安徽金寨银水寺铅锌矿床流体包裹体和同位素地球化学特征     

吴皓然  谢玉玲  钟日晨  王莹  安卫军 《大地构造与成矿学》2019,43(5):967-990

银水寺铅锌矿床位于大别造山带北缘,是该区最大的矽卡岩型矿床。矿体主要发育在中元古界庐镇关岩群仙人冲组大理岩与郑堂子组千枚岩之间的层间破碎带以及正长花岗斑岩与大理岩的接触带中。矿床先后经历了四个成矿阶段,矽卡岩阶段(Ⅰ)、石英.白钨矿阶段(Ⅱ)、石英.硫化物阶段(Ⅲ)、碳酸盐阶段(Ⅳ)。矽卡岩阶段(Ⅰ)主要发育绿帘石、阳起石、石英、绿泥石、磁铁矿及少量金属硫化物等;石英.白钨矿阶段(Ⅱ)主要发育石英、方解石、萤石及少量白钨矿和金属硫化物;石英.硫化物阶段(Ⅲ)广泛发育闪锌矿、方铅矿、黄铜矿等金属硫化物及石英、方解石、萤石、绿泥石等;碳酸盐阶段(Ⅳ)主要发育方解石、石英及少量黄铁矿。矿床中发育三种类型流体包裹体,包括富CO2水溶液包裹体(AC类)、气液两相水溶液包裹体(L类)和含子晶多相包裹体(S型)。根据流体包裹体岩相学、显微测温、激光拉曼研究结果,矽卡岩阶段主要有富CO2包裹体和气液两相水溶液包裹体,均一温度为314~400℃、盐度变化范围较大(1.1%~19.3%NaCleqv);石英.白钨矿阶段发育气液两相水溶液包裹体、含子晶多相包裹体和富CO2包裹体,后两者均一温度相近(263~349℃)、盐度差异较大(32.8%~41%NaCleqv和0.8%~6.1%NaCleqv),表明流体发生了沸腾作用;石英.硫化物阶段主要发育气液两相水溶液包裹体,均一温度为230~332℃,盐度为0.2%~8.9%NaCleqv;碳酸盐阶段只发育气液两相水溶液包裹体,显示低温(162~245℃)、低盐度(0.2%~5.6%NaCleqv)的特征。矿床不同成矿阶段石英、绿帘石中流体包裹体中水H-O同位素研究结果表明,δ18Ofluid值从早到晚逐渐减小,其中矽卡岩阶段为–1.3‰~4.7‰、石英.硫化物阶段为–5.1‰~–3.1‰,表明银水寺矿床早期成矿流体主要为岩浆来源,并在成矿过程中不断有大气降水的加入。石英流体包裹体中CO2的C同位素测试结果表明,矽卡岩阶段δ13CV-PDB值为–9.2‰,石英.硫化物阶段为–25.8‰~–15.4‰,表明早期成矿流体中碳质主要来自岩浆,石英-硫化物阶段有大量有机碳加入,其可能与流体和富含有机质的地层反应有关。矿石中主要金属硫化物的δ34S值(1.7‰~4.4‰)显示了深源硫的特征。Pb同位素变化范围集中(206Pb/204Pb=16.55~16.705,207Pb/204Pb=15.369~15.459,208Pb/204Pb=37.463~37.767),显示壳幔混源的特点。随着成矿作用的进行,岩浆流体与碳酸盐围岩地层发生水岩交代反应形成矽卡岩,该过程造成了成矿矽卡岩阶段磁铁矿和少量闪锌矿的沉淀;断裂活动造成热液体系压力下降,流体发生沸腾,CO2、HF进入气相并逃逸促使矿床中钨的沉淀;同时大气降水沿裂隙灌入,混合作用导致流体的温度、盐度降低,Cl–浓度下降,造成矿床中铅锌的大面积沉淀。  相似文献   

俄罗斯塔尔纳赫岩浆铜镍硫化物矿床中流体参与成矿的矿物学证据     

蒋俊毅  苏尚国  王菁姣 《地学前缘》2019,26(6):228-243

岩浆铜镍硫化物矿床研究中“硫化物矿浆”组成及上侵聚集机制一直存在争议。在新近提出的“岩浆通道成矿系统”的思路下,文章研究了来自俄罗斯诺里尔斯克地区塔尔纳赫铜镍硫化物矿床中的赋矿橄榄苏长辉长岩,发现其主要造岩矿物存在两种类型,在微量元素分配上出现了明显的差异。文章重点报告了其中斜长石的特点。以微量元素的分配模式为依据,所有斜长石可以分为两类：Ⅰ型斜长石强烈富集大离子亲石元素和轻稀土元素,强烈亏损高场强元素,成分为钠长石倍长石,与硫化物共存,指示在含矿硫化物珠滴中应含有大量流体;Ⅱ型斜长石富集轻稀土元素,强烈亏损高场强元素,成分为中长石倍长石,产于岩体中遭受交代改造较弱的区域,指示它们由熔体结晶形成。据此我们认为“硫化物矿浆”在上侵过程中包含大量流体,应该为“熔体流体”。文章为流体在硫化物矿浆富集和运移过程中起着重要作用的论点提供了新的证据。  相似文献   

