The magnetism of a glacial aeolianite sequence from Lanzarote (Canary Islands): coupling between luvic calcisol formation and Saharan dust trapping processes during wet deposition events off northwestern Sahara     

David Williamson  Mike Jackson  Subir K. Banerjee  Nicole Petit-Maire 《Geophysical Journal International》2004,157(3):1090-1104

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影响陶粒页岩烧胀性能因素探讨   总被引：1，自引：0，他引：1  

李卫东  于宝洵  蒋丽洁 《吉林地质》2005,24(4):95-99

烧胀性能是衡量陶粒页岩矿石质量的重要因素,矿石的化学成分及矿物成分决定了陶粒页岩烧胀性能,因此分析矿石的物质组成具有重要意义.  相似文献   

水镁石—水体系氧同位素分馏系数的低温实验研究          下载免费PDF全文

徐宝龙  郑永飞 《地质学报》1997,71(4):340-349

在15—120℃的低温范围内分别应用氮化镁法、氯化镁法和氧化镁法3种化学合成方法,对水镁石-水体系氧同位素分馏系数进行了实验测定。所有合成样品的晶体结构均由XRD测定,其形貌特征则由SEM确定。应用3种不同合成方法得到了一致的水镁石—水体系氧同位素分馏系数,证明同位素平衡分馏已经达到。在实验温度范围内,水镁石—水体系氧同位素分馏系数主要决定于温度,而溶液的酸碱度、化学组分和陈化时间的影响不明显。由实验数据得到的氧同位素分馏曲线方程为:10~3Inα=1.59×10~6/T~2-14.10(r=0.9921)。结合前人对三水铝石—水体系和针铁矿—水体系氧同位素分馏系数的低温实验测定,可以得到氢氧化物中金属M—OH键的~(18)O富集顺序:Al~(3+)-OH>Fe~(3+)-OH>Mg~(2+)-OH。应用化学合成方法实验测定低温条件下水镁石—水体系氧同位素分馏系数,不仅克服了同位素交换反应实验的一些缺陷(如交换速率缓慢、仪器设备复杂昂贵等),而且可以应用不同的化学合成反应机理来检验同位素平衡是否达到,这为研究低温地球化学过程作用提供了有价值的基本参数。  相似文献   

Low-temperature behaviour of haematite: susceptibility and magnetization increase on cycling through the Morin transition   总被引：1，自引：0，他引：1  

Cor B. de Boer  Tom A. T. Mullender  Mark J. Dekkers 《Geophysical Journal International》2001,146(1):201-216

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Low-temperature demagnetization and ice-pressure demagnetization in magnetite and haematite     

Graham John Borradaile 《Geophysical Journal International》1994,116(3):571-584

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Low-temperature, polysulfide reactions of conjugated ene carbonyls: A reaction model for the geologic origin of S-heterocycles     

Robert T. LaLonde  Louis M. Ferrara  Michael P. Hayes 《Organic Geochemistry》1987,11(6)

The theoretical basis for a type of reaction of sulfur-acceptor carbon molecules with donor catenated forms of sulfur is presented. The reactions between conjugated ene carbonyls as sulfur-acceptors and polysulfide as a sulfur donor are described. The scope of this reaction is broadened by demonstrating that the room-temperature action of polysulfide on dienones produces thiophenes. Evidence is given for the structure of 2-benzoyl-5-phenylthiophene, resulting from 1,5-diphenyl-2,4-pentadien-1-one, and 2-acetyl-5-phenylthiophene, resulting from 6-phenyl-3,5-hexadien-2-one. Evidence is also presented for the structure of 2,4-dibenzoyl-3,5-diphenylthiolane, the product resulting from the action of polysulfide on the mixture of benzaldehyde and acetophenone. The same thiolane is shown to result as the minor thiolane component when chalcone reacts with polysulfide in 80% water/20% ethanol. The major component is a known rearranged thiolane identified by its physical properties. The reactiol of chalcone and polysulfide in ethanol at 0 or 25°C results in thiolane formation as evidenced by the isolation of 2,4-dibenzoyl-3,5-diphenylthiolane. However, the reaction of the same two compounds in boiling methanol (65°C) results in a competitive hydrogenation of chalcone giving dihydrochalcone in addition to the formation of thiolane. The demonstration of the low-temperature reaction of polysulfide with conjugated ene carbonyls in the present work adds an additional pathway for possible formation of S-heterocycles in the geosphere.  相似文献   

