Mineralogical and Geochemical Constraints on the Genesis of the Carbonate‐Hosted Jebel Ghozlane Pb–Zn Deposit (Nappe Zone,Northern Tunisia)     

Nejib Jemmali  Fouad Souissi  Emmanuel John M. Carranza  Torsten W. Vennemann 《Resource Geology》2013,63(1):27-41

The Pb–Zn deposit at Jebel Ghozlane, in the Nappe zone (northern Tunisia), is hosted by Triassic dolostones and Eocene limestones and is located along faults and a thrust‐sheet boundary. The sulfide mineralization of the deposit consists mainly of galena and sphalerite and occurs as vein, stockwork, breccia, dissemination and replacement ores. Three hydrothermal stages are involved in the formation of the ores: stage I is dominated by celestite‐barite, hydrothermal dolomite DII, colloform sphalerite, and galena I; stage II consist of galena II; and stage III contains calcite. Galena in the deposit yielded average ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.705, 15.667 and 38.734, respectively, suggesting a single upper crustal source reservoir for metals. Trace element data indicate the presence of Zn‐ and As‐free galena and As‐rich galena (with 0.2–0.5% As). Sphalerite contains 0.4% As, 0.7–0.9% Cd and 0.1–1.5% Fe. Microthermometric analysis of fluid inclusions in celestite shows that the deposit formed from fluids composed of heterogeneous mixtures of saline (19.5 ± 1 wt% NaCl eq.) aqueous solutions sourced from basinal brines, and gaseous CO₂‐rich phases bearing low amounts of CH₄, N₂ and/or H₂S, at temperatures of 172 ± 5°C.  相似文献   

Geochemical monitoring of clays for diagenetic evolution of the Paleozoic–Lower Mesozoic sequence in the northern Arabian plate: Hazro and Amanos regions,Southeastern Turkey     

《Journal of African Earth Sciences》2013

Clay minerals in the diagenetic/very low-grade metamorphic–sedimentary series from southeastern Anatolia in Turkey were analyzed to determine their mineralogical and chemical compositions. In the Amanos region, the lowermost unit is composed of metaclastics with primary clastic textures, as well as slaty cleavages and chlorite-mica stacks including volcanic rock intercalations. The Lower Cambrian is composed of mainly very low-grade metamorphic clastic rocks, while the Ordovician units have siliciclastic and carbonate rocks. In the Hazro region, the Late Silurian–Lower Triassic units are represented by highly diagenetic carbonate and clastic rocks. All of the rock units include illite. In addition, chlorite, mixed-layered illite–chlorite and chlorite–vermiculite are present in the Amanos region, while calcite, dolomite, kaolinite, mixed-layered illite–smectite (I–S) and glauconite occur in the Hazro region. The illites are characterized by the dominance of 2M₁ polytype in the Amanos samples; and 1M_d + 2M₁ in the Hazro samples. The I–S, glauconite and kaolin have R1 and R3, 1M and kaolinite polytypes, respectively. The illites have greater tetrahedral and lower octahedral substitutions than the I–S. Total trace element contents, elemental substitutions and chondrite-normalized trace element and REE values decrease toward illite–I–S–kaolinite. There are obvious fractionations for some major – trace and rare earth elements with respect to each other and clear enrichment with respect to the chondrite, with strong anomalies of positive for Gd and negative for P, K and Eu in the clay minerals. The textural, morphological and geochemical data indicate that kaolinite and I–S in the Hazro area occur in supergene conditions with due to a full neoformation mechanism, whereas illites in the Amanos region represent the hypogene origin. In brief, the K₂O contents, ratios of Eu/Eu^* and La_N/Lu_N and δ¹⁸O and δD values of I–S and illite exhibit notable relationships with increasing diagenetic/metamorphic grade.  相似文献   

An Optimised 1,10‐Phenanthroline Method for the Determination of Ferrous and Ferric Oxides in Silicate Rocks,Soils and Minerals     

Pranab K. Tarafder  Raghbendra Thakur 《Geostandards and Geoanalytical Research》2013,37(2):155-168