东昆仑古特提斯后碰撞阶段伸展作用:来自晚三叠世岩浆岩的证据     

陈国超  裴先治  李瑞保  李佐臣  裴磊  刘成军  陈有炘  王盟  高峰  李小兵 《地学前缘》2019,26(4):191-208

通过对东昆仑造山带晚三叠世岩浆岩的岩石类型、形成时代、岩石地球化学和同位素地球化学资料综合分析,对岩浆岩的岩石组合、分布特征和岩石成因进行研究,探讨东昆仑造山带晚三叠世构造演化的地球动力学背景。东昆仑造山带晚三叠世是古特提斯演化过程中重要的构造转换期,岩浆岩岩石类型多样,主要包括辉长岩、花岗闪长岩、二长花岗岩和正长花岗岩,并且广泛出露具埃达克质特征的岩浆岩和A型花岗岩。晚三叠世岩浆岩的出露规模与俯冲阶段相比,规模较小,一般以小岩体、岩株和岩脉侵入于早期岩体和地层中。东昆仑晚三叠世岩浆岩主体为准铝-弱过铝质高钾钙碱性-钾玄岩系列,轻重稀土元素具有一定分异,富集大离子亲石元素,亏损高场强元素,岩石类型不同时分异程度、富集和亏损程度有一定差异。大部分晚三叠世花岗质岩浆岩的同位素特征与晚二叠世-三叠纪镁铁质岩浆岩近似,部分具有更高的εNd(t)和εHf(t)值。镁铁质岩浆岩、普通花岗岩、埃达克质岩浆岩在东昆仑各个构造带皆有分布,A型花岗岩主要分布在祁漫塔格构造带(东昆北)的阿牙克库木湖-香日德断裂附近。东昆仑晚三叠世镁铁质岩浆岩具有弧岩浆岩特征,为俯冲流体交代的地幔楔部分熔融产物。普通花岗岩和埃达克质岩浆岩多为新生下地壳部分熔融产物,少量埃达克质岩浆岩由于与地幔的交代作用,具有幔源特征。A型花岗岩为残留下地壳部分熔融的产物。部分普通花岗岩、埃达克质岩浆岩和A型花岗岩由于岩浆混合作用,具幔源特征。构造环境研究表明,东昆仑在晚三叠世进入古特提斯演化的后碰撞阶段。巴颜喀拉地块同东昆仑地块的持续碰撞导致地壳加厚,密度增大,使岩石圈重力不稳定发生拆沉作用,引发岩石圈地幔减压熔融,产生大量的镁铁质岩浆岩;镁铁质岩浆底侵不同类型地壳熔融及拆沉地壳部分熔融而形成的岩浆交代地幔,以及岩浆混合和岩浆后期演化,形成了东昆仑造山带晚三叠世丰富多样的岩浆岩。  相似文献   

初论雪峰山地区基性-超基性岩镍钴铜金矿找矿方向     

石少华  邹源  岑敏  朱继华  罗小亚 《矿物岩石地球化学通报》2019,(1):80-89

近年来,雪峰山地区的基性-超基性岩矿床找矿工作取得了一定的进展。为了及时总结成矿规律,指导进一步的找矿工作,本文在大量野外调研的基础上,系统总结了该地区基性-超基性岩岩体的地质特征、已有找矿进展的长界镍矿和字溪金矿地质特征及已发现的镍钴铜金等矿化特征,并与国内外同类型矿床的成矿特征进行了比较,最后提出了如下认识:雪峰山地区具备找寻基性-超基性岩矿床潜力,目标矿种主要为镍、钴、铜及金矿,主要矿床类型为岩浆硫化物型镍钴铜矿及蚀变热液型金矿。前者目标地质体以通道-洪江-中方-古丈一带新元古代基性-超基性岩群/带最为有利,后者则以隘口岩群及艾头坪-大洪山岩群的大洪山段最为有利。  相似文献   

