蒸馏分离-电感耦合等离子体质谱法测定地球化学样品中痕量钌和锇   总被引：1，自引：1，他引：0  

施意华  杨仲平  熊传信  徐华 《岩矿测试》2010,29(4):350-354

建立了蒸馏分离-电感耦合等离子体质谱法测定地球化学样品中痕量钌和锇的分析方法。进行了蒸馏温度和时间、氧化剂、吸收液等条件的选择,消除了等离子体质谱法测定钌和锇的干扰。样品用过氧化钠熔融,酸化后以高锰酸钾-过硫酸钾-氯化钠作为同时蒸馏钌和锇的氧化剂,采用20 mL 50 g/L水合肼溶液同时吸收从混合物中分离出来的痕量钌和锇,用电感耦合等离子体质谱法测定。方法的检出限Ru为0.020 ng/g,Os为0.015 ng/g;方法加标回收率Ru为94.0%~102.7%,Os为96.0%~102.4%;精密度为4.72%~9.58%(n=12)。方法经国家一级标准物质验证,钌和锇的测定结果与标准值相符。  相似文献   

次灵敏线-火焰原子吸收光谱法连续测定 高品位矿石中的铜铅锌量     

张华 《地质与勘探》2010,46(Z1):1282-1287

[摘要]分别以铜327郾4 nm 和249郾2nm、铅283郾3 nm 和261郾4nm、锌307郾6nm 次灵敏线为分析线, 火焰原子吸收光谱法测定了高品位矿石中铜、铅、锌的含量。考察了高品位矿石基体及主要杂质的干扰 情况,结果表明,铜、锌质量浓度小于2 mg/ ml 时,对铅的测定无干扰;铅质量浓度小于2 mg/ ml 时,对铜 测定无干扰,其质量浓度小于0郾5mg/ ml 时,对锌测定无干扰;测定溶液中主要杂质铁、钴、镍、钙、镁质量 浓度在1mg/ ml,铝、硅质量浓度在0郾2mg/ ml 对测定无干扰。铜铅锌的质量浓度分别在0 ~ 1000滋g/ ml 范围内呈良好的线性关系。方法的精密度(RSD,n=5) 小于5%,加标回收率在98郾91% ~ 101郾08%,测 定铜铅锌矿石国家标准物质,结果与标准值相符。  相似文献   

Method of radial sounding and elemental analysis of formations during well logging using neutron inelastic scattering gamma time-of-flight spectrometry     

M.A. Fedorin  B.G. Titov   《Russian Geology and Geophysics》2010,51(12):1295-1303

This paper describes a well logging method and device designed to determine radial inhomogeneities in the elemental content of the borehole environment with high spatial resolution. The sounding factor that determines the spatial resolution is the time elapsed from the moment of neutron emission from the device to the moment the device records the gamma rays from neutron inelastic scattering (inelastic gamma rays, IGRs) in the formation. The time interval characterizes the distance to the point of origin of a gamma ray, and the energy of a gamma ray passing through the formation without interaction determines the chemical element involved in inelastic scattering.Simulations have shown that at each time, the density of inelastic scattering is very well localized in space owing to the small number of fast-neutron scatterings: on average, one to two events. It is the compact localization of inelastic scattering events that provides high radial resolution (and, if necessary, high azimuth resolution) during fast-neutron sounding of formations and measurement of unsteady IGR fluxes. Recording of IGR distributions over time also provides increasing sounding depth because powerful IGR fluxes from nearby regions reach the detector at short times and do not overlap the weaker IGR fluxes from distant regions because the latter reach the detector later.To evaluate the radial resolution of the method, we calculated the response of the sonde for typical models of a borehole environment which include a borehole, an iron casing, cement, an invaded zone, and an uninvaded rock. The boundaries of spatial inhomogeneities and the elemental content in the regions between these boundaries were determined from time dependences of unscattered spectral lines in IGR spectra for the elements Ca, Si, C, O, and Fe. The results of the numerical simulation indicate a high sensitivity of the measurements to the radial boundaries and an adequate spatial resolution: about 1 cm at a 0.1 ns time sampling of logs. The interfaces between the radial zones are clearly marked in the time distributions by steep fronts with a length of 0.1 ns (at a collimation angle of the source of about 30°) to 0.15–0.4 ns (at an angle of 90°).A method of solution was formulated for the inverse problem consisting of determining the boundaries of the radial zones and the elemental content in these zones. The problem is solved using a qualitative model of the borehole environment, for example, a “borehole–casing–cement–invaded zone–uninvaded rock” model. The method is based on searching for approximating model curves to measured time distributions of unscattered IGR fluxes jointly for all components of the model. The search is conducted by spatial optimization of the sought parameters—the distances {rS} from the neutron source to the boundaries of the zones and the concentrations {C} of specified chemical compounds in these zones. The initial approximations for the sought parameters {rS} and {C} are calculated by linear inversion of logs, which proves to be very accurate because the contribution of singly scattered neutrons to the inelastic scattering density at small times (10 ns) is, on average, 50–90%.Model curves are calculated by numerical simulation of the transport of neutrons and gamma rays. An appropriate calculation method is the Monte Carlo technique. Since the multiplicity of neutron scattering is low and, for gamma rays, only the unscattered component is of interest, the numerical simulation is a fast process.The practical implementation of the method requires the use of advanced developments in the design of neutron generators, spectral gamma-ray detectors, and fast analyzers for recording subnanosecond processes. Use of associated-particle neutron generators, Ge semiconductor detectors with electron cooling or LaBr3 (Ce) and BaF2 based fast scintillator blocks of high energy resolution will allow the application of the proposed method to logging measurements.  相似文献   

