锡在流体和花岗质硅酸盐熔体间分配行为的实验研究     

胡晓燕  尚林波  毕献武  胡瑞忠  樊文苓  陈佑纬 《矿物岩石地球化学通报》2007,26(4):359-365

锡的成矿与花岗岩有着密切关系。为深入了解不同的岩浆组成及流体变化对锡分配行为的影响,以不同化学组成的凝胶和不同的流体分别作为初始固液相,进行了锡在流体与花岗质熔体间的分配行为实验研究。实验温度为850℃,压力为100 MPa。结果显示,当液相为0.1 mol/L的HCl时,熔体组成的变化对锡的分配行为有着明显的影响,锡在流熔体间的分配系数DSn随熔体中碱质(Na2O K2O)含量、钠钾(Na/K)和碱铝(AlK/Al)摩尔比的增加而减小;在固相(富钾过碱质熔体)不变的前提下,DSn随流体相中HCl浓度的增加而增大,而流体相中HF及K 、Na 浓度的改变对DSn影响不大;流体Cl-浓度和酸度升高有利于锡分配进入流体相。  相似文献   

Research of the Conductive Structure of Crust and the Upper Mantle beneath the South-Central Tibetan Plateau     

叶高峰金胜  魏文博Martyn Unsworth 《中国地质大学学报(英文版)》2007,18(4):334-343

With the super-wide band magnetotelluric sounding data of the Jilong (吉隆)-Cuoqin (措勤) profile (named line 800) which was completed in 2001 and the Dingri (定日)-Cuomai (措迈) profile (named line 900) which was completed in 2004,we obtained the strike direction of each MT station by strike analysis,then traced profiles that were perpendicular to the main strike direction,and finally obtained the resistivity model of each profile by nonlinear conjugate gradients (NLCG) inversion. With these two models,we described the resistivity structure features of the crust and the upper mantle of the center-southern Tibetan plateau and its relationship with Yalung Tsangpo suture: the upper crust of the research area is a resistive layer with resistivity value range of 200-3 000 ?·m. The depth of its bottom surface is about 15-20 km generally,but the bottom surface of resistive layer is deeper in the middle of these two profiles. At line 900,it is about 30 km deep,and even at line 800,it is about 38 km deep. There is a gradient belt of resistivity at the depth of 15-45 km,and a conductive layer is beneath it with resistivity even less than 5 ?·m. This conductive layer is composed of individual conductive bodies,and at the south of the Yalung Tsangpo suture,the conductive bodies are smaller with thickness about 10 km and lean to the north slightly. However,at the north of the Yalung Tsangpo suture,the conductive bodies are larger with thickness about 30 km and also lean to the north slightly. Relatively,the conductive bodies of line 900 are thinner than those of line 800,and the depth of the bottom surface of line 900 is also shallower. At last,after analyzing the effect factors to the resistivity of rocks,it was concluded that the very conductive layer was caused by partial melt or connective water in rocks. It suggests that the middle and lower crust of the center-southern Tibetan plateau is very thick,hot,flabby,and waxy.  相似文献   

Metasomatism and sulfide mobility in lithospheric mantle beneath eastern Australia: Implications for mantle Re–Os chronology     

William Powell  Suzanne O''Reilly 《Lithos》2007,94(1-4):132-147

Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.

Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition.  相似文献   

地幔流体的交代作用——来自碱性正长岩及其深源岩石包体的证据   总被引：2，自引：0，他引：2  

宋祥峰  刘显凡陶专卢秋霞  龙训荣 《岩石矿物学杂志》2007,26(4):310-314

滇西玉龙县小桥头硅化霓辉正长斑岩中,含有较多镁铁-超镁铁质深源包体岩石。经岩相学和电子探针及扫描电镜分析发现,伴随交代蚀变,寄主岩和各类镁铁-超镁铁质包体岩石中,普遍发育沿粒间和矿物晶体裂隙或解理纹贯入或穿插的黑色不透明物质,主要由微晶硅酸盐矿物和磁铁矿组成。本文研究认为,硅酸盐矿物与磁铁矿在背散射电子图像中表现为熔离特征,这种在透光显微镜下呈黑色不透明的微晶固体,是引发交代蚀变、具熔浆流体特点和超临界流体性质的地幔流体交代作用的一种微观表现。  相似文献   