基于镁铁-超镁铁岩中单斜辉石主量元素含量的决策树集成算法对比     

孙建鹍  杜雪亮  章宝月  王龙  金维浚  张旗  罗熊  朱月琴 《地质通报》2019,38(12):1981-1991

依靠岩浆构造环境的地球化学成分认识岩浆形成过程是岩石地球化学中的重要应用。当前利用岩石地球化学成分判别构造环境的工作还不够深入。用4种基于决策树的机器学习方法对来自全球新生代洋岛玄武岩(OIB)、岛弧玄武岩(IAB)及大洋中脊玄武岩(MORB)等镁铁-超镁铁岩中单斜辉石的13种主量元素构成数据集进行了岩浆构造环境判别和主要特征排序。通过对比4种基于决策树的机器学习方法,验证了树类算法对于地球化学成分识别问题的有效性,并总结出4种方法在处理岩浆构造环境判别问题时的优劣:决策树算法判别过程更易于理解,但是其准确率欠佳;boosting算法中的AdaBoost和GBDT对于岩浆构造环境的鉴别准确度较高,但构造过程复杂;bagging集成算法随机森林在权衡性能和模型可理解性时不失为一个良好的选择。此外,还通过4种算法的特征重要性排序得出Cr_2O_3,TFeO,TiO_2,FeO和Al_2O_3是进行岩浆构造环境判别的重要成分。  相似文献   

Mineral chemistry,crystallization conditions and magma mixing‐mingling at Orduzu volcano (Malatya), Eastern Anatolia,Turkey     

A. nal 《Geological Journal》2008,43(1):95-116

The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

ECONOMIC GEOLOGY     

《Abstract of Chinese Geological Literature》2014,(4)

正20142114Lin Quansheng(China University of Geosciences,Bejing 100083,China)On the Geologic Characteristics and Economic Significance of the Cambrian Lintian Group in Fujian Province(Geology of Fujian,ISSN1001-3970,CN35-1080/P,32(4),2013,p.264-273,2illus.,2tables,6refs.)  相似文献   

GEOCHRONOMETRY & ISOTOPE GEOLOGY     

《Abstract of Chinese Geological Literature》2014,(3)

正20141655 Gao Linzhi(Institute of Geology,CAGS,Beijing 100037,China);Ding Xiaozhong The Revision of the Chentangwu Formation in Neoproterozoic Stratigraphic Column:Constraints on Zircon U-Pb Dating of Tuff from the Mengshan Section in Pujiang County,Zhejiang Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.988-995,5 illus.,1 plate,2 tables,24 refs.)  相似文献   

Impact of fractional probability distributions on statistics of hydraulic conductivity,dynamics of groundwater flow and solute transport at a low-permeability site     

Chengpeng Lu  Wei Qin  Ching-Sheng Huang  Yong Zhang  Tema Koketso Ealotswe 《水文研究》2020,34(21):4112-4127

The fractional Brownian motion (fBm) and fractional Lévy motion (fLm) can easily describe the geometry and the statistical structure of hydraulic conductivity (K) for real-world. However, the fBm and fLm models have not been systematically evaluated when building the K field for a low-permeability site. In this study, both the fBm and fLm are used to simulate the low-K field at NingCheGu (NCG), Tianjin, China. Groundwater flow and solute transport are then computed using MODFLOW and MT3DMS, respectively, and the influence of the fBm/fLm models for K on groundwater flow and solute transport is discussed. Results show that the fLm fits better the statistics of the low-K medium than fBm, and the random logarithmic K (LnK) field generated by fLm is more stable because the resultant LnK field captures more of the measured properties at the field site than that generated by fBm. In contrast, the LnK generated by fBm is more likely to form both high-K channels and low-K barriers. The fBm therefore predicts more extreme behaviours in flow and transport, including the preferential flow, low-concentration blocks and solute retention. The overall groundwater renewal period and solute travel time for the fLm simulation are slightly shorter than those for fBm. The impacts of the fLm and fBm models on the statistics of the resultant LnK fields and the dynamics of groundwater flow and solute transport revealed by this study shed light on the selection and evaluation of the fractional probability distribution models in capturing the K fields for low-K media.  相似文献   

碳酸氢钠冷却结晶动力学          下载免费PDF全文

蒋士姣 《盐湖研究》2021,29(2):50-57

碳酸氢钠(NaHCO_3)俗称小苏打,其产品质量取决于颗粒的大小,晶体的形貌和样品的纯度等诸多因素。本论文基于连续稳态MSMPR结晶器原理,研究了不同停留时间下,碳酸氢钠从碳酸钠溶液中冷却结晶过程动力学。利用实验数据建立了NaHCO_3的结晶动力学操作模型。实验和计算结果表明,随停留时间的增加,NaHCO_3过饱和度降低,晶体生长速率和成核速率均减小,相应的平均粒径增加,细颗粒含量减小;适当延长停留时间是制取高品质小苏打产品的有效途径。冷却结晶过程可有效增加小苏打产量,小苏打收率维持在55%左右。此外,一定Na_2CO_3存在下冷却结晶碳酸氢钠晶体形态由细长的针状变为规整的片状。  相似文献