Isobar Attenuation Using Anion–Gas Reactions for Accelerator Mass Spectrometry and Application to 36Cl     

John Eliades  Xiaolei Zhao  William E. Kieser  Albert E. Litherland 《Geostandards and Geoanalytical Research》2010,34(2):107-115

Preliminary tests of a prototype radio-frequency quadrupole (RFQ) collision cell system, known as an isobar separator for anions (ISA), for the removal of isobaric interferences for accelerator mass spectrometry (AMS) and for studies of anion–gas interactions are reported. The ISA decelerated a mass-analysed beam of anions from an energy (∼ 20 keV) typically generated by an AMS ion source to < 10 eV. RFQs and electrostatic lenses then guided the ions through the collision cell where ion-gas collisions reduced both the energy and energy spread of the ion beam (cooled the ions) and ion-gas reactions attenuated most of the unwanted isobars. The anions were then re-accelerated to their original energy for injection into the rest of the AMS system. With the ISA installed on a full 3 MV AMS system, attenuations of ³²S^-, ¹²C₃^- and ³⁹K^- by six, seven and greater than ten orders of magnitude, respectively were achieved using 0.7–1 Pa NO₂ gas in the collision cell, while maintaining approximately 10–30% of the chlorine anion transmission. A further measurement of a ³⁶Cl/Cl = 4.1 × 10^-11 RM is also described. The results suggest that the ³⁶Cl/Cl lower detection limit of the current system was 10^-14–10^-15 for samples that could be prepared with S/Cl ratios below 10 μg g^-1.  相似文献   

Molecular characterization of dissolved organic matter (DOM) along a river to ocean transect of the lower Chesapeake Bay by ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry   总被引：1，自引：0，他引：1  

Rachel L. Sleighter  Patrick G. Hatcher   《Marine Chemistry》2008,110(3-4):140-152

In this study, electrospray ionization coupled to Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) is utilized to molecularly characterize DOM as it is transported along a river to estuary to ocean transect of the lower Chesapeake Bay system. The ultrahigh resolving power (greater than 500,000) and mass accuracy of FTICR-MS allow for the resolution of the thousands of components in a single DOM sample, and can therefore elucidate the molecular-level changes that occur during DOM transformation from a terrestrial location to the marine environment. An important feature of FTICR-MS is that its sensitivity allows for direct analysis of low salinity samples without employing the traditional concentration approaches involving C₁₈ extraction or ultrafiltration. To evaluate the advantages of using direct analysis, a C₁₈ extract of riverine water is compared to its whole, unfractionated water, and it was determined that the C₁₈ extraction is selective in that it eliminates two major series of compounds. One group is aliphatic amines/amides that are not adsorbed to the C₁₈ disk because they exist as positive ions prior to extraction. The second group is tannin-like compounds with higher oxygen contents and a more polar quality that also allow them not to be adsorbed to the C₁₈ disk. This direct approach could not be used for brackish/saline waters, so the C₁₈ method is resorted to for those samples. Along the subject transect, a significant difference is observed in the molecular composition of DOM, as determined from assigned molecular formulas. The DOM tends to become more aliphatic and contain lower abundances of oxygen-rich molecules as one progresses from inshore to the offshore. A considerable amount of molecular formula overlap does exist between samples from sites along the transect. This can be explained as either the presence of refractory material that persists throughout the transect, due to its resistance to degradation, or that the assigned molecular formulas are the same but the chemical structures are different. ESI-FTICR-MS is a powerful technique for the investigation of DOM and has the ability to detect compositional variations along the river to ocean transect. Visualization tools such as two dimensional and three dimensional van Krevelen diagrams greatly assist in highlighting the shift from the more aromatic, terrestrial DOM to the more aliphatic, marine DOM.  相似文献   