Infiltration Metasomatism of Cumulates by Intrusive Magma Replenishment: the Wavy Horizon, Isle of Rum, Scotland   总被引：4，自引：0，他引：4  

Holness  M. B.; Hallworth  M. A.; Woods  A.; Sides  R. E. 《Journal of Petrology》2007,48(3):563-587

The Eastern Layered Intrusion of the Rum Layered Suite comprisespaired peridotite and allivalite (troctolite and gabbro) layersforming 16 macro-rhythmic units. Whereas the majority of thesemacro-units are believed to have formed by a process of crystal–liquiddifferentiation involving successive accumulation of crystalsfrom multiple picritic replenishments of the chamber, the Unit9 peridotite is interpreted as a layer-parallel picrite intrusion.Closely correlated with this discontinuous peridotite body isa distinctive feature generally known as the Wavy Horizon, whichdivides the overlying allivalite into a lower troctolite andan upper gabbro along a well-defined undulating contact. Wepropose that the Wavy Horizon is a metasomatic feature formedconsequent to the removal of clinopyroxene from an originalgabbroic mush. Foundering of the mush into the picritic sillresulted in the replacement of the original interstitial liquidby one saturated only in olivine (± plagioclase). Progressivethrough-flow of this liquid resulted in the stripping out ofclinopyroxene from the lower parts of the allivalite. We interpretthe Wavy Horizon as a reaction front, representing the pointat which the invading liquid became saturated in clinopyroxene.The distinctive pyroxene-enriched zone immediately above theWavy Horizon could have formed when mixing of the interstitialliquids on either side of the reaction front formed a supercooledliquid oversaturated in pyroxene, as a result of the curvatureof the olivine–plagioclase–clinopyroxene cotectic.The presence of many such approximately layer-parallel features,defined by differences in pyroxene content, in the Eastern LayeredIntrusion of Rum suggests that such an infiltration–reactionprocess was not unique to Unit 9. KEY WORDS: cumulate; infiltration metasomatism; Rum; Eastern Layered Intrusion  相似文献   

Variations in Melt Productivity and Melting Conditions along SWIR (70{degrees}E-49{degrees}E): Evidence from Olivine-hosted and Plagioclase-hosted Melt Inclusions   总被引：1，自引：0，他引：1  

Font  L.; Murton  B. J.; Roberts  S.; Tindle  A. G. 《Journal of Petrology》2007,48(8):1471-1494

Melt inclusion and host glass compositions from the easternend of the Southwest Indian Ridge show a progressive depletionin light rare earth elements (LREE), Na₈ and (La/Sm)_n, but anincrease in Fe₈, from the NE (64°E) towards the SW (49°E).These changes indicate an increase in the degree of mantle meltingtowards the SW and correlate with a shallowing of the ridgeaxial depth and increase in crustal thickness. In addition,LREE enrichment in both melt inclusions and host glasses fromthe NE end of the ridge are compatible with re-fertilizationof a depleted mantle source. The large compositional variations(e.g. P₂O₅ and K₂O) of the melt inclusions from the NE end ofthe ridge (64°E), coupled with low Fe₈ values, suggest thatmelts from the NE correspond to a variety of different batchesof melts generated at shallow levels in the mantle melting column.In contrast, the progressively more depleted compositions andhigher Fe₈ values of the olivine- and plagioclase-hosted meltinclusions at the SW end of the studied region (49°E), suggestthat these melt inclusions represent batches of melt generatedby higher degrees of melting at greater mean depths in the mantlemelting column. Systematic differences in Fe₈ values betweenthe plagioclase- and the olivine-hosted melt inclusions in theSW end (49°E) of the studied ridge area, suggest that theplagioclase-hosted melt inclusions represent final batches ofmelt generated at the top of the mantle melting column, whereasthe olivine-hosted melt inclusions correspond to melts generatedfrom less depleted, more fertile mantle at greater depths. KEY WORDS: basalt; melt inclusions; olivine; plagioclase; Southwest Indian Ridge  相似文献   

