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121.
哈达阳地区出露的镁铁-超镁铁质岩石,分布于嫩江—黑河构造带哈达阳构造混杂岩中,岩石类型主要为角闪辉长岩和角闪石岩,呈异地岩块产出。笔者对其进行了LA-ICP-MS锆石U-Pb年代学及全岩地球化学研究,获得角闪石岩和角闪辉长岩中锆石的加权平均206Pb/238U年龄分别为(362.09±0.55)Ma(n=26)和(363.4±1.2)Ma(n=33),属晚泥盆世,为该构造带内迄今报道的最古老的镁铁-超镁铁质岩年龄。岩石地球化学特征研究表明,角闪石岩低Ti(Ti O2=0.65%~0.97%)、低K(K2O=0.04%~0.12%)和高Mg(Mg O=20.42%~24.07%)、高Fe(TFe O=10.25%~11.46%);LREE和HREE分馏较为明显((La/Yb)N=2.35~3.97),Th、Hf、Ce、Nb富集和Ba、Sr、K、Zr亏损,Zr/Nb=10.04~17.12。角闪辉长岩高Ti(Ti O2=1.30%~5.04%)、高Na(Na2O=2.92%~3.14%)、相对高K(K2O=0.31%~0.45%),Mg相对偏低(Mg O=5.94%~8.25%),LREE和HREE分馏也较为明显((La/Yb)N=1.90~3.23),Zr、Nb亏损,明显富集Th、Sr。分析认为,哈达阳镁铁-超镁铁质岩具有火山弧型玄武岩特征,形成于板块消减带之上的岛弧及前弧盆地,大约363 Ma时嫩江—黑河构造带已经进入了板块俯冲阶段,这为贺根山—扎兰屯构造带东延及大兴安岭北段晚古生代的古亚洲洋构造域演化提供了新的年代学证据。  相似文献   
122.
三氯乙烯在模拟有机质-矿质复合体中的吸附行为研究   总被引:1,自引:0,他引:1  
土壤中有机质与无机矿物长期共存,其存在形式发生着变化。本文利用批实验的方法对三氯乙烯的吸附行为进行模拟研究,结果表明,土壤中有机质与无机矿物是以有机质-矿质复合体形式存在的,有机质与无机矿物的相互作用影响复合体的吸附性能,与有机质、无机矿物单体相比,复合体Kd、Koc明显发生变化;并提出了有机质-矿质复合体模型。  相似文献   
123.
124.
杨斌虎  张成立  李雷 《地质通报》2011,30(203):439-447
东秦岭陡岭杂岩中甘沟、三坪沟和封子山等花岗岩体SiO2含量变化大,低碱、高钠,富集LREE和LILE,贫HFSE,亏损Nb、Sr、P和Ti,具准铝质钙碱性I型花岗岩的特征。吐雾山岩体富Si、碱,高Al,贫Ca、Mg,稀土元素总量高,Eu负异常强,富集Rb、Th、U和Pb,明显亏损Sr、P和Ti,显示了A2型花岗岩的地球化学特征。2类花岗岩体Nd-Pb同位素组成基本一致,指示源自相同的物质源区,地球化学特征的差异主要为岩浆分异演化途径不同所致。它们的Pb同位素组成明显不同于北秦岭基底岩系及同时代花岗岩的高放射性成因Pb,与南秦岭和扬子地块基底岩系低放射成因Pb同位素组成类似,表明这次花岗岩浆活动是新元古代中期扬子地块统一陆块形成过程中岩浆活动在秦岭地区的反映,与北秦岭构造带无任何成因联系。  相似文献   
125.
