Isotopic evidence of TSR origin for natural gas bearing high H<Subscript>2</Subscript>S contents within the Feixianguan Formation of the northeastern Sichuan Basin,southwestern China   总被引：3，自引：1，他引：2  

Guangyou?ZhuEmail author  Shuichang?Zhang  Yingbo?Liang  Jinxing?Dai  Jian?Li 《中国科学D辑(英文版)》2005,48(11):1960-1971

The northeastern area of Sichuan Basin, southwestern China, is the area with the maximal reserve of natural gas containing higher hydrogen sulphide (H₂S) that has been found among the petroliferous basins of China, with the proven and controlled gas reserve of more than 200 billion cubic meters. These gas pools, with higher H₂S contents averaging 9%, some 17%, are mainly distributed on structural belts of Dukouhe, Tieshanpo, Luojiazhai, Puguang, etc., while the oolitic-shoal dolomite of the Triassic Feixianguan Fm. (T₁f) is the reservoir. Although many scholars regard the plentiful accumulation of H₂S within the deep carbonate reservoir as the result of Thermochemical Sulfate Reduction (TSR), however, the process of TSR as well as its residual geological and geochemical evidence is still not quite clear. Based on the carbon isotopic analysis of carbonate strata and secondary calcite, etc., together with the analysis of sulfur isotopes within H₂S, sulphur, gypsum, iron pyrites, etc., as well as other aspects including the natural gas composition, carbon isotopes of hydrocarbons reservoir petrology, etc., it has been proved that the above natural gas is a product of TSR. The H₂S, sulphur and calcite result from the participation of TSR reactions by hydrocarbon gas. During the process for hydrocarbons being consumed due to TSR, the carbons within the hydrocarbon gas participate in the reactions and finally are transferred into the secondary calcite, and become the carbon source of secondary calcite, consequently causing the carbon isotopes of the secondary calcite to be lower (−18.2‰). As for both the intermediate product of TSR, i.e. sulfur, and its final products, i.e. H₂S and iron pyrites, their sulfur elements are all sourced from the sulfate within the Feixianguan Fm. During the fractional processes of sulfur isotopes, the bond energy leads to the ³²S being released firstly, and the earlier it is released, the lower δ ³⁴S values for the generated sulphide (H₂S) or sulfur will be. However, for the anhydrite that participates in reactions, the higher the reaction degree, the more ³²S is released, while the less ³²S remains and the more δ ³⁴S is increased. The testing results have proved the process of the dynamic fractionation of sulfur isotopes.  相似文献   

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff     

David?L.?DettmanEmail author  Manuel?R.?Palacios-Fest  Hudson?H.?Nkotagu  Andrew?S.?Cohen 《Journal of Paleolimnology》2005,34(1):93-105

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.  相似文献   

Zinc, Lead and Cadmium Content in Meadow Plants and Mosses Along the M3 Motorway (Hungary)     

T. Naszradi  A. Badacsonyi  N. Németh  Z. Tuba  F. Batiĉ 《Journal of Atmospheric Chemistry》2004,49(1-3):593-603

The heavy metal content was investigated in meadow plants located in a cultivated area and situated along the M3 motorway (Hungary). In addition to the meadow plants used as passive bioindicators, active bioindicators were also exposed to examine the accumulation rate of air pollutants. Tortula ruralis (Hedw.) Geartn. ssp. ruralis was applied to monitor the status of the environment. Meadow plant samples were collected at distances of 5, 10, 25, 50 and 100 m from the motorway and moss samples were exposed at the same distances. The zinc, lead and cadmium content of meadow plants and moss samples were analysed by ICP spectrophotometry. It was found that the zinc, lead and cadmium contents of the meadow plants decreased as the distance increased from the motorway. There was a significant difference even between values measured at the distances of 5 m and 10 m. The heavy metal contents in the moss samples exceeded those of the meadow plants. The heavy metal content in moss samples decreased with distance from the motorway. On comparing the data with Hungarian standards, it was found that measured values did not exceed the maximum allowed concentration levels.  相似文献   

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume   总被引：2，自引：0，他引：2  

KOKFELT  THOMAS FIND; HOERNLE  KAJ; HAUFF  FOLKMAR; FIEBIG  JENS; WERNER  REINHARD; GARBE-SCHONBERG  DIETER 《Journal of Petrology》2006,47(9):1705-1749

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction  相似文献   

Fluid evolution in the Rushan lode gold deposit of Jiaodong Peninsula, eastern China   总被引：2，自引：0，他引：2  

Fang-Fang Hu  Hong-Rui Fan  Ming-Guo Zhai  Cheng-Wei Jin 《Journal of Geochemical Exploration》2006,89(1-3):161

