锰的催化动力学分析法概况   总被引：8，自引：0，他引：8  

张振辉 《岩矿测试》1991,10(1):56-59

本文就催化动力学测定锰的概况作一介绍,引用直接有关的原始文献60篇。  相似文献   

浙江杭嘉湖平原区土壤中营养元素丰缺状况的评价   总被引：5，自引：2，他引：5  

朱立新  周国华  任天祥  张连生  王徽  顾金秋  杜雄进  王成  蒋永平  周子泉 《物探与化探》1994,18(4):251-262

根据杭嘉湖平原区区域地球化学调查的结果,对本区土壤中农作物营养元素含量及有效量特征进行了评价研究。研究结果表明,本区土壤中营养元素除Mo、S含量表现缺乏外,其它元素为足量和丰富水平。不同土壤中营养元素有效量水平存在明显差异。在区域分布规律上,营养元素的含量及有效量随成土母质、成土过程和人类耕作等因素的不同而显示其差异特征。评价研究结果为本区农业生产中的合理区划、科学施肥、合理种植、土壤改良等提供了重要的地球化学依据。  相似文献   

大洋锰结核中锰矿物的地球化学性质及其成因     

单连芳 《地球化学》1994,23(1):91-98

本文从地球化学角度研究并探讨大洋锰结核中锰矿物化学组分间的相关性，用三组分图，结合显微镜下观察，初步确定不同成因锰矿物的Ｍｎ／Ｆｅ值：原生δ－ＭｎＯ２，２－２．５；次生致密带的次生δ－ＭｎＯ２，１－２；重结晶形成的钡镁锰矿和钠水锰矿，＞５；由于结核中的物质分配和后生作用形成富Ｎｉ，Ｃｕ非晶质铁锰氧化物的Ｍｎ／Ｆｅ值亦大于５。  相似文献   

Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa     

M. Schmidt  R. Borchers  P. Fabian  G. Flentje  W. A. Matthews  A. Szabo  S. Lal 《Journal of Atmospheric Chemistry》1984,2(2):133-143

During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH₄, CO and N₂O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean.  相似文献   

诸广花岗岩体放射性水异常的某些特征     

吴敬炳 《华东地质学院学报》1986,(2)

本文以寻找铀矿为目的,在该岩体140Km~2面积上进行水化学普查,发现水异常370个,其特征为:若异常多且成片出现,则预示着有单个矿体规模不大的矿体群存在;条带状展布的水异常预示着存在方向相同的矿化带;阻水阻气构造带近旁之异常预示水源上方存在矿化;水温偏高之水异常与矿化关系密切;与矿化有关的多为铀—氡混合异常;大构造处之水异常并不表示此构造存在矿化,面往往是在其附近次一级构造中成矿.  相似文献   

滇西实验场两次中强地震前后尾波衰减的区域特征分析   总被引：9，自引：0，他引：9  

秦嘉政  刘祖荫 《中国地震》1995,11(3):212-221

本文在地方震尾波散理论模式的基础上，研究了１９９２年１２月发生在滇西地震预报实验场永胜期纳地区的两次Ｍｓ５．４，５．１地震前后的序列地震尾波振幅衰减率β和尾波Ｑ＾－１值随时间和空间变化的衰减特征。结果表明，尾波衰减率在空间分布上表现出明显的小区域范围的非均匀性，在主震震中附近的近场区内，主震期间的β值是０．００７６ｓ＾－１，相应的Ｑｃ＾－１值是０．００５６；余震期间的β值是０．０２０９ｓ＾－１，相  相似文献   

鲜水河地区现今形变及地球动力学特征     

杜方  吴江 《四川地震》1995,(3):22-31

本文根据非线性理论的新方法，稳健估计技术和多核函数等，对鲜水河地区垂直和水平形变监测资料进行了分析处理，获得了鲜水河地区的现今地壳动态信息，从而分析获得鲜水河断裂的现今活动与地震的关系，鲜水河断裂的现今活动模型及其应力状态。  相似文献   

Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer   总被引：2，自引：0，他引：2  

Paul Frenzen  Christoph A. Vogel 《Boundary-Layer Meteorology》2001,99(2):173-206

The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the _m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most _m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised _m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear _m relation for the stable case; (3) data that define collinear _m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of _m and z/L.  相似文献   

四川盆地东北部三叠系飞仙关组碳酸盐岩成岩作用和白云岩成因的研究现状和存在问题   总被引：10，自引：0，他引：10  

黄思静  Hairuo QING  胡作维  王春梅  郜晓勇  邹明亮  王庆东 《地球科学进展》2007,22(5):495-503

四川盆地东北部三叠系飞仙关组是我国重要的天然气储集层，优质储层形成机制直接与碳酸盐岩成岩作用、尤其是白云岩化作用相关，但飞仙关组碳酸盐岩在锰含量、锶含量、阴极发光性等特征上反映其成岩过程与经典成岩理论相悖；碳酸盐岩的锶同位素组成和锰、锶含量的关系也表明与大气水有关的成岩过程和作为重要储集岩的结晶白云岩的形成机制无关，传统的白云岩化机制难以解释结晶白云岩的成因。具有海源色彩的高锶、低锰成岩流体在很大程度上控制了飞仙关组碳酸盐的成岩作用，其来源与成因值得进一步关注，控制其运移、封存和发生水—岩反应的时空机制有待回答。整个海相三叠纪时间段盆地尺度碳酸盐岩和蒸发岩的沉积地球化学研究、尤其是不同结构组分碳酸盐的锶同位素组成、锶和锰含量研究（包括碳酸盐岩中不同结构组分的阴极发光性研究），可为四川盆地东北部飞仙关组碳酸盐岩成岩作用（尤其是白云岩化作用和作为重要储集岩的结晶白云岩的成因研究），天青石矿床成因研究和四川盆地三叠系深层富钾、锶、硼、溴卤水的成因研究提供重要的线索。  相似文献   

个旧锰结核矿床地质地球化学与成因初步研究     

张宝贵  张忠  胡静  符亚洲  刘世荣 《矿物学报》2007,27(3):366-371

个旧锰结核矿床产在锡石-多金属硫化物矿田顶部的第四系砂锡矿之中。从矿床地质产状、化学组成、微量元素、稀土元素、矿物组合等方面进行了讨论，认为个旧锰结核属于异地海相成因，后经搬运沉积在第四系砂锡矿之中；与中太平洋海山CAD19锰结核的物质组成和微量元素进行对比，表明个旧和CAD19锰结核有相类似的稀土模式，相对富集轻稀土，并出现明显的Eu负异常和Ce的正异常。  相似文献