碳酸盐岩与泥质烃源岩生气规律对比研究   总被引：10，自引：1，他引：10  

黄志龙  钟宁宁  张四海 《地球化学》2003,32(1):29-34

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。  相似文献   

Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea   总被引：1，自引：0，他引：1  

Kyounghee Yang  Jin-Yeon Hwang  Sung-Hyo Yun 《Island Arc》2003,12(4):411-422

Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ¹³C_PDB = 2.4 to 4.0‰ and δ¹⁸O_SMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts.  相似文献   

磷脂脂肪酸在地下水微生物生态学中的应用及存在的若干问题   总被引：6，自引：0，他引：6  

潘响亮  邓伟  张道勇 《地理科学》2003,23(6):740-745

磷脂脂肪酸(PLFA)是研究地下水微生物生态的一种新兴技术，它比基于培养基的传统方法有许多明显的优势，但同时也存在一些需要解决的问题。样品中的PLFA总量可以通过转换因子估算地下水微生物的生物量，但微生物群落组成的差异和环境的物理变化都是潜在的误差来源，以传统微生物技术互补和选择合适的转换因子可提高结果的可靠性；PLFA还可以被用来指示地下水微生物在各种环境压力下的生理状态；用特定的PLFA生物标志物、PLFA的组成模式、指纹技术来描述地下水微生物的群落结构和变化特征时，存在的主要问题是不同微生物PLFA的重叠、背景值的干扰和环境因子变化的影响，以PLFA技术为主导，借助于数学统计方法，结合传统微生物技术、核酸鉴定、同位素示踪等多种技术可望有效地消除各种干扰因子，从而揭示完整的地下水微生物的生理生态，为地下水污染的生物修复提供理论指导。  相似文献   

Sediment Phosphorus Chemistry and Microbial Biomass along a Lowland New Zealand Stream   总被引：1，自引：0，他引：1  

R. W. McDowell 《Aquatic Geochemistry》2003,9(1):19-40

An evaluation of the distribution of P concentrations in streamflow, P fractions andthe microbial biomass P pool was made of bed and bank sediments along a lowlandstream in New Zealand. Agricultural intensification increased downstream. However,most P fractions decreased downstream (total P decreased from c. 400 to 250 mg kg^-1) in bed sediments, while P in streamflow remained relatively constant (generally < 0.005 mg l^-1) and sediment microbial P increased from 2 to 8 mg kg^-1. An investigation of P release from dried and rewetted sediments showed that solution P (CaCl2-P) increased, on average > 300%, and proportional to the size of the microbial biomass P pool before drying, except in sediments with much organic carbon (OC). When supplied with a P source (1 mg l^-1) and then simultaneously with a C source (glucose, 100 mg l^-1), all sediment behaved similarly and biotic sorption accounted for, on average, 27 and 34% of the total sediment uptake, respectively (maximum of 58%). The quantity of P taken up was related to the initial size of the microbial biomass P pool, and the availability of P as influenced by organic P complexes and OC. The sediment microbial biomass represents a transient, but small store of P could be useful to indicate bioavailable P inputs.  相似文献   

龙门山地区泥盆纪碳酸盐与硅质碎屑的混积相与混积机理   总被引：7，自引：0，他引：7       下载免费PDF全文

李祥辉  刘文均  郑荣才 《沉积与特提斯地质》1997,17(3):1-10

碳酸盐与陆源碎屑的混合沉积研究至今尚未引起足够重视。文献屈指可数。扬子西经缘龙门山地区盆纪发育了了这类良好的混合沉积。作者根据实际材料，首次从这一思路出发，识别该区泥盆纪Ｅｍｓｉａｎ期到Ｇｉｖｅｔｉａｎ早期的混积相四种，混积亚相约１４种，阐明了其优势混积作用；根据混积作用特征、沉积背景关系，划分出两大混积类型，即泥质背景下的混积１型和砂灰质背景下的混积Ⅱ型；对混积作用机理进行了探讨；并指出不同级次  相似文献   

黔南Triticites带旋回层序碳同位素特征及冰川型海平面变化   总被引：4，自引：0，他引：4  

李儒峰  刘本培 《地质学报》1996,70(4):342-350

应用层序地层学理论对黔南独山地区晚石炭世麦粒链带地层进行了详细的沉积层序分析和系统的碳同位素测定，识别出２个三级沉积层序和１７个准层序，其可与北美中大陆同期地层中发现的２个三级沉积层序和１７个亚层序对比，是晚石炭世Ｇｚｈｅｌｉａｎ期存在全球沉积记录同时性的佐证。同时探讨了碳同位素演化与全球海平面变化之间的内在联系，总结出沉积层序内碳同位素演化规律。  相似文献   

Dissolved carbon in pore waters from the carbonate barrier reef of Tahiti (French Polynesia) and its basalt basement     

R. Fichez  P. Harris  G. Cauwet  P. Dejardin 《Aquatic Geochemistry》1996,2(3):255-271

This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg^–1 pH of 7.6 and p(CO₂) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg^–1, pH of 7.70 and p(CO₂) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO₂) up to 5.6 times the atmospheric P(CO₂).  相似文献   

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron     

Wolfgang H. Berger  Memorie K. Yasuda  Torsten Bickert  Gerold Wefer 《International Journal of Earth Sciences》1996,85(3):466-495

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.  相似文献   

The Silurian of Gotland (Sweden): facies interpretation based on stable isotopes in brachiopod shells     

Chr Samtleben  A. Munnecke  T. Bickert  J. Pätzold 《International Journal of Earth Sciences》1996,85(2):278-292

The Silurian of Gotland, Sweden, consists of 440 m of carbonate deposits. Repeatedly, uniform sequences of micritic limestones and marls are interrupted by complex-structured reefs and by adjacent platform sediments. Generally, the alteration of facies is interpreted as the result of sea-level fluctuations caused by a gradual regression with superimposed minor transgressive pulses. The purpose of this study is a facies interpretation based on both field observations and stable isotope measurements of brachiopod shells. Approximately 700 samples from stratigraphically arranged localities in different facies areas have been investigated. The carbon and oxygen isotopes show principally parallel curves and a close relationship to the stratigraphic sequence. Lower values occur in periods dominated by deposition of marly sequences. Higher values are observed in periods dominated by reefs and extended carbonate platforms. The oxygen isotope ratios are interpreted to reflect paleosalinity changes due to varying freshwater input, rather than to paleotemperature. Carbon isotope ratios are believed to have been connected to global changes in the burial of organic carbon in black shales during periods of euxinic deep water conditions. Consequently, the facies succession on Gotland results from global paleoclimatic conditions. Changes in terrigenous input due to different rates of weathering and freshwater runoff, rather than sea-level fluctuations, control the carbonate formation of the Silurian on Gotland.  相似文献   

碳酸盐岩地区电磁波场的特性分析     

刘海滨  佟文琪 《世界地质》1996,15(1):82-87

形成岩溶的高阻碳酸盐岩对电磁波的吸收较弱，而且成层沉积的特定环境使碳酸盐岩地区岩石的各向异性现象较明显，由于地空界面的存在及岩溶洞壁两侧介质电性差异明显，界面清晰，又使电磁波出现强烈的反射及散射现象，从理论上对碳酸盐岩地区电磁波传播的特有现象进行了研究和分析，并给出结论。  相似文献