A precise, accurate and rapid method for the sequential determination of FeO and Fe₂O₃ in rocks, soils and some non‐refractory minerals by 1,10‐phenanthroline spectrophotometry is described. Fe(II) and Fe(III) were leached from the sample (?200 mesh) using a mixture of NH₄HF₂ and H₂SO₄ at 40–80 °C for 10 min on a hot plate. Both Fe(II) and Fe(III) could be conveniently estimated sequentially from the same reaction mixture at the μg g^?1 to percentage level. The method is better than the existing wet chemical methods, including the commonly used Pratt's titrimetric redox method, for Fe(II) and Fe(III) determinations in rock and soil samples in terms of precision, accuracy and rapidity. The throughput of the method was very high; at least forty to fifty samples could be estimated easily in a day. The results obtained compare favourably with those obtained by Pratt's method, as well as for certified/recommended values of a set of eleven certified reference materials having FeO and Fe₂O₃ contents in the range 0.21–14.63% and 0.58–8.48%, respectively. The optimised 1,10 phenanthroline method was found to be accurate to within 0.21% m/m FeO and 0.30% m/m Fe₂O₃ compared with the literature values of the certified reference materials studied.  相似文献   

中俄蒙毗邻地区主要金属矿产分布特征   总被引：1，自引：0，他引：1  

柴璐  朱群  周永恒 《地质与资源》2013,22(5):397-402

通过介绍中俄蒙毗邻地区区域地质背景、成矿区划及区内金、银、铜、铅锌、铁等主要金属矿产资源概况,归纳总结了该区主要金属矿床的时空分布特征:金属矿床分带特征明显,成矿时期集中于燕山期,成矿作用主要与蒙古-鄂霍次克构造带拼合-碰撞造山作用有关.  相似文献   

我国煤炭资源主要工业指标应用问题研究     

万会  苗琦  万贵龙 《中国煤炭地质》2013,(7)

矿床工业指标的运用直接关系到矿体的圈定、勘查类型的划分、资源储量类别的确定和资源储量总量。作为煤炭资源大国,我国现行煤炭资源工业指标存在不尽合理的问题,它将影响到资源利用率评价数据的可靠性,给矿产资源储量监督管理工作带来不便。通过分析现行规范推荐的一般工业指标存在的主要问题,指出了目前工业指标管理中存在的漏洞。认为目前亟待制订科学合理、适时有效的工业指标,据此估算资源储量,掌控我国煤炭资源家底,以实施有效的煤炭资源监督。修定新的煤炭工业指标应有利于指导勘查单位合理地圈定资源储量,并对维护矿产资源国家所有权益、促进矿产资源积极作用和综合利用、提高矿政管理水平发挥积极作用。  相似文献   

具磷灰石假象绿松石的岩石矿物学及谱学特征     

申广耀  卢保奇  亓利剑 《上海国土资源》2013,(4):96-100

采用x射线粉晶衍射（XRD）、博里叶变换红外光谱（FTI码以及拉曼光谱等方法对安徽马鞍山具磷灰石假象的绿松石进行了研究。结果表明：其主要矿物组成为绿松石,保留了磷灰石六边形的形态特征。XRD~U试的特征谱线d值为36745～36748（111）、29008～29025（123）、34247～34293（2101、32709～32781（113）、61626～61781（011）3020130～20162（301）,与绿松石的标准衍射谱线基本致。红外光谱测试分析表明：3510～3465cm。间的谱带归属绿松石0（OH）的伸缩振动,3300～3070cm’间的谱带归属为绿松Nu（M-H。O）伸缩振动,1210-1012cm’间的谱带归属为绿松石U3口O。）ira缩振动,在838cm。附近的吸收谱带归属为绿松石6（OH）弯曲振动,655-480cm。间的谱带归属为绿松石u4（P04）弯曲振动。拉曼光谱测试分析表明：3466cm’附近的尖锐拉曼谱峰归属于绿松石（OH）基团的伸缩振动所致,宽缓的拉曼谱峰3281cm’~03078cm’归属于绿松石中水合络离子的伸缩振动,798cm’谱峰则是由于OH的弯曲振动所致。  相似文献   

