水平电极发射光谱法测试多目标生态地球化学土壤样品中的钼     

郑瑞华 《福建地质》2007,26(2):126-130

以K2SO4、S粉、C粉、聚三氟氯乙烯粉、Al2O3、MgO混合物作为缓冲剂,以Sb为内标,电极发射光谱法测试多目标地球化学土壤样品中的钼。方法的检出限为0.28μg/g(3S),方法的精密度(RSD)为7.25%~8.66%。测试了国家一级地球化学标准物质,结果与标准值相符合。该方法已用于10000多件土壤样品的分析,并取得满意的结果。  相似文献   

Heavy clastic minerals from the Far East island-arc complexes     

A. I. Malinovsky  P. V. Markevich 《Russian Journal of Pacific Geology》2007,1(1):71-81

The results of the study of heavy clastic minerals from the Cretaceous-Paleogene terrigenous complexes of Sikhote-Alin and Kamchatka, as well as from the Cenozoic sediments of the deepwater Vanuatu Trench, are summarized. The data obtained have been interpreted on the basis of their comparison with heavy mineral assemblages of recent sediments deposited in known geodynamic settings. It is shown that the heavy clastic minerals of sedimentary rocks, their relative quantities, and chemical compositions may serve as reliable indicators of different island-arc settings and magmatic processes; these indicators may also be used for identification of such settings in paleobasins of orogenic regions.  相似文献   

Mineral magnetic and physical properties of surficial sediments and onshore samples from the southern basin of Lake Baikal, Siberia     

J.A. Lees  R.J. Fowler  P.G. Appleby 《Journal of Paleolimnology》1998,20(2):175-186

Results of lithostratigraphic and mineral magnetic analysis of two surficial sediment cores (21 cm and 45 cm in length) collected from the Southern basin of Lake Baikal at a water depth of 1390 m, are presented. The sediments have been measured for a wide range of mineral magnetic parameters in order to assess their value in the identification of turbidite layers. Particle size and geochemical data are also presented and these explain some of the down core variations in magnetic mineralogy. It is suggested that changes in the particle size frequency distributions down core may be related to fossil diatom shells. One of the cores has been dated using ²¹⁰Pb. The sediment cores were cross-correlated using low frequency magnetic susceptibility (f) and these cores can also be correlated with a nearby core collected earlier in 1992. Changes in the magnetic parameters of lf, IRMs and HIRM₂₁₀ suggest that there are significant changes in the concentration of ferrimagnetic minerals in the sediment cores, indicating changing sediment sources and/or increasing concentrations of spheroidal carbonaceous particles and the dissolution of minerals through reduction below the oxidised layer within the sediment core.  相似文献   

铝硅酸盐矿物和玻璃中Al的配位与局部结构   总被引：3，自引：2，他引：1  

彭明生  李迪恩 《矿物学报》1998,18(4):425-430

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。  相似文献   

地壳浅部导电性矿物的一种新的压溶机制：应力原电池过程   总被引：3，自引：0，他引：3  

李和平 《矿物学报》1998,18(1):80-83

以黄铁矿为例,通过导电性矿物的力学-电化学相互作用实验,得出：导电性矿物的电极电位与弹性轴压应力是较好的负线性相关关系。以此为基础,通过电化学理论分析,得出：地壳浅部与溶液接触的导电性矿物颗粒内部存在各种各样的应力原电池,通过应力原电池过程,压溶作用得以实现。导电性矿物应力原电池引起压涛作用的发现,无疑对诸如构造地球化学、地电化学甚至湿法冶金等领域的有关研究具有重要意义。  相似文献   

Oxygen isotope fractionation in mantle minerals     

Yongfei Zheng  Chunsheng Wei  Gentao Zhou  Baolong Xu 《中国科学D辑(英文版)》1998,41(1):95-103