The Rushan gold deposit in the Jiaodong Peninsula is currently the largest lode gold in China. Gold occurs mainly in pyrite- and polymetallic sulfide–quartz vein/veinlet stockworks. Fluid inclusions in the deposit are divided into three main types, namely CO₂–H₂O, H₂O–CO₂ ± CH₄ and aqueous ones. Microthermometric data show that the pre-gold fluids were CO₂-dominant (X_CO2 up to 0.53), and the total homogenization temperatures fall in the range of 298377 °C. These fluids, modified by fluid/wallrock reactions, gradually evolved into fluids with less CO₂ (X_CO2 = 0.010.19) in the main ore-forming stage, and the total homogenization temperatures range from 170 to 324 °C. Hydrogen and oxygen stable isotope data suggest that ore-forming fluids were mixture of magmatic and meteoritic origin. Co-occurrence of gold and sulfides implies that gold was most likely transported in the form of gold–sulfide complexes. The wide distribution of CO₂ inclusions means that the pH variation during gold transportation was controlled by CO₂ buffering.  相似文献   

科尔沁沙地樟子松水分来源贡献率的稳定同位素模型估计(英文)     

魏雅芬  方杰  赵学勇  伊梅  张瑞军  李胜功 《资源与生态学报(英文版)》2012,(4):308-315

利用稳定同位素技术测定降水、土壤水、植物茎干水的同位素组成,结合多元线性混合模型(IsoSource)确定科尔沁沙地东南部樟子松人工林内樟子松的根系吸水范围以及各水源的水分贡献率。通过连续观测强降水事件前后樟子松水分来源的变化,探究降水对樟子松水分利用的影响。结果表明樟子松茎干水与20cm以下土层的土壤水同位素组成最为接近,樟子松的水分吸收主要集中在这一层(最大取样深度80cm)。IsoSource模拟结果与观测结果一致,土壤水分条件较好时,大约60%以上的水分来自于20-80cm土层;当这一深度土壤含水量降低时,樟子松将会更多地依赖更深层的土壤水分。樟子松根系分布的最大深度远小于地下水位,因此很难利用到地下水。2009年7月13日14.4mm的降水前后,樟子松茎干水同位素组成的变化表明,降水结束后36小时樟子松可以感应到降水对表层20cm土壤水分的补充,这一土层的水分贡献率在接下来的24小时内迅速降低。不同水分条件下水分来源的多样性表明樟子松能较好地适应沙地生境。  相似文献   

最近500年来福建玉华洞石笋氧同位素记录及气候意义     

姜修洋  李志忠  李金全  孔兴功  郭允 《地理科学》2012,(2):207-212

基于福建将乐玉华洞一支石笋(YH1)4个230Th年龄和370个氧同位素数据,并利用具有年层时标的湖北清江和尚洞石笋氧同位素记录的校正,重建了AD 1530以来1~3 a分辨率的石笋氧同位素序列。与当地现代器测气象资料对比发现,最近60 a来玉华洞石笋δ18O与当地夏半年降水量相关性最为显著(R=-0.35,n=55),而受温度的影响较弱,玉华洞石笋氧同位素较好的指示了当地夏半年降水量变化的信息。最近100 a来,福建玉华洞石笋的氧同位素组成具有逐渐变重的趋势,与其他地区高分辨率石笋δ18O具有相同的变化趋势,而且也与季风指数指示的季风减弱趋势相一致,进一步证实季风区石笋δ18O反映了东亚季风大尺度环流特征;在小冰期中后期(AD 1530~1850),玉华洞石笋δ18O在平均值-5.9‰高频振荡,存在一系列的数十年际尺度的季风增强和减弱事件,与亚洲—太平洋涛动(Asian Pacific Oscillation,APO)指数密切相关,说明玉华洞石笋δ18O所指示的降水信息受APO变化的影响。  相似文献   

山东大张矽卡岩型铁矿床中铁的富集机制 ——来自流体包裹体和氢、氧同位素的证据     

张兆年  曹毅  朱裕振  庞振山  沈立军  管继云  郭晨芳 《矿床地质》2022,41(1):91-105

大张铁矿是鲁西地区近年来新发现的一个重要的矽卡岩型矿床.矿体主要赋存于石英二长闪长岩与奥陶系马家沟组灰岩接触带及其附近.根据脉体穿插关系和交代蚀变特征,将大张矽卡岩型铁矿床成矿过程划分为矽卡岩阶段、氧化物阶段、硫化物阶段和碳酸盐阶段.通过对透辉石、绿帘石、石英和方解石等透明矿物显微观察发现,大张铁矿中流体包裹体类型主要...  相似文献   

铅对不同土壤中青菜生长的影响     

汤莉莉  牛生杰  徐建强  晏培  杨雪贞  谢学俭 《南京气象学院学报》2008,31(1):104-108

采用盆栽试验,研究了南京和北京土壤中Pb污染对青菜生长的影响。结果表明：土壤质地对青菜生长有明显的影响;在土壤Pb含量低的处理水平下,对青菜的生长有一定影响;低含量范围内,青菜中Pb含量随土壤Pb处理含量的增加出现先升后降的变化趋势;在100mg／kg时,青菜的生长受到抑制,植株中Pb的含量高于对照组和200mg／kgPb处理。  相似文献   

Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: The modern Qinghai Lake, Qinghai–Tibet Plateau     

Weiguo Liu  Xiangzhong Li  Ling Zhang  Zhisheng An  Liming Xu 《Chemical Geology》2009,268(1-2):126-136

The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ¹⁸O values, and these vary with water salinity. The relationship between lake water δ¹⁸O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ¹⁸O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ¹⁸O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ¹⁸O values of ostracod and bulk carbonate.  相似文献