Very Low-grade Metamorphic Evolution of Pelitic Rocks under High-pressure/Low-temperature Conditions, NW New Caledonia (SW Pacific)   总被引：2，自引：0，他引：2  

POTEL  S.; MAHLMANN  R. FERREIRO; STERN  W. B.; MULLIS  J.; FREY  M. 《Journal of Petrology》2006,47(5):991-1015

The P–T gradient in a Late Eocene low-T high-P metamorphicbelt in northern New Caledonia increases from SW to NE. Metapelitesin the pumpellyite–prehnite and blueschist zones containlawsonite, Mg-carpholite, Fe-stilpnomelane and Fe-glaucophane.Thermodynamic calculations indicate a progression of metamorphicconditions from less than 0·3 GPa and 250°C in akaolinite-bearing rock in the SW, up to 1·5 GPa and 410°Cin a lawsonite–glaucophane-bearing sample in the NE ofthe Diahot terrane. Through a multi-method investigation ofphyllosilicates, organic matter and fluid inclusions, we demonstratethat the evolution of organic matter and illite crystallinitydepends strongly on the evolution of the P–T path withtime. In addition, we show that the illite–muscovite bcell dimension provides a robust estimate of maximum pressurereached in low-temperature domains with polyphase metamorphichistories, despite subsequent high-temperature–low-pressureevents. Fluid inclusion study reveals an isothermal decompressionin the Diahot terrane. KEY WORDS: low-temperature/high-pressure metapelites; illite crystallinity; coal rank; illite–muscovite b cell dimension; New Caledonia  相似文献   

Prograde pressure-temperature path of jadeite-bearing eclogites and associated high-pressure/low-temperature rocks from western Tianshan, northwest China   总被引：2，自引：0，他引：2  

Wei  Lin  Masaki  Enami 《Island Arc》2006,15(4):483-502

Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (X_jd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge.  相似文献   

裂变径迹LA-ICP-MS/FT法原理、实验流程和应用     

武利民  闵康  高剑峰  彭头平 《地质与资源》2021,30(1):75-84

裂变径迹是一种重要的低温热年代学测年方法,目前被广泛应用于岩体冷却年龄测试及各种构造演化热历史等的研究.该方法主要包括传统的外探测器法和近年来新开发的激光-电感耦合等离子质谱法（LA-ICP-MS/FT）.由于传统的外探测器法一直受限于国内反应堆中子热化不充分、辐照周期长以及辐照带来的环境安全等问题,无法有效、快速地获得数据.相反, LA-ICP-MS/FT法的建立和应用不仅避免了因中子热化不充分、热中子分布不均带入的误差而提高了测年精度,而且还极大地提高了测试效率,缩短了解决科学问题的时间.通过对近年来新建立的裂变径迹LA-ICP-MS/FT法的测年基本原理和方法、实验步骤、常用年龄值和裂变径迹退火等的详细介绍,综述了该方法在相关应用方面的研究进展,并与传统的外探测器法进行了详细的对比.最后综述了LA-ICP-MS/FT法在造山带冷却隆升历史、沉积盆地分析、盆-山耦合系统分析、断裂活动、成矿时代和矿体保存等多方面的应用.  相似文献   

基于压力烧结法的小尺寸人工冰样制备工艺研究          下载免费PDF全文

洪嘉琳  马笑聪  陈静  杨腾朝  李波  郝颖  张楠 《探矿工程》2021,48(9):25-33

小尺寸人工冰样主要用于冰的力学特性研究,具有制备程序简单、周期短、成本低、不受季节和地域限制等优点。本文在-3.5~-17.3 ℃温度和10~100 MPa压力条件下开展了雪压力烧结实验研究,采用压力烧结法制备了小尺寸人工冰样,其结果揭示了烧结应力和烧结时间对雪压力烧结过程中的密度演化和冰样最终烧结密度的影响,得出使用压力烧结法来制备冰样时可以选择长时间、低应力、近融点温度或短时间、高应力、低温度的条件,来制备密度为0.917 g/cm³的人工冰样。实验结果验证了压力烧结法制备人工冰样的的可靠性和可重复性,为冰力学特性实验提供了一套切实可行的小尺寸人工冰样制备工艺。  相似文献