相山铀矿田典型蚀变矿物地面光谱特征研究     

李满根  方鹏高  刘寅翔  任国刚  魏超  宋祥健 《华东地质学院学报》2013,(4):381-384,448

利用光谱特征进行岩石矿物分析受到了国内外研究者的广泛关注,大多数蚀变矿物如赤铁矿、水云母等在可见光-近红外-短波红外波段具有诊断性强的波谱特征。因此,利用典型岩石矿物光谱特征可为矿产资源勘查与评价提供一种新的手段和方法。本文对相山铀矿田蚀变矿物进行光谱测量,经数据处理获得了不同典型蚀变岩石矿物的反射率光谱曲线。通过对这些光谱曲线特征的分析研究,提出了影响岩石矿物反射率的因素,探讨了水云母、萤石、赤铁矿等典型蚀变岩石的反射率曲线特征,并建立了相应的典型蚀变矿物光谱识别模型。  相似文献   

实验矿物学方法研究进展     

雷洁  王金荣  赵磊 《甘肃地质》2013,22(1):90-93

基于3S技术的数字填图RGMAP区域地质调查技术实现了区域填图中数据采集的全过程信息化,其中背景图层数据参数的正确调整是数字化区调项目野外各项工作顺利开展的前提。本文根据笔者在数字填图技术应用中得切身体会,对背景图层参数不规范,比例尺不统一及路线或剖面导入后无法正常显示等常见问题的解决方法进行了较为详细的介绍。  相似文献   

冀南邯邢地区白涧和西石门夕卡岩型铁矿磁铁矿成因矿物学研究          下载免费PDF全文

张聚全  李胜荣  王吉中  白明  卢静  魏宏飞  聂潇  刘海明 《地学前缘》2013,20(3):76-87

对邯邢地区典型夕卡岩型铁矿床白涧铁矿和西石门铁矿中不同产状的磁铁矿的成分、热电性、爆裂温度及O同位素进行了详细的成因矿物学研究。研究发现：层间矿体具有低Ti、∑REE、爆裂温度、δ18O的特征,热电性系数较小但变化范围大;接触带矿体为高Ti、∑REE、爆裂温度、δ18O的特征,热电性系数较大,变化范围小。白涧铁矿层间矿和西石门铁矿中磁铁矿的REE表现出Eu的正异常,而白涧铁矿接触带矿为负异常。白涧铁矿磁铁矿中单层矿体热电性系数具有中部小、顶底大的特征。综合磁铁矿的成因矿物学研究,以热电性的空间变化规律为基础,建立了该区夕卡岩型铁矿的成因和找矿模型。  相似文献   

华夏陆块闽西南坳陷二叠系含有机质页岩组成及赋气孔隙特征          下载免费PDF全文

房立志  琚宜文  王国昌  卜红玲 《地学前缘》2013,20(4):229-239

华夏陆块从早古生代以来,经历了多期推覆与伸展构造的叠加。文中对华夏陆块闽西南仙亭、曲斗等地区/矿区附近及井下所采集的含有机质页岩样品进行实验测试,分析了有机质参数、矿物组成及赋气孔隙参数,将对中国华夏陆块闽西南二叠系页岩的储层特征研究及页岩气勘探前景预测提供理论依据。研究结果表明：(1)采用TOC残余碳分析实验、荧光显微镜及显微镜光度计实验等,认为闽西南二叠系页岩含碳量中等,为0.15%~2.71%;有机质成熟度高,为3.51%~4.33%。(2)储层矿物组成方面,利用X射线衍射实验进行全岩分析,结果显示黏土矿物占38.2%~49.6%,含量较高,主要为伊利石,含少量的绿泥石、蒙皂石;常见非黏土矿物主要为石英,均占45%以上;钾长石和斜长石含量较少,占1%~2.3%。(3)储层孔渗性方面：有效孔隙度为0.3%~11.4%,渗透率为(0.006 5~0.987)×10-3μm2;利用低温液氮吸附实验等对纳米级孔隙进行分析,认为部分小孔(2~50 nm)的孔容、比表面积较大,其次为微孔(小于2 nm)和大孔(大于50 nm)。此外,累计比表面积和累计孔容呈现出较好的正相关性,纳米孔隙累计比表面积、累计孔容与孔径之间的关系表明,闽西南二叠系页岩气主要赋存于微孔和小于10 nm的小孔中。依照页岩储层评价标准,闽西南二叠系海陆交互相页岩在有机质丰富、有机质成熟度、页岩厚度、矿物组成、孔隙结构等方面符合页岩气开发最低标准,具有勘探开发前景。  相似文献