Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan   总被引：1，自引：0，他引：1  

Yasuhiro Kato    Koichiro Fujinaga  Tatsuo Nozaki    Kentaro Nakamura    Ryuji Ono  Hiroshi Osawa 《Resource Geology》2005,55(4):291-300

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.  相似文献   

湖南芙蓉锡矿床中萤石的Sr－Nd同位素研究   总被引：2，自引：0，他引：2  

赵葵东  蒋少涌  姜耀辉  凌洪飞 《地球学报》2005,26(Z1):171-173

芙蓉锡矿床是一个新探明的超大型锡矿床，产于湘南的骑田岭花岗岩体中。本次研究测试了该矿床中与锡石硫化物共生的萤石的Sr和Nd同位素组成。各矿脉中萤石的87Sr/86Sr比值并不相同，变化从0.70770～0.71484，反映了成矿流体的初始87Sr/86Sr比值并不均一。萤石的Sm－Nd同位素组成并没有构成很好的等时线，计算的ENd（t）值变化在－6.6～－9.8之间。萤石的Sr－Nd同位素组成并不同于花岗岩，成矿流体中的Sr和Nd有很大一部分来自围岩的碳酸盐岩地层。  相似文献   

翁泉沟含铀硼铁矿床综合开发利用研究与对策   总被引：1，自引：1，他引：1  

夏学惠  魏祥松 《化工矿产地质》2005,27(2):65-70

翁泉沟含铀硼铁矿中硼(B2O3)储量约占我国总储量的一半,矿床经勘探后一直没有很好得到利用。在综合利用资料积累与地质研究基础上,认为影响矿床利用的因素主要为矿石分解状况。研究认为矿床中硼镁铁矿-磁铁矿和硼镁石-磁铁矿两种主要类型矿石中绝大部分为可利用的变质后期热液作用产生的硼镁石-磁铁矿型矿石。这种热液作用形成的矿石是有规律可寻的。为达到综合利用的目的,有必要按不同类型矿石重新圈定矿体,根据不同矿体中硼镁铁矿分解率指标,选择两种不同综合利用方案。  相似文献   

江西修水西部金矿成矿地质条件分析     

张振 《城市地质》2005,17(2):20-25

通过对地层、岩浆岩、构造及化探异常与成矿关系的分析，认为江西修水西部地区具有寻找中一大型金矿床的潜力。  相似文献   

西藏自治区乃东县劣布铜矿综合地质特征     

江化寨  陈自康 《地质找矿论丛》2005,20(8):81-86

文章介绍区域地质背景、矿区地物化特征，对成矿时代、流体包裹体特征进行初步研究，并指出找矿远景，希望对矿区的矿产勘查具有借鉴和指导意义。  相似文献   

雅满苏铁矿床地质特征及成因浅析     

王兴保 《地质找矿论丛》2005,20(8):125-128

雅满苏铁矿矿体的空间分布受成矿期断裂构造的控制，呈透镜状、舒缓波状延伸，分3个层位产出。铁矿的形成与火山热液活动关系密切，矿体中既有热液活动的特征又有矿质流体贯入的特征，早期热液活动形成交代充填型矿石，后期富铁流体贯入充填后形成品位较高的磁铁矿体。  相似文献   

广西南丹地区有色金属尾砂型人工矿床地质特征及其资源化     

陈志强苏亮  杨保疆 《地质找矿论丛》2005,20(8):139-144

广西南丹地区尾矿分布于大厂、车河、芒场等矿区。尾砂来自以锡石为主的多金属矿床，尾砂中除Sn，Pb，Zn，Ag，Sb的质量分数达到工业指标外，Au亦达到综合利用指标。通过试验证明，对尾矿中的细微粒锡石可采用风力分级选矿、磁选和化学选矿等方法回收；尾砂中的非金属资源可作为填充材料、水泥原料利用，使尾砂型人工矿床充分的资源化。  相似文献   

Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids   总被引：16，自引：2，他引：16  

Shifeng Dai  Chen-Lin Chou  Mei Yue  Kunli Luo  Deyi Ren   《International Journal of Coal Geology》2005,61(3-4):241-258

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.  相似文献   

9: Processes of tectonism, magmatism and mineralization: Lessons from Europe     

Derek Blundell  Nicholas Arndt  Peter R. Cobbold  Christoph Heinrich 《Ore Geology Reviews》2005,27(1-4):333

Metallogenic provinces in Europe range in age from the Archaean to the Neogene. Deposit types include porphyry copper and epithermal Cu–Au, volcanic-hosted massive sulphide (VMS), orogenic gold, Fe-oxide–Cu–Au, anorthosite Fe–Ti-oxide and sediment-hosted base-metal deposits. Most of them formed during short-lived magmatic events in a wide range of tectonic settings; many can be related to specific tectonic processes such as subduction, hinge retreat, accretion of island arcs, continental collision, lithosphere delamination or slab tear. In contrast, most sediment-hosted deposits in Europe evolved in extensional, continental settings over significant periods of time. In Europe, as elsewhere, ore formation is an integral part of the geodynamic evolution of the Earth's crust and mantle. Many tectonic settings create conditions conducive to the generation of water-rich magma, but the generation of ore deposits appears to be restricted to locations and short periods of change in temperature and stress, imposed by transitory plate motions. Crustal influence is evident in the strong structural controls on the location and morphology of many ore deposits in Europe. Crustal-scale fault–fracture systems, many involving strike-slip elements, have provided the fabric for major plumbing systems. Rapid uplift, as in metamorphic core complexes, and hydraulic fracturing can generate or focus magmatic–hydrothermal fluid flow that may be active for time spans significantly less than a million years. Once a hydrologically stable flow is established, ore formation is strongly dependent on the steep temperature and pressure gradients experienced by the fluid, particularly within the upper crust. In Europe, significant fracture porosity deep in the crystalline basement (1%) is not only important for magmatic–hydrothermal systems, but allows brines to circulate down through sedimentary basins and then episodically upward, expelled seismically to produce sediment-hosted base-metal deposits and Kupferschiefer copper deposits. Emerging research, stimulated by GEODE, can improve the predicting power of numerical simulations of ore-forming processes and help discover the presence of orebodies beneath barren overburden.  相似文献