反应,其随频率变化形式与软土单覆盖层的地表运动有较强的对应性,且此时单覆盖层地表位移幅值为其下降;(2)盆地的二维散射效应特点显著波的汇聚作用使盆地中的地表运动显著放大,总体上较软土单覆盖层的地表位移幅值要大,其频域内的最大反应则明显大于单覆盖层情况,但最大反应在盆地表面出现的位置依赖于入射波角度、盆地深宽比和盆地的软硬程度;(3)沉积盆地中地表位移运动有强烈扭转效应,且随盆地变软和入射波频率增高而增强。 相似文献