Contribution of oceanic circulation to the polewar heat flux     

Huang Ruixin 《中国海洋大学学报(英文版)》2005,4(4):277-287

Oceanic contribution to the poleward heat flux in the climate system includes two components: the sensible heat flux and the latent heat flux. Although the latent heat flux has been classified as atmospheric heat flux exclusively, it is argued that oceanic control over this component of poleward heat flux should play a critically important role. The so-called swamp ocean model practice is analyzed in detail, and the critical role of oceanic circulation in the establishment of the meridional moisture transport is emphasized.  相似文献   

AN IMPROVED LAND-SURFACE PROCESS MODEL AND ITS SIMULATION EXPERIMENT—PART II:COUPLING SIMULATION EXPERIMENT OF LAND-SURFACE PROCESS MODEL WITH REGIONAL CLIMATE MODEL          下载免费PDF全文

丁一汇  张晶  赵宗慈 《Acta Meteorologica Sinica》2000,(1)

The Land-surface Process Model(LPM-ZD)has been successfully coupled with the regionalclimate model RegCM2 of NCAR.Then thus-obtained coupled model(CRegCM)has been appliedto simulate the climate characteristics of heavy rain in middle and East China for three months fromMay to July 1991.and compared with model output of NCAR-RegCM2 using BATS as land-surface process scheme,abbreviated as NRegCM.The results show that CRegCM has good abilityand performance.CRegCM successfully simulates the extreme precipitation event and thesimulations of CRegCM for surface temperature and some physical variables related to land surfaceprocess are more reasonable than those of NRegCM.  相似文献   

Simulation of double cold cores of the 35°N section in the YellowSea with a wave-tide-circulation coupled model     

夏长水  乔方利  张勐宁  杨永增  袁业立 《中国海洋湖沼学报》2004,(3)

Based on the MASNUM wave-tide-circulation coupled numerical model, the temperature structure along 35°N in the Yellow Sea was simulated and compared with the observations. One of the notable features of the temperature structure along 35°N section is the double cold cores phenomena during spring and summer. The double cold cores refer to the two cold water centers located near 122°E and 125°E from the depth of 30m to bottom. The formation, maintenance and disappearance of the double cold cores are discussed. At least two reasons make the temperature in the center (near 123°E) of the section higher than that near the west and east shores in winter. One reason is that the water there is deeper than the west and east sides so its heat content is higher. The other is invasion of the warm water brought by the Yellow Sea Warm Current (YSWC) during winter. This temperature pattern of the lower layer (from 30m to bottom) is maintained through spring and summer when the upper layer (0 to 30m) is heated and s  相似文献   

Simulation and analysis on seasonal variability of average salinityin the Yellow Sea   总被引：1，自引：0，他引：1  

马建  乔方利 《中国海洋湖沼学报》2004,22(3):306-313

The CTD (conductivity, temperature and depth) data collected by six China-Korea joint cruises during 1996-1998 and the climatological data suggest that the seasonal variability of average salinity in the Yellow Sea (Sa) presents a general sinusoid pattern. To study the mechanism of the variability, annual cycles of Sa were simulated and a theoretical analysis based on the governing equations was reported.Three main factors are responsible for the variability: the Yellow Sea Warm Current (YSWC), the Changji-ang (Yangtze) River diluted water (YRDW) and the evaporation minus precipitation (E-P). From December to the next May, the variability of Sa is mainly controlled by the salt transportation of the YSWC. But in early July, the YSWC is overtaken and replaced by the YRDW which then becomes the most important controller in summer. From late September to November, the E-P gradually took the lead. The mass exchange north of the 37癗 line is not significant.  相似文献   

APPLIED STUDY ON ATMOSPHERE-OCEAN-WAVE COUPLED MODEL IN SOUTH CHINA SEA     

关皓  周林  薛彦广  张阳 《热带气象学报(英文版)》2013,19(4):367-374

Based on MM5,POM,and WW3,a regional atmosphere-ocean-wave coupled system is developed in this work under the environment of Message Passing Interface.The coupled system is applied in a study of two typhoon processes in the South China Sea(SCS).The results show that the coupled model operates steadily and efficiently and exhibits good capability in simulating typhoon processes.It improves the simulation accuracy of the track and intensity of the typhoon.The response of ocean surface to the typhoon is remarkable,especially on the right side of the typhoon track.The sea surface temperature(SST)declines,and the ocean current and wave height are intensified.In the coupling experiment,the decline of SST intensifies and the inertial oscillation amplitude of the ocean current increases when the ocean-wave effect is considered.Therefore,the atmosphere-ocean-wave coupled system can help in the study of air-sea interaction and improve the capability of predicting and preventing weather and oceanic disasters in SCS.  相似文献