吉林磐石三道岗含铜镍硫化物矿床岩体群年代学意义   总被引:1,自引:0,他引:1  
吉林省中南部产出系列铜镍硫化物矿床,形成于中生代早期的含矿镁铁-超镁铁质岩体在含矿岩体空间上受断裂构造控制,并且在一定范围内集中出现,构成具有成因联系的含矿岩体群。三道岗含矿岩体主要岩石类型为闪长岩、辉长岩、角闪辉石岩-辉石岩、含长角闪橄榄岩等组合,侵位于下二叠统范家屯组浅变质岩系中。辉长岩中LA-ICP-MS锆石原位定年得到(232.75±0.95)Ma(MSWD=0.87)的岩体结晶年龄,同时,角闪石单矿物40Ar-39Ar法测年得到(121.45±2.52)Ma的蚀变年龄,暗示三道岗含矿岩体群与红旗岭一样形成于印支中亚造山晚期,燕山期岩浆活动产生的热液叠加蚀变对矿床形成产生重要影响。  相似文献   
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127.
Industrial linkages of two medium-sized Brazilian urban manufacturing systems are analyzed. Clusters are similar to those of the national economy while complexes are uneven for the two cities which implies that neither the size nor the diversity of the local industry influences the evolution of complexes. Development depends on time and on the volume (threshold) of manufacturing activity. If manufacturing complexes are carefully implemented and maintained, medium-sized centers might become viable manufacturing growth center communities.  相似文献   
128.
The northern margin of the North China Craton (NCC) was an active convergent margin during Palaeozoic and preserves important imprints of magmatic and metasomatic processes associated with oceanic plate subduction. Here, we investigate the mafic–ultramafic rocks in the Xiahabaqin–Sandaogou complexes from the northern NCC including pyroxenite, hornblendites, hornblende gabbro, and their rodingitized counterparts within a serpentinite domain. We present petrological, zircon U–Pb geochronological, and geochemical data to constrain the nature and timing of the magmatic and metasomatic processes in the subduction zone mantle wedge. The rock suites investigated in this study are characterized by low contents of SiO2, Na2O, and K2O, with high CaO, FeO, Fe2O3, and MgO. The rodingitized rocks show markedly high CaO and lower MgO compared to their ultramafic protolith, suggesting extensive post-magmatic infiltration of Ca-rich, Si-poor fluids derived by serpentinization of mantle peridotite. The enrichment of large ion lithophile and light rare earth elements such as Ba, Sr, K, La, and Ce with relative depletion of high field strength elements like Nb, Ta, Zr, and Hf in the ultramafic rocks collectively suggest metasomatism of a fore-arc mantle wedge by fluids released through dehydration of subducted oceanic slab and subduction-derived sediments. Dehydration and decarbonation leading to metasomatic fluid influx and serpentinization of mantle wedge peridotite account for the enriched geochemical signatures for the rodingitized rocks. The zircon grains in these rocks show textures indicating magmatic crystallization followed by fluid-controlled dissolution–precipitation. Magmatic zircons from altered pyroxenite, hornblendite, and rodingitized pyroxenite in Xiahabaqin yield protolith crystallization ages peaks at 396 Ma and 392 Ma and metasomatic grains show ages of 386 Ma, 378 Ma, and 348 Ma. The zircons from hornblendite and basaltic trachyandesite indicate protolith emplacement during 402–388 Ma. Metasomatic zircon grains from rodingitized hornblende gabbro in Sandaogou complex show a wide range of ages as 412 Ma, 398 Ma, 383 Ma, and 380 Ma. The common magmatic zircon ages peaks at 398–388 Ma in most of the rocks suggest a similar time for magma crystallization in the Xiahabaqin and Baiqi during Middle Devonian. Subsequently, repeated pulses fluids and melts resulted in metasomatic reactions in mantle wedge until early Permian. The Lu–Hf analysis of the zircon grains from these rocks display markedly negative εHf(t) values ranging from ?22.4 to ?7.7, suggesting magma derivation from an enriched, hydrated lithospheric mantle through fluid–rock interaction and mantle wedge metasomatism. Rodingitization processes are associated with exhumation of ultramafic mantle wedge rocks within a serpentinized subduction channel close to the subducted slab in response to slab roll back in a long-lasting subduction regime. This study offers insights into magmatic and metasomatic processes of ultramafic rocks in the fore-arc mantle wedge which were exhumed and accreted to an active continental margin during the southward subduction of the Palaeo-Asian oceanic lithosphere beneath the NCC.  相似文献   
129.
