黄海海域陆相中生界油气远景   总被引：8，自引：1，他引：8  

李刚  陈建文  肖国林  温珍河  戴春山  龚建明  闫桂京 《海洋地质前沿》2003,19(8):7-11

黄海海域油气勘探已40余载，尚未实现油气突破，其找油前景引起石油地质学家的极大关注。根据前人的认识和最新研究成果，结合邻区油气地化资料，探讨了黄海海域中生界地层生、储、盖特征，特别是白垩系，它分布广，厚度大，烃源岩达到较好生油岩标准，并且生、储、盖组合理想，中生界是该区下部油气勘探首选目标。  相似文献   

Sources and hydrothermal alteration of organic matter in Quaternary sediments: A synthesis of studies from the Central Gulf of California     

Bernd R. T. Simoneit 《Marine and Petroleum Geology》1986,3(4)

Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone.  相似文献   

夏、冬两季长江口及邻近海域悬浮物的分布特征及其沉积量   总被引：11，自引：0，他引：11  

庞重光  王凡  白学志  张明翰 《海洋科学》2003,27(12):31-35

利用2001年7～8月 ,2002年1月两个航次的悬浮物浓度资料 ,并参考其它水文参数 ,简要分析长江口及邻近海域悬浮物的分布特征 :无论夏季还是冬季 ,长江入海悬浮物总是向东南方输运 ;冬季由于再悬浮作用显著 ,悬浮物浓度明显高于夏季 ,且南北分布范围也明显增大 ,垂向分布均匀。同时采用数值模拟的海流流速值和观测的悬浮物浓度值计算悬浮物的断面通量 ,并最终得计算区悬浮物夏、冬两季的沉积量 ,夏、冬季长江口及邻近海域悬浮物的沉积量分别为0.79×108t,1.44×108t。  相似文献   

Quantum yield for the photochemical production of dissolved inorganic carbon in seawater   总被引：2，自引：0，他引：2  

Sophia C. Johannessen  William L. Miller 《Marine Chemistry》2001,76(4):108

The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e^{−(6.66+0.0285(λ−290))}; coastal φ(λ)=e^{−(6.36+0.0140(λ−290))}; and open ocean φ(λ)=e^{−(5.53+0.00914(λ−290))}. Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction.  相似文献   

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean     

Christopher L. Dupont  James. W. Moffett  Robert R. Bidigare  Beth A. Ahner 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1961-1974

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.  相似文献   

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas   总被引：3，自引：0，他引：3  

Seunghee Han  Gary A. Gill  Ronald D. Lehman  Key-Young Choe 《Marine Chemistry》2006,98(2-4):156-166

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献   

A dynamic response analysis of tension leg platforms including hydrodynamic interaction in regular waves     

Chuel-Hyun Kim  Chang-Ho Lee  Ja-Sam Goo   《Ocean Engineering》2007,34(11-12):1680-1689

A numerical procedure is described for predicting the motion and structural responses of tension leg platforms (TLPs) in waves. The developed numerical approach, in a TLP is assumed to be flexible instead of rigid, is based on a combination of the three dimensional source distribution method and the finite-element method. The hydrodynamic interactions among TLP members, such as columns and pontoons, are included in the motion and structural response analysis. Numerical results are compared with the experimental and numerical ones. The results of comparison confirmed the validity of the proposed approach.  相似文献   

廉州湾南部海域泥沙来源及运移趋势分析     

谷东起  吴桑云 《海洋科学进展》2001,19(1):25-31

重矿物组合、含量变化和特征矿物的分布及变化规律是沿海泥沙来源和运移趋势判断的重要手段之一。通过对廉州湾南部海域海底表层沉积物的重矿物分析 ,发现该区重矿物分布以北海地角为界 ,其百分含量和特征矿物南北有别 ,可能分别代表不同的物质来源区。其中廉州湾北部南流江流域来沙是该区主要物源 ,运移趋势为自 NE向 SW;地角西南岸段、岭南侧海岸侵蚀及银滩来沙也为该区提供了部分物源 ,运移趋势为绕过冠头岭沿海岸向 N方向运移。由于缺乏北海陆域陆相地层重矿物含量等相关资料 ,暂未做物质来源区的具体判断  相似文献   

南极中山站大气气溶胶的化学组成及其来源的判别   总被引：1，自引：1，他引：1  

黄自强  暨卫东  杨绪林  黄荣坦  汤荣坤  于涛  张功勋 《台湾海峡》2003,22(3):334-346

从1998年3月7日至1999年11月23日历时21个月，在南极中山站连续采集89个海洋气溶胶样品，本文提供全部样品的13种化学元素Cu、Pb、Zn、Cd、Fe、Al、Mn、Cr、V、K、Na、Ca、Mg含量的实测值．研究表明中山站气溶胶化学成份的含量具有季节性变化的特征．通过相关分析、因子分析、富集因子等方法判别不同时间段中山站气溶胶化学成份的来源。  相似文献   

Eddy Diffusion Coefficients of Suspended Particulate Matter: Effects of Wind Energy Transfer and Stratification     

Lars Chresten Lund-Hansen  Morten Pejrup  Jens Valeur  Anders Jensen 《Estuarine, Coastal and Shelf Science》1994,38(6)

Gross sedimentation rates (GSR) have been measured using sediment traps placed at nine different levels above the bed (0·3, 0·5, 0·8, 1·0, 2·0, 4·0, 6·0, 8·0 and 10·0 m). The sediment traps were deployed for 1·25 years and recovered 28 times during the study period. Low average GSR values of 5·5 g m^-2 day^-1 were obtained at 10·0 m, and high average GSR values of 114·8 g m^-2 day^-1 were obtained at 0·3 m. An expression for the eddy diffusion coefficient of suspended particulate matter (K_s), based on the measured GSR is given. The expression has been used for modelling of K_s at the different trap levels above the bed. High values (≈42 cm² s^-1) of K_s were obtained at the upper traps, whereas low values (≈2 cm² s^-1) were obtained near the bed. Comparison between level of turbulent energy in terms of shear stress at the boundaries of the water column, i.e. from the wind and the bed flow, showed that wind energy exceeded that of the bed flow by a factor 16. At 5·0 m K_s was positively correlated (r=0·66) to the eddy diffusion coefficient of momentum (K_m) derived from the wind energy transfer to the water, giving an average β of 0·5 for K_s =βK_m. The density difference between surface and bottom waters has been designated a parameter of stratification, and is discussed in relation to variations of K_s and K_m .  相似文献