The increment method is adopted to calculate oxygen isotope fractionation factors for mantle minerals, particularly for the polymorphic phases of MgSiO₃ and Mg₂SiO₄. The results predict the following sequence of¹⁸O-enrichment:pyroxene (Mg, Fe, Ca)₂Si₂O₆>olivine (Mg, Fe)₂SiO₄ > spinel (Mg, Fe)₂SiO₄> ilmenite (Mg, Fe, Ca) SiO₃>perovskite (Mg, Fe, Ca) SiO₃. The calculated fractionations for the calcite-perovskite (CaTiO₃) System are in excellent agreement with the experimental calibrations. If there would be complete isotopic equilibration in the mantle, the spinel-structured silicates in the transition zone are predicted to be enriched in¹⁸O relative to the perovskite-structured silicates in the lower mantle but depleted in¹⁸O relative to olivines and pyroxenes in the upper mantle. The oxygen isotope layering of the mantle might result from differences in the chemical composition and crystal structure of mineral phases at different mantle depths. Assuming isotopic equilibrium on a whole earth scale, the chemical structure of the Earth’s interior can be described by the following sequence of¹⁸O-enrichment:upper crust>lower crust>upper mantle>transition zone>lower mantle>core. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.  相似文献   

陕西金堆城斑岩钼矿床成矿流体研究   总被引：18，自引：0，他引：18  

徐兆文  杨荣勇 《高校地质学报》1998,4(4):423-431

陕西金堆城斑岩钼矿床是中国最大的钼矿床之一,按照脉体相互切割关系,成矿过程可分为两期十个阶段。矿区内流体包裹体研究表明：成矿流体以富CO2为特征,温度介于83℃～142℃之间,盐度介于27.5～42.5wt％NaCl两个区间内,具有典型的双配分模式特征。氢氧同位素特征研究表明成矿物质主要来源于岩浆流体。晚阶段有大量雨水混入热液流体中,导致流体的温度、盐度和δ18OH2O、δD值下降,引起了成矿流体中的钼金属沉淀,形成了金堆城超大型斑岩钼矿床。  相似文献   

浅论马鞍山地区的膨胀土     

简河清 《世界地质》1998,17(3):83-85

膨胀土由于粘土矿物含量较多,在一定气候条件下其体积随含水量的增加而膨胀,随含水一的减少而收缩,以膨胀土为地基的低层建筑物常常成群开裂,笔者首次报道了马鞍山地区的膨胀土,并对该区膨胀土的分布,成因,评价方法和防治措施等提出了初步看法。  相似文献   

Sea level induced variations in clay mineral composition in the southwestern South China Sea over the past 17,000 yr     

Stephan Steinke  Till J.J. Hanebuth  Christoph Vogt  Karl Stattegger 《Marine Geology》2008,250(3-4):199-210

Variations in clay mineral composition of sediment cores from the margin and continental slope of the Sunda Shelf (southern South China Sea, SE Asia) covering the past 17,000 yr reflect changing influences of sediment sources together with clay mineral partitioning processes in shallow waters. We identify the deglacial sea level rise as the principal factor driving these changes. During the late glacial, high values of kaolinite are interpreted to reflect a higher contribution of clays from soils that have formed on the exposed Sunda Shelf and in the southern archipelagos of Indonesia. At this time core sites were located in close proximity to the mouths of the Sunda Shelf palaeo-drainage systems on the emerged shelf (“Sundaland”). The progressive landward displacement of the coastline and breakdown of these vast drainage systems during deglaciation led to a decrease in influence of the kaolinite-rich southern sources. When the coastline had retreated closely to its present-day position in mid-Holocene times, the former dominance of southern sources was replaced by a stronger influence of illite-rich sources (e.g. Borneo). The overriding control of sea level changes on the clay mineral distribution patterns precludes a definite climatic interpretation of clay mineral data in terms of climatic/monsoonal changes in such highly dynamic sedimentary environment.  相似文献   

柴达木盆地烃蚀变矿物高光谱遥感识别研究   总被引：2，自引：0，他引：2  

胡畔  田庆久  闫柏琨 《国土资源遥感》2009,(2):54-61

高光谱遥感识别烃蚀变矿物可用于探测油气烃类微渗漏和定位地下油气藏.以有天然气分布的柴达木盆地东部三湖地区为研究区,对Hyperion高光谱数据进行重采样处理,克服了目标识别矿物不明显和传感器低信噪比的影响.通过确定烃蚀变矿物高光谱遥感探测的指示标志,采用线性光谱(SAM)拟合与光谱匹配(SAM)相结合的方法确定了影像端元对应的矿物组分.识别结果表明,合理缩减影像波段数和确定影像端元的方法,能有效提高烃蚀变矿物的高光谱遥感识别精度.  相似文献