达拉库岸镁铁-超镁铁岩位于东昆仑造山带南带之喀拉米兰晚古生代沟弧系,由二辉橄榄岩、单辉橄榄岩、橄榄辉石岩、单辉岩、含长辉石岩和辉长岩组成。单辉橄榄岩和橄榄辉石岩中橄榄石均为贵橄榄石(Fo=84.55~89.08),其MnO含量为0.13%~0.29%,NiO含量为0.09%~0.28%;单斜辉石为透辉石和普通辉石,其MgO含量为15.12%~16.98%,Fe O含量为3.84%~5.34%,CaO含量为21.10%~22.95%;与蛇绿岩套中的同类岩石的橄榄石和单斜辉石成分存在较大差异,与夏日哈木和金川镁铁-超镁铁岩中同类岩石的矿物成分类似,表明达拉库岸岩体不是蛇绿岩套的组成部分,而是陆壳中的侵入体。单斜辉石成分表明其母岩浆为拉斑玄武质岩浆,可能形成于与俯冲有关的大陆边缘裂谷环境。达拉库岸岩体具有形成岩浆型铜镍硫化物矿床的条件。  相似文献   
130.
Although there are many mafic-ultramafic intrusions in the western and central regions of Mongolia, Central Asian Orogenic Belt (CAOB), no economic-grade Ni-Cu deposits have yet been discovered. To understand the economic Ni-Cu deposit potential of the intrusions in central Mongolia, the parental magma affinity and sulfide saturation of the Oortsog, Dulaan, and Nomgon Ni-Cu mineralized mafic-ultramafic intrusions are studied. These three intrusions are predominantly gabbroic in composition, while the Oortsog and Dulaan intrusions also contain small proportions of peridotites. The parental magmas of the Oortsog and Dulaan intrusions are tholeiitic, as indicated by their Cr-spinel and clinopyroxene compositions, whereas the parental magma of the Nomgon intrusions is likely calc-alkaline. The compositions of Cr-spinel and clinopyroxene, combined with the presence of significant Nb-Ta depletions, indicate that these rocks were most likely derived from modified mantle sources. Both the Oortsog and Nomgon intrusions form two clusters in terms of their olivine composition, suggesting that multiple magma surges were involved during their emplacement. The relatively low Fo values and Ni contents in olivine from the three intrusions compared to those from Ni-Cu deposits in NW China, as well as those in the Voisey’s Bay deposit in Canada, indicate that the three intrusions were crystallized from relatively evolved magmas. The Cu/Zr ratios of rocks of the Oortsog, Dulaan, and Nomgon intrusions are higher than 1, suggesting that these rocks contain cumulus sulfide. This, coupled with the presence of rounded sulfide inclusions in olivine of the Oortsog and Dulaan intrusions, suggests that sulfide saturation occurred before or during olivine crystallization. The distribution patterns of platinum group elements (PGEs) of the Dulaan and Oortsog intrusions record slight Rh, Pt, and Pd (PPGE) enrichment relative to Os, Ir, and Rh (IPGE). Furthermore, the Ni/Cu ratios of sulfide-bearing rocks from the Oortsog intrusion vary from 1.8 to 3.8, which are consistent with those of the Ni-Cu sulfide deposits in NW China. In contrast, the Ni/Cu ratios of sulfide-bearing rocks from the Nomgon intrusion are extremely low (0.03 to 0.07). This, together with the significant enrichment in PPGE relative to IPGE, suggests that these sulfides of the Nomgon intrusion were segregated from a magma that was extremely enriched in Cu and PPGE but depleted in Ni and IPGE. The characteristics of the chalcophile elements in these intrusions are attributed to the fact that the derivation of the Nomgon magma was significantly different from that of the Dulaan and Oortsog parental magmas. Overall, although the parental magmas of the intrusions in central Mongolia are more evolved than those in NW China, they are comparable in terms of the sizes of their intrusions, constituent minerals, and mineral chemistry. These similarities suggest that the intrusions in central Mongolia have economic Ni-Cu sulfide potential. Furthermore, intrusions similar to the Nomgon intrusion may feature PGE mineralization potential.  相似文献   
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