封闭体系有机质与有机碳氢氮恢复动力学研究   总被引：3，自引：0，他引：3  

彭平安  秦艳  张辉  刘大永  张善文  隋风贵  李钜源  李政 《海相油气地质》2008,13(2):27-36

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献   

金岭寺—羊山盆地北票组烃源岩特征   总被引：2，自引：0，他引：2  

何保李茂丰  刘颖鑫 《中国煤炭地质》2008,20(3):25-27

通过对采集的岩样进行地球化学综合分析,得出金羊盆地北票组为盆地主要烃源岩,为盆地油气生成提供了物质基础;北票组烃源岩有机质丰度不高,属差一中等烃源岩;干酪根类型以腐殖型为主,成烃母质为陆地高等植物：金羊盆地北票组烃源岩已经进入成烃门限．并处于成熟阶段中的低成熟到中成熟阶段。  相似文献   

伊舒地堑方正断陷新安村组沉积微相研究   总被引：3，自引：1，他引：2  

陈宪保  柳成志  董秀超  李国一 《上海国土资源》2008,(3):41-44

依据岩心、地震、测井和录井资料,应用层序地层学和沉积学的原理和方法,查明了伊舒地堑方正断陷新安村组沉积微相特征.结果表明,方正断陷新安村组发育的沉积微相类型主要为分流河道、水下分流河道、河口坝、席状砂、滨浅湖砂质滩坝、泥质滩坝.在平面上沿北西部断裂向断陷中间依次过渡为扇三角洲平原、扇三角洲前缘、湖泊相,部分区域发育湖底扇;沿南东部断裂向断裂中间依次发育扇三角洲前缘和湖泊相.扇三角洲相在北部发育,湖泊相在南部和中部发育。  相似文献   

New basis for the constitutive modelling of aggregated soils   总被引：1，自引：1，他引：0  

Azad Koliji  Laurent Vulliet  Lyesse Laloui 《Acta Geotechnica》2008,3(1):61-69

Natural and compacted soils are usually characterized by aggregation of particles. The mechanical behaviour of these materials depends on soil structure. The oedometric compression tests performed on aggregated samples presented here showed that these materials exhibit a yield limit depending not only on stress history and stress state but also on soil structure. Evidence is provided using the neutron tomography technique. These results revealed that soil structure modification occurs together with plastic deformations. The experimental results are used to propose a new state parameter to quantify the soil structure. Based on pore-scale experimental observations, an evolution law for this parameter is proposed as a function of associated plastic strains. Considering both soil fabric and inter-particle bonding effects, a new yield limit depending on stress state, stress history and soil structure is introduced for the aggregated soils. Accordingly, a new constitutive framework consistent with strain hardening plasticity is proposed to consider soil structure effects in the modelling of aggregated soils.  相似文献   

试论我国城市发展方针   总被引：6，自引：0，他引：6  

陈雯 《地理研究》1996,15(3):16-22

在执行重重工业的发展战略和城乡分割体制的计划经济背景下,我国制定了“控制大城市规模,合理发展中等城市,积极发展小城市”的城市建设方针。但是分析表明,这一方针不能适应市场经济和对外开放形势的需要,也不符合我国人多地少、农村剩余劳动力多的国情,必须调整现有的城市发展方针,选择适宜的城市化发展道路。因此,本文就适度发展大中城市,提高城市现代化水平;加速乡村城市化,积极合理发展小城镇;以及根据不同地区的具体情况,因地制宜地指定城市化途径等方面作了探讨。  相似文献   

A dynamic box model of bioactive elements in the southern Taiwan Strait   总被引：3，自引：0，他引：3  

洪华生  商少凌 《中国海洋湖沼学报》1994,12(2):120-129

A dynamic box model was applied to study the characteristics of biogeochemical cycling of PO_4-P,NO_3-N,AOU,POC and PON in the southern Taiwan Strait region based on field data of the"Minnan Taiwan Bank Fishing Ground Upwelling Ecosystem Study" during the period of Dec.1987-Nov.1988.According to the unique hydrological and topographical features of the region,six boxesand three layers were considered in the model.The variation rates and fluxes of elements induced by hor-izontal current,upwelling,by diffusion,sinking of particles and biogeochemical processes were estimatedrespectively.Results further confirmed that upwellings had important effects in this region.Thenearshore upwelling areas had net input fluxes of nutrients brought by upwelling water,also had high de-pletion rates of nutrients and production rates of particulate organic matter and dissolved oxygen.Theabnormal net production of nutrients in the middle layer(10-30m) indicated the important role of bacte-ria in this high production region.Th  相似文献   

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)     

Hollander DJ  Sinninghe Damste JS  Hayes JM  de Leeuw JW  Huc AY 《Organic Geochemistry》1993,20(8):1253-1263

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.  相似文献   

The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models     

Santschi  Peter H.  Honeyman  Bruce D.  Quigley  Matthew S. 《Aquatic Sciences - Research Across Boundaries》1993,55(4):230-239

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.  相似文献   

山东省日照市蓝色经济区工程建设适宜性评价     

朱伟  李玲  杨鹏  杨崇敬  艾洪键 《地球学报》2024,45(1):112-122

本文以山东省日照市蓝色经济区为研究区, 通过野外地质调查和室内综合分析, 选取场地稳定性、工程地质条件、地下水条件, 地形排水条件、地质灾害及其他因素6个一级评价因子, 构造活动、场地土类型、建筑场地类别等13个二级评价因子, 利用专家-层次分析定权法进行区内工程建设适宜性评价, 得到了相应工程建设评价分区图。评价结果表明, 日照市场地工程建设适宜性总体较好, 大部分地区适宜进行高层建筑工程建设, 占84.50%; 地下空间开发利用条件优越, 全区多数地区属于城市地下空间建设适宜区, 适宜性差及不适宜区主要分布在付疃河两岸附近和海岸附近、大型高速公路和铁路沿线一带区域及城区; 轨道交通建设适宜性良好, 小部分不适宜区主要集中在付疃河下游夹仓和小古镇一带及其沿海地区。评价结果可有效地服务于该地区规划布局、建设发展和工程选址, 具有重要的理论和实践指导意义。  相似文献   

Diagenesis of vascular plant organic matter components during burial in lake sediments   总被引：12，自引：0，他引：12  

Philip A. Meyers  Mary J. Leenheer  Richard A. Bourbonniere 《Aquatic Geochemistry》1995,1(1):35-52

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.  相似文献