郭家岭岩体矿物包裹体研究     

王海芹  曲晓明  王鹤年 《山东国土资源》1998,(2)

通过对胶东金成矿区郭家岭岩体中熔融包裹体、含石盐子晶包裹体、ＣＯ２三相包裹体和Ｈ２Ｏ两相包裹体的显微测温,结果表明,该岩体在岩浆结晶晚期发生过高盐度流体与硅酸盐熔体的不混熔过程。根据熔融包裹体均一温度与均一过程的时间,利用相应公式,计算出郭家岭岩体包裹体熔体的粘度和含水量,认为该岩体是从一种高温高粘度的岩浆中结晶成岩的。  相似文献   

高压超高压变质作用中流体—熔体—岩石相互作用   总被引：2，自引：0，他引：2  

张泽明  韩郁菁 《地质科技情报》1998,17(3):24-30

在高压超高压变质作用过程中所释放的流体对俯冲板块的演化起着重要作用,与岛弧岩浆活动有着直接联系,随着温度和压力的增加,俯冲板片将发生高压到超高榴辉岩相转变,大量的水将通过含水矿物的消失反应释放出来,这些流体可引起上覆岩圈大规模水化,并促进地幔楔状体的部分熔融,同时,通过流体的向上迁移可将某些组分带入上覆岩石圈板块,并改变其总体组成,许多含水矿物,同变质脉体,高压自形晶体组成的布丁,原生液态包裹体和  相似文献   

上地幔熔体-岩石相互作用与大陆地幔演化   总被引：11，自引：2，他引：9  

徐义刚 《地学前缘》1998,(Z1)

根据实验岩石学、幔源岩石的岩石地球化学资料以及微量元素地球化学理论模拟等,评述了上地幔熔体岩石相互作用研究领域的最新进展,指出熔体岩石相互作用不仅深刻地制约了岩石圈地幔的矿物学、地球化学和物理性质的变化以及地幔不均一性的形成及演化,而且也会最终控制各种构造环境下喷出岩浆的地球化学特征,以及深部岩浆的分离机制。  相似文献   

Modelling observed and future runoff from a glacierized tropical catchment (Cordillera Blanca, Perú)   总被引：1，自引：1，他引：0  

Irmgard Juen  Georg Kaser  Christian Georges 《Global and Planetary Change》2007,59(1-4):37

Monthly runoff from the 34.3% glacierized tropical catchment of Llanganuco in the tropical Cordillera Blanca, Perú, is successfully simulated and compared with a measured 44 year time series. In the investigation area, the climate is characterized by all-year round homogenous temperature conditions and a strong variability in air humidity and moisture content of the atmosphere. Thus, contrary to the mid latitudes, the seasonal variation in glacier melt strongly depends on moisture-related variables, rather than on air temperature. The here presented ITGG-2.0-R model aims for these requirements. The lack of moisture-related input data other than precipitation demands for an intermediate calibration step. Net shortwave radiation, the emissivity of the atmosphere and a sublimation/melt ratio are related to precipitation amounts. Runoff is well simulated and correlates with the measured record with r² = 0.76. Seasonally obtained r² are only slightly smaller. On a long-term, the cumulative deviation is minor, and the mean annual cycle of runoff is reproduced rather well (r² = 0.99). Based on four different IPCC climate change scenarios, future runoff is simulated. All runoff scenarios are modelled for the respective steady-state glacier extent. This leads to a reduction in the glacier size and a decreased amount of glacier melt. On the other hand, direct runoff increases due to larger glacier free areas. Consequently, mean annual runoff remains almost unchanged, but the seasonality intensifies considerably with more runoff during the wet and less runoff during the dry season.  相似文献